Abstract
Solid polymer electrolyte films based on hydroxypropyl methylcellulose (HPMC) complexed with sodium iodide (NaI) were prepared using solution cast method. The dissolution of the salt into the polymer host and the structural properties of pure and complexed HPMC polymer electrolyte films were confirmed by X-ray diffraction (XRD) studies. XRD results revealed that the amorphous domains of HPMC polymer matrix were increased with increase in NaI salt concentration. The degree of crystallinity was found to be high in pure HPMC samples. The thermal properties were studied using differential scanning calorimetry (DSC). DSC results revealed that the presence of NaI in the polymer matrix increases the melting temperature; however, it is observed that fusion heat is high for pure HPMC films. The variation of film morphology was examined by scanning electron microscopy. Fourier transform infrared spectral studies revealed vibrational changes that occurred due to the effect of dopant salt in the polymer. Direct current conductivity was measured in the temperature range of 313–383 K. The magnitude of electrical conductivity was found to increase with the increase in salt and temperature concentration. The data on the activation energy regions (regions I and II) indicated the dominance of ion-type charge transport in these polymer electrolyte films. The composition HPMC:NaI (5:4) is found to exhibit the least crystallinity and the highest conductivity.
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References
Armand MB (1993) Solid State Ion 9/10:745
Papke BL, Ratner, Shriver DF (1992) J Electrochem Soc 129:1694
Berthier C, Gorecki W, Miner M, Amand MB, Chabagno JM, Riguad P (1983) J Solid State Ion 11:91
Armand MB (1986) Annu Rev Mater Sci 16:245–261
Jaipal Reddy M, Chu PP (2002) Electrochim Acta 47:1189–1196
Reitman EA, Kaplan ML, Kava RJ (1985) J Solid State Ionics 17:67
Mclin M, Angell CA (1992) J Solid State Ionics 56:1027
Lee YL, Crist BJ (1986) J Appl Phys 60:2683
Lascaud S, Perrier M, Vallee A, Besner S, Prud home J, Armand M (1994) Macromolecules 27:7469
Balaki Bhargav P, Madhu Mohan V, Sharma AK, Rao VVRN (2007) J Ionics 13:173–178
Mohammad Saleem Khan, Abdul Shakur (2010) J Ionics 16:539–542
Tarascon JM, Armand M (2001) Issues and challenges facing rechargeable lithium batteries. Nature 414:359–367
Subba Reddy CV, Jin AP, Zhu QY, Mai LQ, Chen W (2006) Eur Phys 19:471
Anantha PS, Hariharn K (2003) J Phys Chem Solids 64:1131
Sreekanth Reddy T, Jaipal Reddy M, Ramalingaiah S, Subbarao UV (1999) J Power Sources 79:105
Greenbaum SG, Pak YS, Wintersgill MC, Fontanella JJ, Schultz JW (1988) J Electrochem Soc 135:235
Sreepathi Rao S, Jaipal Reddy M, Laxmi Narsaiah E, Subba Rao UV (1995) Mater Sci Eng B 33:173
Tripathi SK (2012) Bull Mater Sci Indian Acad Sci 35(6):969–975
S. Honary, P. Ebrahimi, N. Emrani (2010) Int J Pharma Bio Sci l(2)
Hardy IJ, Cook WG, Melia CDS (2006) Compression and compaction properties of plasticized high molecular weight hydroxypropyl methylcellulose (HPMC) as a hydrophilic matrix carrier. Inter J Pharm 311(1–2):26–32
Hunter CC, Ingram MD (1984) Solid State Ionics 14:31
Bruce PG, Vincent CA (1993) J Chem Soc Faraday Trans 89:3187–3203
Madhu Mohan V, Raja V, Sharma AK, Narasimha Rao VVRN (2004) J Mater Chem Phys 94:177
Hermans PH, Weidinger A (1961) Makromol Chem 24:44
Sangappa, Demappa et al (2008) Nucl Instr Meth Phys Res B 266:3975–3980
Zhang S, Lee JY, Hong L (2004) J Power Sources 115:288
Chu PP, Reddy MJ (2003) J Power Sources 115:288
Subba Reddy CHV, Sharma AK, Narasimha Rao VVR (2006) J Polymer 47:1318
Bhide A, Hariharan K (2006) J Power Sources 159(2):1450
HiranKumar G, Selvasekarapandian S, Kuwata N, Kawamura J, Hattori T (2005) J Power Sources 144:262
Balaji Bhargav P, Mahy Mohan V, Sharma AK, Rao VVRN (2007) J Ionics 13:173–178
Chakraborty G et al (2011) J Solid State Commun 151:754–758
Janaki Rami Reddy T, Achari VBS, Sharma AK, Rao VVRN (2007) Ionics 13:435–439
Devendrappa H, Subba Rao UV, Ambika Prasad MVN (2006) J Power Sources 155(2):368
Michael MS, Jacob MME, Prabhaharan SRS, Radhakrishnan S (1997) Solid State Ion 98:167
Acknowledgments
The authors acknowledge all the support and the useful discussion by Professor Srikantaiah, Retired Scientist, BARC, Mumbai. We are thankful to the technical staff at SID and Material Science Department, IISc, Bangalore for DSC, FTIR, and SEM analysis. We thank Grian Technologies Pvt. Limited, Bangalore for their support in electrical conductivity studies. Special thanks to Dr Shibu M Eappen, Scientist in Charge, SAIF Cochin University of Science and Technology, Cochin, for XRD measurements.
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Rani, N.S., Sannappa, J., Demappa, T. et al. Structural, thermal, and electrical studies of sodium iodide (NaI)-doped hydroxypropyl methylcellulose (HPMC) polymer electrolyte films. Ionics 20, 201–207 (2014). https://doi.org/10.1007/s11581-013-0952-8
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DOI: https://doi.org/10.1007/s11581-013-0952-8