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Molecular structure of poly(siloxaneimide) films and the rate of charge relaxation

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Abstract

The length of the thermodynamically flexible siloxane block of the macromolecules under study is shown to affect the rate of relaxation of charge buildup by corona discharge in thin polymer films. The experimental evidence is interpreted in terms of appearance of energy states with energies close to the Fermi level of metals owing to the electrization effect.

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Authors and Affiliations

  1. Ioffe Physicotechnical Institute, Russian Academy of Sciences, Politekhnicheskaya ul. 26, St. Petersburg, 194021, Russia

    A. N. Ionov & O. F. Pozdnyakov

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31, St. Petersburg, 199004, Russia

    M. N. Nikolaeva & V. M. Svetlichnyi

  3. Institut für Experimentalphysik, Freie Universität Berlin, 14195, Berlin, Germany

    R. Rentzsch

  4. St. Petersburg State Polytechnical University, Politekhnicheskaya ul. 29, St. Petersburg, 195251, Russia

    M. E. Borisova & O. V. Galyukov

Authors
  1. A. N. Ionov
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  2. M. N. Nikolaeva
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  3. O. F. Pozdnyakov
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  4. V. M. Svetlichnyi
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  5. R. Rentzsch
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  6. M. E. Borisova
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  7. O. V. Galyukov
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Correspondence to A. N. Ionov.

Additional information

Original Russian Text © A.N. Ionov, M.N. Nikolaeva, O.F. Pozdnyakov, V.M. Svetlichnyi, R. Rentzsch, M.E. Borisova, O.V. Galyukov, 2008, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2008, Vol. 50, No. 2, pp. 286–294.

This work was supported by the program of Basic Research of the Division of Chemistry and Materials Sciences, Russian Academy of Sciences, “Creation and Study of Macromolecular Structures for Macromolecular Electronics,” the program of the Presidium of the Russian Academy of Sciences “Quantum Nanostructures,” and the program of the St. Petersburg Scientific Center, Russian Academy of Sciences “New Materials.”

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Ionov, A.N., Nikolaeva, M.N., Pozdnyakov, O.F. et al. Molecular structure of poly(siloxaneimide) films and the rate of charge relaxation. Polym. Sci. Ser. A 50, 174–180 (2008). https://doi.org/10.1007/s11498-008-2012-0

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  • DOI: https://doi.org/10.1007/s11498-008-2012-0

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