Skip to main content
Log in

EXAFS studies on local atomic structure in the amorphous Mg65Cu25Gd10 alloy

  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

Local atomic structures of an amorphous Mg65Cu25Gd10 alloy and the structural changes by thermal annealing have been studied by extended X-ray absorption fine structure (EXAFS). The correlation between structural changes and mechanical properties for the Mg65Cu25Gd10 alloy has also been discussed. Results showed that Cu atoms around Gd in Mg65Cu25Gd10 lost rapidly during annealing, resulting in the segregation of Cu atoms. The coordination number NGd-Mg of Mg65Cu25Gd10 annealed at 373 K first diminished and then augmented with the increase of annealing time. The formation of polyhedral short-range order unit with coordination number of nearly 12 around Gd atoms is in favor of the improvement of mechanical properties. The chemical short-range order, not topological short-range order in the amorphous Mg65Cu25Gd10 alloy had obvious changes during annealing.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A Inoue, T Nakamura, N Nishiyama, et al. Mg-Cu-Y Bulk Amorphous Alloys with High Tensile Strength Produced by a High-pressure Die Casting Method[J]. Materials Transactions JIM, 1992, 33(10): 937–945

    CAS  Google Scholar 

  2. A Inoue, M Kohinata, A P Tsai, et al. Mg-Ni-La Amorphous Alloys with a Wide Supercooled Liquid Region[J]. Materials Transactions JIM, 1989, 30(5): 378–381

    CAS  Google Scholar 

  3. S G Kim, A Inoue, T Masumoto. High Mechanical Strenths of Mg-Ni-Y and Mg-Cu-Y Amorphous Alloys with a Wide Supercooled Liquid Region[J]. Materials Transactions JIM, 1990, 31(11): 929–934

    CAS  Google Scholar 

  4. E Matsubara, T Tamura, Y Waseda, et al. Structural Study of Amorphous Mg50Ni30La20 Alloy by the Anomalous X-ray Scattering (AXS) Method[J]. Materials Transactions JIM, 1990, 31(3): 228–231

    CAS  Google Scholar 

  5. S V Madge, D T L Alexander, A L Greer. An EFTEM Study of Compositional Variations in Mg-Ni-Nd Bulk Metallic Glasses[J]. Journal of Non-Crystalline Solids, 2003, 317(1–2): 23–29

    Article  CAS  Google Scholar 

  6. U Mizutani, H Sugiura, Y Yamada, et al. Electronic Structure and Electron Transport Properties of Al-Cu-Y and Mg-Cu-Y Amorphous Alloys[J]. Materials Science Engineerng A, 1994, 179–180: 132–136

    Article  Google Scholar 

  7. U Mizutani, K Tanaka, T Matsuda, et al. Electronic Structure and Electron Transport Properties Amorphous Mg-Ni-La and Mg-Cu-Y Alloys[J]. Journal of Non-Crystalline Solids, 1993, 156–158: 297–301

    Article  Google Scholar 

  8. M K Miller, K F Russell, P M Martin, et al. Characterization of Bulk Metallic Glasses with the Atom Probe[J]. Journal De Physique IV Colloque C5, supplément au Journal de Physique III, septembre 1996, 6: C5-217–C5-222

    Google Scholar 

  9. M Matsuura, M Sakurai, K Amiya, et al. Local Structures Around Zn and Y in the Melt-Quenched Mg97Zn1Y2 Ribbon[ J]. Journal of Alloys and Compounds, 2003, 353: 240–245

    Article  CAS  Google Scholar 

  10. H Men, D H Kim. Fabrication of Ternary Mg-Cu-Gd Bulk Metallic Glass with High Glass-Forming Ability Under Air Atmosphere[J]. J. Mater. Res., 2003, 18: 1 502–1 504

    Article  CAS  Google Scholar 

  11. G Y Yuan, A Inoue. The Effect of Ni Substitution on the Glass-Forming Ability and Mechanical Properties of Mg-Cu-Gd Metallic Glass Alloys[J]. J. Alloys Compd., 2005, 387: 134–138

    Article  CAS  Google Scholar 

  12. G Q Li, Q Cai, H X Li, et al. Structure Relaxation of Mg65Cu25Gd10 Metallic Glass and Its Effect on Strength[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2009, 24(2): 210–213

    Article  CAS  Google Scholar 

  13. G Q Li, Z F Zhang, H X Li. EXAFS Analysis of Short-range Rearrangement during Crystallization in Mg65Cu25Gd10 Metallic Glass[J]. Rare Metal Materials and Engineering, 2007, 36(12): 2 132–2 135

    CAS  Google Scholar 

  14. C K Lin, C C Wang, R R Jeng, et al. Preparation and Thermal Stability of Mechanically Alloyed Ni-Zr-Ti-Y Amorphous Powders[J]. Intermetallics, 2004, 12(7–9): 1 011–1 017

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Guoqiang Li  (李国强).

Additional information

Funded by National 863 Program (No. 2003AA305071) and For Ying Tong Education Foundation(No.114014)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, G., Zheng, L., Cai, Q. et al. EXAFS studies on local atomic structure in the amorphous Mg65Cu25Gd10 alloy. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 26, 98–101 (2011). https://doi.org/10.1007/s11595-011-0176-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-011-0176-6

Key words

Navigation