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Mechanical properties of vanadium-alloyed austempered ductile iron for crankshaft applications

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Abstract

This study focused on the development of austempered ductile iron (ADI) with desirable combination of mechanical properties for crankshaft applications by the combined effect of vanadium (V) alloying and an optimized heat treatment process. The produced unalloyed GGG60, 0.15% V-alloyed GGG60 (V-15), and 0.30% V-alloyed GGG60 samples were subjected to austenitizing at 900 °C for 1 h and subsequent austempering processes at 250, 300, and 350 °C for 15, 30, 60, 90, and 180 min. As a result of these austempering processes, different bainitic structures were obtained, which led to the formation of diverse combinations of mechanical properties. The mechanical properties of the austempered samples were tested comprehensively, and the results were correlated with their microstructures and the stability of the retained austenite phases. From the microstructural observations, the V-alloyed samples exhibited a finer microstructure and a more acicular ferrite phase than unalloyed samples. The V addition delayed the coarsening of the acicular ferrite structures and considerably contributed to the improvement of the mechanical properties of GGG60. Moreover, the X-ray diffraction results revealed that the retained austenite volume and the carbon enrichment of austenite phases in ADI samples were remarkably affected by the addition of vanadium. The increase in volume fraction of retained austenite and its carbon content provided favorable ductility and toughness to V-15, as confirmed by the elongation and impact test results. Consequently, the dual-phase ausferrite microstructure of V-15 that was austempered at 300 °C for 60 min exhibited high strength with substantial ductility and toughness for crankshaft applications.

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References

  1. Putatunda S K, Gadicherla P K. Influence of austenitizing temperature on fracture toughness of a low manganese austempered ductile iron (ADI) with ferritic as cast structure. Materials Science and Engineering: A, 1999, 268(1–2): 15–31

    Article  Google Scholar 

  2. Du Y Z, Gao X Q, Wang X L, Wang X, Ge Y F, Jiang B L. Tribological behavior of austempered ductile iron (ADI) obtained at different austempering temperatures. Wear, 2020, 456–457: 203396

    Article  Google Scholar 

  3. Kiani-Rashid A R. The bainite transformation and the carbide precipitation of 4.88% aluminium austempered ductile iron investigated using electron microscopy. Journal of Alloys and Compounds, 2009, 474(1–2): 490–498

    Article  Google Scholar 

  4. Meier L, Hofmann M, Saal P, Volk W, Hoffmann H. In-situ measurement of phase transformation kinetics in austempered ductile iron. Materials Characterization, 2013, 85: 124–133

    Article  Google Scholar 

  5. Cui J J, Chen L Q. Microstructure and abrasive wear resistance of an alloyed ductile iron subjected to deep cryogenic and austempering treatments. Journal of Materials Science and Technology, 2017, 33(12): 1549–1554

    Article  Google Scholar 

  6. Keough J R, Hayrynen K L. Automotive Applications of Austempered Ductile Iron (ADI): A Critical Review. SAE Technical Paper 2000-01-0764, 2000

  7. Nallicheri N V, Clark J P, Field F R. Material Alternatives for the Automotive Crankshaft; A Competitive Assessment Based on Manufacturing Economics. SAE Technical Paper 910139, 1991

  8. Zhang H, Wu Y X, Li Q J, Hong X. Mechanical properties and rolling-sliding wear performance of dual phase austempered ductile iron as potential metro wheel material. Wear, 2018, 406–407: 156–165

    Article  Google Scholar 

  9. Asai T, Takitani Y, Sano N, Matsumoto H. Strength enhancement of nitrocarburized crankshaft material. SAE International Journal of Materials and Manufacturing, 2009, 1(1): 204–210

    Article  Google Scholar 

  10. Vijaya Ramnath B, Elanchezhian C, Jeykrshnan J, Ragavendar R, Rakesh P K, Dhamodar J S, Danasekar A. Implementation of reverse engineering for crankshaft manufacturing industry. Materials Today: Proceedings, 2018, 5(1): 994–999

    Google Scholar 

  11. Citti P, Giorgetti A, Millefanti U. Current challenges in material choice for high-performance engine crankshaft. Procedia Structural Integrity, 2018, 8: 486–500

    Article  Google Scholar 

  12. Development of austempered ductile iron (ADI) for automobile crankshafts. Journal of Materials Engineering and Performance, 2013, 22(10): 2795–2800

  13. Bahmani M, Elliott R, Varahram N. Austempered ductile iron: a competitive alternative for forged induction-hardened steel crankshafts. International Journal of Cast Metals Research, 1997, 9(5): 249–257

    Article  Google Scholar 

  14. Liu Y, Barber G C, Wang B. Influence of shot-peening on wear resistance of austempered and quench-tempered ductile irons. Physics of Metals and Metallography, 2020, 121(14): 1478–1485

    Article  Google Scholar 

  15. Brandenberg K R, Ravenscroft J, Rimmer A, Hayrynen K L. An ADI Crankshaft Designed for High Performance in TVR’s Tuscan Speed Six Sports Car. SAE Technical Paper 2001-01-0408, 2001

  16. Aranzabal J, Gutierrez I, Rodriguez-Ibabe J M, Urcola J J. Influence of the amount and morphology of retained austenite on the mechanical properties of an austempered ductile iron. Metallurgical and Materials Transactions A, 1997, 28(5): 1143–1156

    Article  Google Scholar 

  17. Sellamuthu P, Samuel D G H, Dinakaran D, Premkumar V P, Li Z, Seetharaman S. Austempered ductile iron (ADI): influence of austempering temperature on microstructure, mechanical and wear properties and energy consumption. Metals, 2018, 8(1): 53

    Article  Google Scholar 

  18. Basso A, Martínez R, Sikora J. Influence of chemical composition and holding time on austenite (γ) → ferrite (α) transformation in ductile iron occurring within the intercritical interval. Journal of Alloys and Compounds, 2011, 509(41): 9884–9889

    Article  Google Scholar 

  19. Ławrynowicz Z, Dymski S. Analysis of carbon partitioning during ausferritic reaction in ADI. Archives of Foundry Engineering, 2008, 8(3): 69–74

    Google Scholar 

  20. Zimba J, Simbi D J, Navara E. Austempered ductile iron: an alternative material for earth moving components. Cement and Concrete Composites, 2003, 25(6): 643–649

    Article  Google Scholar 

  21. Mallia J, Grech M, Smallman R E. Effect of silicon content on transformation kinetics of austempered ductile iron. Materials Science and Technology, 1998, 14(5): 452–460

    Article  Google Scholar 

  22. Kim Y J, Shin H, Park H, Lim J D. Investigation into mechanical properties of austempered ductile cast iron (ADI) in accordance with austempering temperature. Materials Letters, 2008, 62(3): 357–360

    Article  Google Scholar 

  23. de Souza B V, Ribeiro T M, Francois A, dos Santos C A. Austempering heat treatments of ductile iron using molten metal baths. Materials and Manufacturing Processes, 2018, 33(15): 1667–1673

    Article  Google Scholar 

  24. Chang L C. Carbon content of austenite in austempered ductile iron. Scripta Materialia, 1998, 39(1): 35–38

    Article  Google Scholar 

  25. Bosnjak B, Asanovic V, Radulovic B, Pop-Tonev K. Influence of microalloying and heat treatment on the kinetics of bainitic reaction in austempered ductile iron. Journal of Materials Engineering and Performance, 2001, 10(2): 203–211

    Article  Google Scholar 

  26. Gazda A, Warmuzek M, Bitka A. Optimization of mechanical properties of complex, two-stage heat treatment of Cu-Ni (Mn, Mo) austempered ductile iron. Journal of Thermal Analysis and Calorimetry, 2018, 132(2): 813–822

    Article  Google Scholar 

  27. Tyrała E, Górny M, Kawalec M, Muszyńska A, Lopez H F. Evaluation of volume fraction of austenite in austempering process of austempered ductile iron. Metals, 2019, 9(8): 893

    Article  Google Scholar 

  28. Basso A, Caldera M, Massone J. Development of high silicon dual phase austempered ductile iron. ISIJ International, 2015, 55(5): 1106–1113

    Article  Google Scholar 

  29. Batra U, Ray S, Prabhakar S R. The influence of nickel and copper on the austempering of ductile iron. Journal of Materials Engineering and Performance, 2004, 13(1): 64–68

    Article  Google Scholar 

  30. Saal P, Meier L, Li X H, Hofmann M, Hoelzel M, Wagner J N, Volk W. In situ study of the influence of nickel on the phase transformation kinetics in austempered ductile iron. Metallurgical and Materials Transactions A, 2016, 47(2): 661–671

    Article  Google Scholar 

  31. Cekic O E, Sidjanin L, Rajnovic D, Balos S. Austempering kinetics of Cu-Ni alloyed austempered ductile iron. Metals and Materials International, 2014, 20(6): 1131–1138

    Article  Google Scholar 

  32. Górny M, Tyrała E, Lopez H. Effect of copper and nickel on the transformation kinetics of austempered ductile iron. Journal of Materials Engineering and Performance, 2014, 23(10): 3505–3510

    Article  Google Scholar 

  33. Rao P P, Putatunda S K. Investigations on the fracture toughness of austempered ductile iron alloyed with chromium. Materials Science and Engineering: A, 2003, 346(1–2): 254–265

    Article  Google Scholar 

  34. Landesberger M, Koos R, Hofmann M, Li X H, Boll T, Petry W, Volk W. Phase transition kinetics in austempered ductile iron (ADI) with regard to mo content. Materials, 2020, 13(22): 5266

    Article  Google Scholar 

  35. Panneerselvam S, Martis C J, Putatunda S K, Boileau J M. An investigation on the stability of austenite in austempered ductile cast iron (ADI). Materials Science and Engineering: A, 2015, 626: 237–246

    Article  Google Scholar 

  36. Harding R A. The production, properties and automotive applications of austempered ductile iron. Kovove Materialy, 2007, 45(1): 1–16

    Google Scholar 

  37. Sohi M H, Ahmadabadi M N, Vahdat A B. The role of austempering parameters on the structure and mechanical properties of heavy section ADI. Journal of Materials Processing Technology, 2004, 153–154: 203–208

    Article  Google Scholar 

  38. Rezvani M, Harding R A, Campbell J. Microstructural changes during the annealing of ductile iron alloyed with vanadium. International Journal of Cast Metals Research, 1999, 11(5): 401–406

    Article  Google Scholar 

  39. Cui J J, Chen L Q. Infuence of austempering process on microstructures and mechanical properties of V-containing alloyed ductile iron. Journal of Iron and Steel Research International, 2018, 25(1): 81–89

    Article  Google Scholar 

  40. Kumar S, Ghose A K, Chakrabarty I. Austempering and cryogenic treatment of vanadium modified carbidic ductile iron. Materials and Manufacturing Processes, 2021, 36(12): 1352–1364

    Article  Google Scholar 

  41. Han C F, Sun Y F, Wu Y, Ma Y H. Effects of vanadium and austempering temperature on microstructure and properties of CADI. Metallography, Microstructure, and Analysis, 2015, 4(3): 135–145

    Article  Google Scholar 

  42. Rao P P, Putatunda S K. Influence of microstructure on fracture toughness of austempered ductile iron. Metallurgical and Materials Transactions A, 1997, 28(7): 1457–1470

    Article  Google Scholar 

  43. Cardoso P H S, Israel C L, Strohaecker T R. Abrasive wear in austempered ductile irons: a comparison with white cast irons. Wear, 2014, 313(1–2): 29–33

    Article  Google Scholar 

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Correspondence to Fatma Bayata.

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Bayata, F., Vatan, S.B. Mechanical properties of vanadium-alloyed austempered ductile iron for crankshaft applications. Front. Mech. Eng. 18, 30 (2023). https://doi.org/10.1007/s11465-023-0746-2

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