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Geochemistry and Zircon U–Pb age of the Yao’an pseudoleucite porphyry, Yunnan Province, China

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Abstract

The Yao’an Pb–Ag deposit, located in the Chuxiong Basin, western Yangtze Block, is an important component of the Jinshajiang–Ailaoshan alkaline porphyry–related polymetallic intrusive belt. This complex suite of rock bodies includes a vein of pseudoleucite porphyry within deposits of syenite porphyry and trachyte. The pseudoleucite is characterized by a variable greyish, greyish-white, and greyish-green porphyritic texture. Phenocrysts are mainly pseudoleucite with small amounts of alkali feldspar and biotite. In an intense event, leucite phenocrysts altered to orthoclase, kaolinite, and quartz. Both the pseudoleucite porphyry and the syenite porphyry samples were typical alkali-rich, K-rich, al-rich rocks with high LaN/YbN ratios; enriched in light rare earth elements and large-ion lithophile elements, and depleted in high field strength elements; and with strongly negative Ta, Nb, and Ti (TNT) anomalies and slightly negative Eu anomalies—all characteristics of subduction-zone mantle-derived rock. We obtained a LA-ICP-MS zircon U–Pb age of 34.1 ± 0.3 Ma (MSWD = 2.4), which is younger than the established age of the Indian and Eurasian Plate collision. The magma derived from a Type-II enriched mantle formed in a post-collisional plate tectonic setting. The geochemical characteristics of the Yao’an pseudoleucite porphyry are powerful evidence that the porphyry’s development was closely linked to the Jinshajiang–Ailaoshan fault and to the Indian-Eurasian collision.

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References

  • Bi XW, Hu RZ, Cornell DH (2000) The origin of altered fluid: REE evidence from primary and secondary feldspars in the mineralization-alteration zone. Chin Sci Bull 45:1429–1432 (in Chinese)

    Article  Google Scholar 

  • Bi XW, Hu RZ, Cornell DH (2001) Trace element and isotope evidence for the evolution of ore-forming fluid of Yao’an gold deposit, Yunnan Province, China. Geochimica 30:264–272 (in Chinese with English abstract)

    Google Scholar 

  • Bi XW, Hu RZ, Peng JT, Wu KX (2004) REE and HFSE geochemical characteristics of pyrites in Yao’an gold deposit: tracing ore forming fluid signatures. Bull Mineral Petrol Geochem 23:1–4 (in Chinese with English abstract)

    Google Scholar 

  • Bi XW, Hu RZ, Peng JT, Wu KX, Su WC, Zhang XZ (2005) Geochemical characteristics of the Yao’an and Machangqing alkaline-rich intrusions. Acta Petrol Sin 21:113–124 (in Chinese with English abstract)

    Google Scholar 

  • Bi XW, Hu RZ, Mungall JE, Hanley JJ, Peng JT, Wu KX, Li HL (2006) Mineral chemistry studies of Cu-and Au-mineralized alkaline intrusions. Acta Mineral Sin 26:377–386 (in Chinese with English abstract)

    Google Scholar 

  • Boynton WV (1984) Geochemistry of the race earth elements: meteorite studies. In: Henderson P (ed) Rare earth element geochemistry. Elsevier, Amsterdam, pp 66–114

    Google Scholar 

  • Cai JH, Yan GH, Mu BL, Ren KX, Li FT, Yang B (2012) Geochronology and geochemistry of Sungezhuang alkaline complex in, Jixian County, Tianjin. J Jilin Univ Earth Sci Edit 41:1901–1913 (in Chinese with English abstract)

    Google Scholar 

  • Cheng J, Xia B, Zhang YQ (2007) Petrological and geochemical characteristics of Yao’an alkaline complex in Yunnan Province. Geotecton Metallog 31:118–125 (in Chinese with English abstract)

    Google Scholar 

  • Chung SL, Lo CH, Lee TY, Zhang YQ, Xie YW, Li XH, Wang LW, Wang PL (1998) Diachronous uplift of the Tibetan plateau starting 40 Myr ago. Nature 394:769–773

    Article  Google Scholar 

  • Collins WJ, Beams SD, White AJR et al (1982) Nature and origin of A-type granites with particular reference to south-eastern Australia. Contrib Mineral Petrol 80:189–200

    Article  Google Scholar 

  • Cornell DH, Schutte SS, Eglington BL (1995) The Ongeluk basaltic andesite formation in Griqualand West South Africa: submarine alteration in a 2222 Ma Proterozoic sea. Precambr Res 79:101–123

    Article  Google Scholar 

  • Cui YL, Chen XS, Zhang YX, He LT (2002) Ore-forming conditions and characteristics of gold deposits related to alkali-rich porphyry in the cenozoic in western Yunnan. Geotecton Metallog 26:404–408 (in Chinese with English abstract)

    Google Scholar 

  • Dewey JF, Shackleton RF, Chang CF, Sun YY (1988) The tectonic evolution of the Tibetan Plateau. In: The geological evolution of Tibet London. The Royal Society Press, pp 379–413

  • Ge LS, Guo XD, Zou YL, Yang JH, Li YJ (2002) Geology and genesis of the Yao’an gold deposit related to alkali-rich. Geol Resour 11:29–37 (in Chinese with English abstract)

    Google Scholar 

  • Ge LS, Zou YL, Xing JB, Wang ZH, Guo XD (2004) Gold mineralization system related to alkali-rich porphyries in Himalayan, the northwestern part of Yunnan. Gold Geol 10:39–47 (in Chinese with English abstract)

    Google Scholar 

  • Hoskin PWO, Schaltgger U (2003) The composition of zircon and igneous and metamorphic petrogenesis. In: Hanchar JM, Hoskin PWO (eds) Mineralogical society of America reviews in mineralogy geochemistry, vol 53 pp 27–62

  • Hou ZQ, Ma HW, Khin Z, Zhang YQ, Wang MJ, Wang Z, Pan GT, Tang RL (2003) The Himalaya Yulong porphyry copper belt: product of large-scale strike-slip faulting in eastern Tibet. Econ Geol 98:125–145

  • Hu X, Huang Z (1997) The petrology and petrogensis of the Yangtze platform western margins alkali-rich granite porphyty. Geotecton Metallog 21:173–180 (in Chinese with English abstract)

    Google Scholar 

  • Jahn BM, Wu FY, Lo CH, Tsai CH (1999) Crust-mantle interaction induced by deep subduction of the continental crust: geochemical and Sr–Nd isotopic evidence from post-collisional mafic-ultramafic intrusions of northern Dabie complex, central China. Chem Geol 157:119–146

    Article  Google Scholar 

  • Ke S, Mo XX, Luo ZH, Zhan HM, Liang T, Li L, Li WT (2006) Petrogenesis and geochemistry of Cenozoic Taxkorgan alkalic complex and its geological significance. Acta Petrol Sin 22:905–915 (in Chinese with English abstract)

    Google Scholar 

  • King PL, White AJR, Chappell BW, Allen CM (1997) Characterization and origin of aluminous A-type granites from the Lachlan Fold space, Southeastern Australia. J Petrol 38:371–391

    Article  Google Scholar 

  • Le Maitre RW, Bateman P, Dudek A, Keller J, Lameyre J, Le Bas MJ, Sabine PA, Schmid R, Sorensen H, Streckisen A, Wooley AR, Zanettin B (1989) A classification of igneous rocks and glossary of terms. Blackwell, Oxford

    Google Scholar 

  • Li HK, Zhu SX, Xiang ZQ, Su WB, Lu SN, Zhou HY, Geng JZ, Li S, Yang FJ (2010) Zircon U–Pb dating on tuffbed from Gaoyuzhuang Formation in Yanqing Beijing: further constraints on the new subdivision of the Mesoproterozoic stratigraphy in the northern North China Craton. Acta Petrol Sin 26:2131–2140 (in Chinese with English abstract)

    Google Scholar 

  • Li Y, Yu XH, Huang XK, He WY (2011) Petrogenesis of alkali rich porphyry of Yao’an Sanjiang in the northwest of Yunnan Province-geochemical and geochronological. Bull Miner Geochem 30:67–68 (in Chinese with English abstract)

    Google Scholar 

  • Liao SP, Chen ZH, Luo XC, Zou AJ (2002) Discovery of leucite phonolite in the Tangra Yumco area, Tibet and its geological significance. Geol Bull China 21:735–738 (in Chinese with English abstract)

    Google Scholar 

  • Liu XF, Cai YW, Lu QX, Tao Z, Zhao FF, Cai FY, Li CH, Song XF (2010) Actual traces of mantle fluid from alkalfrich porphyries in western Yunnan, and associated implications to metallogenesis. Earth Sci Front 17:114–136 (in Chinese with English abstract)

    Google Scholar 

  • Lu BX, Qian XG (2000) Tectonic types of Cenozoic alkalic series mimetic rocks in Sanjiang region, western Yunnan, China. Geol Yunnan 19:232–243 (in Chinese with English abstract)

    Google Scholar 

  • Luo YN, Yu RL (2001) Major features and dynamic model of the Himalayan tectono-magmatism in the intracontinental orogenic space in Longmenshan-Jinpingshan Mountains. In: Ynchuan C et al (eds) Study on Himalayan endogenic mineralization. Seismic Publishing House, Beijing, pp 88–95 (in Chinese)

    Google Scholar 

  • Ma J, Zeng PS, Gou RT, Wang JJ, Dai YJ (2015) Genesis and metallogenesis of alkaline complexes in China mainland. Geol Explor 51:466–477 (in Chinese with English abstract)

    Google Scholar 

  • Maniar PD, Piccoli PM (1989) Tectonic discrimination of granitoids. Geol Soc of Am Bull 101:635–643

  • National Standardization Technical Committee of national land and resources (2010) Petrochemical analytical method of silican rocks (GB/T 14506.30-2010). Standards Press of China, Beijing, pp 1–6; 1–10; 1–14 (in Chinese)

  • Pearce JA, Harris NBW, Tindle AG (1984) Trace element discrimination diagrams for the tectonic interpretation of granitic rocks. J Petrol 24:956–983

    Article  Google Scholar 

  • Philippe P, Jose A (1984) India-Eurask collision chronology has inplications for crustal shortening and driving mechanism of plates. Nature 311:615–621

    Article  Google Scholar 

  • Qian XG, Li ZW (2000) Geologicil and geochemical characteristics of the Yao’an gold ore deposit in centeral Yunnan. Geotecton Metallog 24:31–36 (in Chinese with English abstract)

    Google Scholar 

  • Qiu JS, Wang DZ, Liu H, Ling WL (2002) Post-collisional potash-rich volcanic rocks in the north margin of Dabie orogenic space: geochemistry and petrogenesis. Acta Petrol Sin 18:319–330 (in Chinese with English abstract)

    Google Scholar 

  • Ren KX (2003) Study progress of the alkaline rocks: a review. Geol Chem Miner 25:151–163 (in Chinese with English abstract)

    Google Scholar 

  • Ren T (2011) Geochemistry of the Langdu skarn copper deposit in the Zhongdian region Yunnan Province. Institute of Geochemistry, Chinese Academy of Sciences, Guiyang (in Chinese with English abstract)

  • Rickwood PC (1989) Boundary lines within petrologic diagrams which use oxides of major and minor elements. Lithos 22:247–263

  • Rittmann A (1993) Stable mineral assemblages of igneous mountains. Springer, Heideberg

  • Sun SS, McDonough WF (1989) Chemical and isotopic systematics of oceanic basalts: implication for mantle composition and processes. In: Saunder AD, Norry MJ (eds) Magmatism in the ocean basins. Geological society of special publications, London, pp 313–345

    Google Scholar 

  • Tan XS (1988) Origin and indicator for deposit of Yao’an gold deposit in Yunnan Province. Geol Sci Technol Inf 2:65–76 (in Chinese)

  • Tu GC (1989) On the alkali-rich intrusive rocks. Miner Resour Geol 13:1–4 (in Chinese with English abstract)

    Google Scholar 

  • Tu GC, Zhang YQ, Zhao ZH (1984) A preliminary study on the two alkali-rich intrusive rock spaces in South China. In: Geology of granites and its relations with mineralization. Jiangsu Science and Technology Press, Nanjing, pp 21–37 (in Chinese)

  • Turner S, Arnaud N, Liu J, Rogers N, Hawkesworth C, Harris N, Kelley S, VanCalsteren P, Deng W (1996) Post-collision, shoshonitic volcanism on the Tibetan plateau: implications for convective thinning of the lithosphere and the source of ocean island basalts. J Petrol 37:45–71

  • Whalen JB, Currie KL, Chappell BW (1987) A-type granites: geochemical characteristics, discrimination and petrogenesis. Contrib Mineral Petrol 95:407–419

    Article  Google Scholar 

  • Wu H, Han R, Wu P, He J, Feng XJ, Liang XW, Sun XD (2014) Hydrothermal alteration during diagenesis and reworked periods in the Haojiahe sandstone-type copper deposit, Yunnan, Southwest China: evidence from mass balance calculation of migrated components. Geotecton Metallog 38(04):866–878 (in Chinese with English abstract)

    Google Scholar 

  • Yan H, Zhao ZD, Liu D, Wang Q, Zhu D, Jiang W, Hu ZC, Zheng JP (2013) Geochronology and geochemistry of the Yangbajing leucite porphyry, Tibet: implication for timing of N-S rift. Acta Petrol Sin 29:3731–3744 (in Chinese with English abstract)

    Google Scholar 

  • Yang ZL, Yang SK, Wang C, Yang CH, Dai QH (2007) The geology of Laojiezi Pb deposit and existence of Ag Yao’an Yunnan. Yunnan Geol 26:106–111 (in Chinese with English abstract)

    Google Scholar 

  • Yuvi K (2014) Handbook of mineral resources industry requirements editorial board. Geological Publishing House, Beijing, pp 1–952 (in Chinese)

    Google Scholar 

  • Zeng PS, Yang WG, Yu XH (1999) Alkalic porphyry space in western Yunnan and its relation to gold mineralization. Acta Geosci Sin 20:367–372 (in Chinese with English abstract)

    Google Scholar 

  • Zeng PS, Mo XX, Yu XH (2002) Nd, Sr and Pb isotopic characteristics of the alkaline-rich porphyries in western Yunnan and its compression strike-slip setting. Acta Petrol Mineral 21:231–241 (in Chinese with English abstract)

    Google Scholar 

  • Zhang ZZ (1981) The zonal texture of orthoclase in alkaline rock from Yao’an county, Yunnan Province. Sci Geol Sin 2:171–175 (in Chinese with English abstract)

    Google Scholar 

  • Zhang L (1994) The geology of Laojiezi Pb deposit and existence of Ag Yao’an. Southwest Miner Geol 8:23–31 (in Chinese)

  • Zhang YQ, Xie YW (1997) Geochronology of alkalic intrusive rocks in Jinshajiang–Ailaoshan region and its isotope characteristics of Nd, Sr. Sci China (D) 27:289–293 (in Chinese)

    Google Scholar 

  • Zhang YQ, Xie YW, Tu GC (1987) A preliminary study on the relationship between rift and Jinshajiang–Ailaoshan alkaline intrusive rocks. Acta Petrol Sin 3:17–25 (in Chinese with English abstract)

    Google Scholar 

  • Zhang Z, Huang ZL, Xu C (2002) Sulfur isotope geochemistry of Yao’an gold deposit. Miner Depos (sup) 21:1102–1105 (in Chinese with English abstract)

    Google Scholar 

  • Zhao FF (2012) Evolution of Cenozoic alkaline-rich magma and mantle fluid from Western Yunnan Province and the related metallogenic effect. Chengdu University of Technology, Chengdu, pp 1–197 (in Chinese)

    Google Scholar 

  • Zhao ZH, Qiong XL, Wang Q, Bao Z, Zhang YQ, Xie YW, Ren SK (2003) Alkali-rich igneous rocks and related Au and Cu large and superlarge deposits in China. Sci China (D) 32:1–10 (in Chinese)

    Google Scholar 

  • Zhou JX, Dou S, Huang ZL, Cui YL, Ye L, Li B, Gan T, Sun HR (2016) Origin of the Luping Pb deposit in the Beiya area, Yunnan Province, SW China: constraints from geology, isotope geochemistry and geochronology. Ore Geol Rev 72:179–190

    Article  Google Scholar 

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Acknowledgements

This research was jointly funded by National Natural Science Foundation of China (Grant Number: 41102049), Mineral Resources Prediction and Evaluation Engineering Laboratory of Yunnan Province and the Program of Provincial and University Innovation Team. The authors thank Prof. Tao Ren and Jiasheng Wang, from Kunming University of Science and Technology, and Xiangping Gu, from Central South University for their advice.

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Sun, C., Wu, P., Wang, D. et al. Geochemistry and Zircon U–Pb age of the Yao’an pseudoleucite porphyry, Yunnan Province, China. Acta Geochim 36, 316–328 (2017). https://doi.org/10.1007/s11631-017-0149-3

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