Abstract
The Yarlung Zangbo River Basin (YZRB) is situated in the southern part of the Tibetan Plateau and remains in a mostly natural state. To understand the chemical characteristics of spring water and its controlling factors in the YZRB, 68 sets of spring water samples were analyzed using hydrochemical and isotopic techniques. The spring water was found to be slightly alkaline with total dissolved solids (TDS) below 1000 mg L−1. Major ions were Mg2+, Ca2+, SO42−, and HCO3−. The spring water types in this basin were determined to be HCO3-Ca·Mg and SO4·Cl-Ca·Mg. Ion exchange and dissolution of carbonate, gypsum, and silicate were identified as the prevalent hydrogeochemical processes contributing and defining spring water chemistry in this basin. Saturation indices (SI) of most major minerals studied in this region were below zero, indicating that these minerals remain under-saturated in the spring water in this area. Overall, the rank of different processes in terms of their contribution to the chemical composition of spring water in the YZRB was carbonate weathering > evaporate dissolution > silicate weathering > precipitation input. The content of 18O in spring water ranged from −22.22‰ to −14.08‰ with a mean of −18.15‰. Samples collected below and close to the local and global meteoric water lines indicated that spring water in this area is derived from meteoric water with chemistry affected by evaporation.
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References
Appelo CAJ, Postman D, (2005) Geochemistry, Groundwater and Pollution. 2nd Edition, Balkema, Rotterdam. https://doi.org/10.1201/9781439833544
Bai JK, Li CL, Kang SC, et al. (2014) Chemical speciation and risk assessment of heavy metals in the middle part of Yarlung Zangbo surface sediments. Environ Sci 35(9): 3346–3351. (In Chinese). https://doi.org/10.13227/j.hjkx.2014.09.014
Bozau E, Stärk HJ, Strauch G (2013) Hydrogeochemical characteristics of spring water in the Harz Mountains, Germany. Chem Erde-Geochem 73(3): 283–292. https://doi.org/10.1016/j.chemer.2013.02.002
Galy A, France-Lanord C (1999) Weathering processes in the Ganges-Brahmaputra basin and the riverine alkalinity budget. Chem Geol 159(1–4): 31–60. https://doi.org/10.1016/S0009-2541(99)00033-9
Gao ZY, Wang XD, Yin G (2007) Hydrological rule and isotopic composition of water bodies in Yarlung Zangbo River. Acta Geogr Sinica 62(9): 1002–1007. (In Chinese)
Gibbs RJ (1971) Mechanisms controlling world water chemistry. Science 172(3985): 870–872. https://doi.org/10.1126/science.170.3962.1088
Huang X, Sillanpää M, Gjessing ET, et al. (2011) Water quality in the southern Tibetan Plateau: chemical evaluation of the Yarlung Tsangpo (Brahmaputra). River Res Appl 27(1): 113–121. https://doi.org/10.1002/rra.1332
Huang XA, Sillanpää M, Gjessing ET, et al. (2009) Water quality in the Tibetan Plateau: major ions and trace elements in the headwaters of four major Asian rivers. Sci Total Environ 407(24). https://doi.org/10.1016/j.scitotenv.2009.09.001
IAEA, WMO (2014) Global network of isotopes in precipitation. The GNIP database. https://nucleus.iaea.org/wiser/index.aspx (Accessed on 6 March 2019)
Investigation and Evaluation Report on Groundwater Quality in Key Areas of Qinghai-Tibet Plateau (2015) Center for Hydrogeology and Environmental Geology, China Geological Survey. (In Chinese)
Jia JW, Lv SY, W ZX (2008) Characteristics of water resources in Yarlung Zangbo River Basin. Yangtze River (17). (In Chinese)https://doi.org/10.16232/j.cnki.1001-4179.2008.17.008
Jiang LG, Yao ZJ, Wang R, et al. (2015) Hydrochemistry of the middle and upper reaches of the Yarlung Tsangpo River system: weathering processes and CO2 consumption. Environ Earth Sci 74(3): 2369–2379. https://doi.org/10.1007/s12665-015-4237-6
Kumar MS, Dhakate R, Yadagiri G, et al. (2017) Principal component and multivariate statistical approach for evaluation of hydrochemical characterization of fluoride-rich groundwater of Shaslar Vagu watershed, Nalgonda District, India. Arab J Geosci 10(4): 83. https://doi.org/10.1007/s12517-017-2863-x
Kumar SK, Babu SH, Rao PE, et al. (2017) Evaluation of water quality and hydrogeochemistry of surface and groundwater, Tiruvallur District, Tamil Nadu, India. Appl Water Sci 7(5): 1–12. https://doi.org/10.1007/s13201-016-0447-7
Li PY, Wu JH, Qian H (2016) Hydrochemical appraisal of groundwater quality for drinking and irrigation purposes and the major influencing factors: a case study in and around Hua County, China. Arab J Geosci 9(1): 1–17. https://doi.org/10.1007/s12517-015-2059-1
Li XY, Wu H, Qian H, et al. (2018) Groundwater chemistry regulated by hydrochemical processes and geological structures: a case study in Tongchuan, China. Water 10(3): 338. https://doi.org/10.3390/w10030338
Li ZL, Xu ZX, Gong TL (2008) Characteristics of runoff variation in the Yarlung Zangbo River basin. Geogr Res 27(2): 353–361. (In Chinese)
Liu TC (1999) Hydrological characteristics of Yalungzangbo River. Acta Geogr Sin S1: 157–164. (In Chinese)
Liu JJ, Zhao YS, Huang X, et al. (2018a) Spatiotemporal variations of hydrochemistry and its controlling factors in the Yarlung Tsangpo River. China Environ Sci 38(11). (In Chinese) https://doi.org/10.19674/j.cnki.issn1000-6923.2018.0479
Liu JT, Gao ZJ, Wang M, et al. (2018b) Study on the dynamic characteristics of groundwater in the valley plain of Lhasa City. Environ Earth Sci 77: 646. https://doi.org/10.1007/s12665-018-7833-4
Liu JT, Gao ZJ, Wang M, et al. (2019a) Hydrochemical characteristics and possible controls in the groundwater of the Yarlung Zangbo River Valley, China. Environ Earth Sci 76: 78. https://doi.org/10.1007/s12665-019-8101-y
Liu JT, Gao ZJ, Wang M, et al. (2019b) Stable isotope characteristics of different water bodies in the Lhasa River Basin. Environ Earth Sci 79: 71. https://doi.org/10.1007/s12665-019-8078-6
Liu JT, Wang M, Gao ZJ, et al. (2020b) Hydrochemical characteristics and water quality assessment of groundwater in the Yishu River basin. Acta Geophys 68: 877–889. https://doi.org/10.1007/s11600-020-00440-1
Liu JT, Peng YM, Li CS, et al. (2020a) Characterization of the hydrochemistry of water resources of the Weibei Plain, Northern China, as well as an assessment of the risk of high groundwater nitrate levels to human health. Environ Pollut 268: 115947. https://doi.org/10.1016/j.envpol.2020.115947
Liu Z, Yao Z, Huang H, et al. (2014) Land use and climate changes and their impacts on runoff in the Yarlung Zangbo River Basin, China. Land Degrad Dev 25(3): 203–215. https://doi.org/10.1002/ldr.1159
Manga M (2003) Using springs to study groundwater flow and active geologic processes. Annu Rev Earth Planet Sci 29(9): 201–228. https://doi.org/10.1146/annurev.earth.29.1.201
Ministry of Health (2006a) Standard examination methods for drinking water-Organoleptic and physical parameters, 2006. GB5750.4-2006. Ministry of Health of the People’s Republic of China, Beijing.
Ministry of Health (2006b) Standards for drinking water quality.GB5749-2006. Ministry of Health of the People’s Republic of China, Beijing.
Piper AM (1944) A graphic procedure in the geochemical interpretation of water-analyses. Neurochem Int 6: 27–39. https://doi.org/10.1029/TR025i006p00914
Qian H, Li PY, Wu JH, et al. (2013) Isotopic characteristics of precipitation, surface and ground waters in;the Yinchuan plain, Northwest China. Environ Earth Sci 70(1): 57–70. https://doi.org/10.1007/s12665-012-2103-3
Wang LH, Dong YH, Xu ZF, et al. (2017) Hydrochemical and isotopic characteristics of groundwater in the northeastern Tennger Desert, northern China. Hydrogeol Journal 25: 2363–2375. https://doi.org/10.1007/s10040-017-1620-2
Wu H, Chen J, Qian H, et al. (2015) Chemical Characteristics and Quality Assessment of Groundwater of Exploited Aquifers in Beijiao Water Source of Yinchuan, China: A Case Study for Drinking, Irrigation, and Industrial Purposes. J Chem 2015: 1–14. https://doi.org/10.1155/2015/726340
Wu JH, Li PY, Qian H (2015) Hydrochemical characterization of drinking groundwater with special reference to fluoride in an arid area of China and the control of aquifer leakage on its concentrations. Environ Earth Sci 73(12): 8575–8588. https://doi.org/10.1007/s12665-015-4018-2
Xiao J, Jin ZD, Wang J, et al. (2015). Hydrochemical characteristics, controlling factors and solute sources of groundwater within the Tarim River Basin in the extreme arid region, NW Tibetan Plateau. Quatern Int 380–381(5): 237–246. https://doi.org/10.1016/j.quaint.2015.01.021
Xiao J, Jin ZD, Zhang F (2013) Geochemical and isotopic characteristics of shallow groundwater within the Lake Qinghai catchment, NE Tibetan Plateau. Quatern Int 313–314: 62–73. https://doi.org/10.1016/j.quaint.2013.05.033
Xiao J, Jin ZD, Zhang F, et al. (2012) Solute geochemistry and its sources of the groundwaters in the Qinghai Lake catchment, NW China. J Asian Earth Sci 52(4): 21–30. https://doi.org/10.1016/j.jseaes.2012.02.006
Xiao J, Zhang F, Jin ZD (2016) Spatial characteristics and controlling factors of chemical weathering of loess in the dry season in the middle Loess Plateau, China: In the middle Loess Plateau, China. Hydrol Process 30(25): 4855–4869. https://doi.org/10.1002/hyp.10959
Xing LT, Huang LX, Hou XY, et al. (2018) Groundwater hydrochemical zoning in inland plains and its genetic mechanisms. Water 10(6): 752. https://doi.org/10.3390/w10060752
Yuan YY, Liu YL, Luo KL, et al. (2020) Hydrochemical characteristics and a health risk assessment of the use of river water and groundwater as drinking sources in a rural area in Jiangjin District, China. Environ Earth Sci 79(7): 160. https://doi.org/10.1007/s12665-020-8900-1
Yurteri C, Simsek S (2017) Hydrogeological and hydrochemical studies of the Kaman-Savcili-Büyükoba (Kirsehir) geothermal area, Turkey. Geothermics 65: 99–112. https://doi.org/10.1016/j.geothermics.2016.09.002
Zega M, Rožič B, Gaberšek M, et al. (2015) Mineralogical, hydrogeochemical and isotopic characteristics of the Žveplenica sulphide karstic spring (Trebuša Valley, NW Slovenia). Environ Earth Sci 74(4): 1–14. https://doi.org/10.1007/s12665-015-4357-z
Zghibi A, Tarhouni J, Zouhri L (2013) Assessment of seawater intrusion and nitrate contamination on the groundwater quality in the Korba coastal plain of Cap-Bon (North-east of Tunisia). J Afr Earth Sci 87: 1–12. https://doi.org/10.1016/j.jafrearsci.2013.07.009
Zhai YZ, Wang JS, Teng YG, et al. (2011) Hydrochemical and isotopic characteristics of springs in Beijing and their implications. Geol Bull China 30(9): 1442–1449. (In Chinese)
Zhai YZ, Wang JS, Zhang BT, et al. (2014) Physical, hydrochemical and isotopic characteristics of springs in Beijing, China, compared to historical properties. J Radioanal Nucl Chem 300(1): 315–323. https://doi.org/10.1007/s10967-014-3018-0
Zhang YL, Sillanpää M, Li CL, et al. (2015) River water quality across the Himalayan regions: elemental concentrations in headwaters of Yarlung Tsangbo, Indus and Ganges River. Environ Earth Sci 73(8): 4151–4163. https://doi.org/10.1007/s12665-014-3702-y
Acknowledgements
This research was supported by the Center for Hydrogeology and Environmental Geology Survey, China Geological Survey (112120114059601, DD20160298, 2019QZKK020703, KKLFSE201304) and the China Postdoctoral Science Foundation (2020M682207). Meanwhile, we thank the anonymous reviewers and editors for their useful comments, which helped improve the manuscript.
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Li, Yz., Gao, Zj., Liu, Jt. et al. Hydrogeochemical and isotopic characteristics of spring water in the Yarlung Zangbo River Basin, Qinghai-Tibet Plateau, Southwest China. J. Mt. Sci. 18, 2061–2078 (2021). https://doi.org/10.1007/s11629-020-6625-y
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DOI: https://doi.org/10.1007/s11629-020-6625-y