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Effect of E-44 Epoxy Resin and Pyrolysis Temperature on the Adhesion Strength of SiBCN Ceramic

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Abstract

An adhesive of the SiBCN ceramic was synthesized through the polymer derived ceramics (PDC) route. Meanwhile with higher adhesion strength and simpler process condition, the polyborosilazane (PSNB) was modified by E-44 epoxy resin. The E-44 epoxy resin was used to promote the oxidation process of SiBCN, in other words, to produce more amount of SiO2-B2O3 glasses. The phase composition, elemental analysis, chemical bonds and microstructure were investigated by using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) measurements. The E-44 modified adhesives were cured at 120 °C in air for 2 h, and were pyrolyzed at 1 200, 1 400, and 1 500 °C for 2 h in air, respectively. The highest adhesion strength of the modified adhesive was up to 5.33, 12.23, and 12.50 MPa after being heat treated at 1 200, 1 400, and 1 500 °C, respectively. Finally, we proposed an adhesion model and revealed the adhesion mechanism of SiBCN ceramic.

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Authors and Affiliations

  1. Shaanxi Key Lab of MEMS/NEMS, Northwestern Polytechnical University, Xi’an, 710072, China

    Zhibo Ma  (马志波)

  2. Department of Environment Engineering and Technology, China Institute for Radiation Protection, Taiyuan, 030006, China

    Sen Chang  (常森), Xuemei Song, Kunjun Wang & Yongguo Li

  3. Key Lab of Micro/Nano Systems for Aerospace, Ministry of Education, Xi’an, 710072, China

    Min Li

  4. Science and Technology on Thermo Structural Composite Materials Laboratory, Northwestern Polytechnical University, Xi’an, 710072, China

    Sen Chang  (常森), Xinming Xu, Qiqi Zhang, Lei Wang, Rong Yu, Xin’gang Luan & Laifei Cheng

Authors
  1. Zhibo Ma  (马志波)
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  2. Sen Chang  (常森)
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  3. Xuemei Song
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  4. Min Li
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  5. Kunjun Wang
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  6. Yongguo Li
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  7. Xinming Xu
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  8. Qiqi Zhang
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  9. Lei Wang
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  10. Rong Yu
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  11. Xin’gang Luan
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  12. Laifei Cheng
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Corresponding author

Correspondence to Sen Chang  (常森).

Additional information

MA Zhibo and CHANG Sen contributed equally to this work

Funded by the Research Fund of the National Key Research and Development Program of China (No. 2017YFB0703200), the State Key Laboratory of Solidification Processing (NWPU), China (No. 135-QP-2015), and the Fundamental Research Funds for the Central Universities (No. 3102017zy058)

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Ma, Z., Chang, S., Song, X. et al. Effect of E-44 Epoxy Resin and Pyrolysis Temperature on the Adhesion Strength of SiBCN Ceramic. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 35, 81–86 (2020). https://doi.org/10.1007/s11595-020-2230-8

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  • DOI: https://doi.org/10.1007/s11595-020-2230-8

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