Skip to main content
Log in

Formation of Zr-contained Amorphous Alloy Films by Magnetron Co-sputtering

  • Metallic Materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

In order to explore the application of magnetron co-sputtering in fabricating the amorphous alloy, Zr-contained amorphous films were prepared by this technique and investigated by scanning electron microscope, energy disperse spectroscopy and X-ray diffraction. The results show that the co-sputtered films are in fully amorphous state or with amorphous-nanocrystalline structure. The XRD patterns of the Zr-Cu and Zr-Ni amorphous films exhibit a double-peak phenomenon. There is a shift of diffusive peak with changing the sputtering current which is possibly attributed to the change of Zr-Ni and Zr-Cu intermetallic like short range orders. In addition, Zr-Cu-Ni ternary co-sputtered films have a sharper peak at high angle. The sputtering yield of element during co-sputtering ranks as Cu>Ni>Zr, which can be ascribed to the contribution of melting and boiling temperature, atomic size and electrical conductivity of elements.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Inoue A. Stabilization of Metallic Supercooled Liquid and Bulk Amorphous Alloys[J]. Acta Materialia, 2000, 48: 279–306

    Article  Google Scholar 

  2. Johnson W L. Bulk Amorphous Metal-An Emerging Engineering Material[J]. JOM-Journal of the Minerals Metals & Materials Society, 2002, 54: 40–43

    Article  Google Scholar 

  3. Schultz L, Eckert J. Glassy Metals III[M]. Berlin: Springer Varlag, 1994

    Google Scholar 

  4. Guo L Y, Geng S N, Pang J, et al. Structural Transformation and Property Improvement of Fe78Si9B13 Amorphous Ribbon by Pulsed Laser Processing[J]. Materials & Design, 2018, 160: 538–548

    Article  Google Scholar 

  5. Jia C G, Pang J, Pan S P, et al. Tailoring the Corrosion Behavior of Fe-based Metallic Glasses through Inducing Nb-triggered Netlike Structure[J]. Corrosion Science, 2019, 147: 94–107

    Article  Google Scholar 

  6. Wang X, Pang J, Guo L Y, et al. Thermal Analysis of Directional Pressure Annealed Fe78Si9B13 Amorphous Ribbons[J]. Thermochimica Acta, 2018, 661: 67–77

    Article  Google Scholar 

  7. Ristič R, Stubičar M, Babić E. Correlation between Mechanical, Thermal and Electronic Properties in Zr-Ni, Cu Amorphous Alloys[J]. Philosophical Magazine, 2007, 87: 5 629–5 637

    Article  Google Scholar 

  8. Basu J, Murty B S, Ranganathan S. Glass Forming Ability: Miedema Approach to (Zr, Ti, Hf)-(Cu, Ni) Binary and Ternary Alloys[J]. Journal of Alloys and Compounds, 2008, 465: 163–172

    Article  Google Scholar 

  9. Chen C J, Huang J C, Chou H S, et al. On the Amorphous and Nanocrystalline Zr-Cu and Zr-Ti Co-sputtered Thin Films[J]. Journal of Alloys and Compounds, 2009, 483: 337–340

    Article  Google Scholar 

  10. Jing Q, Xu Y, Zhang X Y, et al. Zr-Cu Amorphous Films Prepared by Magnetron Co-sputtering Deposition of Pure Zr and Cu[J]. Chinese Physics Letters, 2009, 26: 086 109–086 112

    Article  Google Scholar 

  11. Marshall A F, Walmsley R G, Stevenson D A. Crystallization of an Amorphous Cu88Zr20 Alloy Prepared by Magnetron Sputter Deposition[J]. Materials Science and Engineering, 1984, 63: 215–227

    Article  Google Scholar 

  12. Luo S, Yan B X, Shen J. Enhanced Photoelectric Property of Mo-C Codoped TiO2 Films Deposited by RF Magnetron Cosputtering[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2017, 32: 223–228

    Article  Google Scholar 

  13. Li B J, Huang L J, Zhou M, et al. Preparation and Spectral Analysis of Gold Nanoparticles using Magnetron Sputtering and Thermal Annealing[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2014, 29: 651–655

    Article  Google Scholar 

  14. Liu C Y, He F, Yan N N, et al. Influence of Deposition Pressure on Properties of ZnO: Al Films Fabricated by RF Magnetron Sputtering[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2016, 31: 1 235–1 239

    Article  Google Scholar 

  15. Swann S. Magnetron Sputtering[J]. Physics in Technology, 1988, 19: 67

    Article  Google Scholar 

  16. Zalnezhad E. Effect of Structural Evolution on Mechanical Properties of ZrO2 Coated Ti-6Al-7Nb-biomedical Application[J]. Applied Surface Science, 2016, 370: 32–39

    Article  Google Scholar 

  17. Baradaran S, Zalnezhad E, Basirun W J, et al. Statistical Optimization and Fretting Fatigue Study of Zr/ZrO2 Nanotubular Array Coating on Ti-6Al-4V[J]. Surface and Coatings Technology 2014, 258: 979–990

    Article  Google Scholar 

  18. Carcia P F, McLean R S, Reilly M H, et al. Transparent ZnO Thin-film Transistor Fabricated by RF Magnetron Sputtering[J]. Applied Physics Letters, 2003, 82: 1 117–1 119

    Article  Google Scholar 

  19. Dudonis J, Brucas R, Miniotas A. Synthesis of Amorphous Zr-Cu Alloys by Magnetron Co-sputtering[J]. Thin Solid Films, 1996, 275: 164–167

    Article  Google Scholar 

  20. Xu Y. Study on the Preparation and Crystallization Process of Zr-Cu Amorphous Alloy Thin Films[D]. Qinghuangdao: Yanshan University, 2005

    Google Scholar 

  21. Li Y, Guo Q, Kalb J A, et al. Matching Glass-Forming Ability with the Density of the Amorphous Phase[J]. Science, 2008, 322: 1 816–1 819

    Article  Google Scholar 

  22. Chou H S, Huang J C, Lai Y H, et al. Amorphous and Nanocrystalline Sputtered Mg-Cu Thin Films[J]. Journal of Alloys and Compounds, 2009, 483: 341–345

    Article  Google Scholar 

  23. Miyazaki H. Fabrication of YbAl 3 Film via Annealing Amorphous Yb-Al Film Deposited by RF Magnetron Sputtering[J]. Vacuum, 2008, 83: 416–418

    Article  Google Scholar 

  24. Mattern N, Kühn U, Gebert A, et al. Microstructure and Thermal Behavior of Two-phase Amorphous Ni-Nb-Y Alloy[J]. Scripta Materialia, 2005, 53: 271–274

    Article  Google Scholar 

  25. Antonian Z, Tu G H, Strom-Olsen J O. Crystallization Characteristics of Ni-Zr Metallic Glasses from Ni20Zr80 to Ni70Zr30[J]. Journal of Applied Physics, 1983, 54: 3 111–3 116

    Article  Google Scholar 

  26. Sigmund P. Theory of Sputtering. I. Sputtering Yield of Amorphous and Polycrystalline Targets[J]. Physical Review, 1969, 184: 383–315

    Article  Google Scholar 

  27. Dean J A. Lange’s Handbook of Chemistry[M]. New York: McGraw-Hill, Inc., 1999

    Google Scholar 

Download references

Acknowledgement

The authors are grateful to Prof. Xiaolin Wang from University of Wollongong for his valuable discussions and assistance in the present paper.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Weimin Wang  (王伟民).

Additional information

Funded by Shandong Government Financial Supporting (No. L37002013098), Jinan Government Financial Supporting (Nos. JK201303067 and 301305033) and the National Natural Science Foundation of China (Nos. 51771103, 51471099 and 51571132)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Niu, Y., Guo, L., Zheng, Y. et al. Formation of Zr-contained Amorphous Alloy Films by Magnetron Co-sputtering. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 34, 662–667 (2019). https://doi.org/10.1007/s11595-019-2101-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-019-2101-3

Key words

Navigation