Abstract
The studies over forty years on rare earth catalysts in polymer syntheses of diene, alkyne, alkylene oxide, thiirane, carbon dioxide copolymerization, lactide, caprolactone, cyclic carbonate and so forth in China have been reviewed.
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References
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Shen Zhiquan, Yu Luping, Yang Mujie, New scandium coordination catalysts for the cis-polymerization of acetylene, Inorganica Chimica Acta, 1985, 109: 55–57
Yu Luping, Shen Zhiquan, Yang Mujie, The kinetics and mechanism of polymerization of acetylene by rare earth coordination catalysts, Synth. Met., 1985, 11: 53–60
Yang Mujie, Qiao Yinan, Xiang Xinzhen, Chen Zhongxin, Shen Zhiquan, Electrical conductive polyacetylene/elastomer composite films, Polym. Mater. Sci. & Eng., 1985, (1): 55–62 (in Chinese)
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Chen Zhongxin, Shen Zhiquan, Liu Min, Shi Mingxiao, Hummel D.-O., Fourier transform infrared spectroscopic study of polyacetylene II. Thermal isomerization kinetics and mechanism, Makromol. Chem., 1987, 188: 2697–2703
Shen Zhiquan, Chen Zhongxin, Yang Mujie, Ferric chloride doped rare earth polyacetylene, Acta Chimica Sinica, 1986, 44: 575–579 (in Chinese)
Chen Zhongxin, Shen Zhiquan, Chen Changshen, Zhao Yonggang, Yang Mujie, Conductivity and spectroscopic characterization of polyacetylene doped with ferric chloride, Makromol. Chem., 1987, 188: 349–355
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Peng Jiande, Zhang Yifeng, Shen Zhiquan, A kinetics study of ring-opening polymerization of alkylene oxide based on rare earth coordination catalysts, Acta Polymeric Sinica, 1991, (2): 184–189 (in Chinese)
Peng Jiande, Zhang Yifeng, Shen Zhiquan, Li Yebing, Study on the formation of active species of rare earth catalyst, Journal of Zhejiang University, 1990, 24(6): 809–816(in Chinese)
Zeng Xianbiao, Zhang Yifeng, Shen Zhiquan, Ring-opening polymerization of propylene oxide by chitosan supported rare earth catalytic system and its kinetics, J. Polym. Sci., Part A: Polym. Chem., 1997, 35(11): 2177–2182
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Sun Junquan, Wu Peizhan, Shen Zhiquan, The Kinetics of ring opening polymerization of epichlorohydrin with rare earth catalyst, Chinese Journal of Catalysis, 1989, 10(3): 301–308 (in Chinese)
Liu Jianfei, Sun Junquan, Shen Zhiquan, The polymerization of epichlorohydrin with Nd(O-iPr)3-Al(i-Bu)3, Chinese Journal of Polymer Science, 1994, 12(2): 153–156
Shen Zhiquan, Jiang Donglin, Zhang Yifeng, Rare earth polymer complex catalyst for ring-opening polymerization of epichlorohydrin, Chemical Research in Chinese Universities, 1995, 11(3): 238–242
Shen Zhiquan, Wu Jian, Wang Guoping, Use of rare earth coordination catalyst for ethylene oxide and propylene oxide copolymerization, J. Polym. Sci., Part A: Polym. Chem., 1990, 28: 1965–1971
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Ge Ling, Huang Qiaohong, Zhang Yifeng, Shen Zhiquan, Ring-opening polymerization of styrene oxide with rare earth coordination catalysts, Euro. Polym. J., 2000, 36(12): 2699–2705
Sun Weilin, Zhang Yifeng, Shen Zhiquan, Ring-opening polymerization of chloromethyl thiirane(CMT) by rare earth coordination catalysts II. Polymerization of CMT and polymerization kinetics, Chin. Chem. Lett., 1994, 5(2): 157–158
Li Weishi, Shen Zhiquan, Zhang Yifeng, Ring-opening polymerization of chloromethyl thiirane with catalytic systems composed of lanthanide compound and ethyl aluminum sesquichloride, Chin. Chem. Lett., 1998, 9(2): 149–151
Li Weishi, Shen Zhiquan, Zhang Yifeng, Ring-opening polymerization of chloromethyl thiirane with AlCl3 and LnL3-Al2Et3Cl3 coordination catalyst, Polym. J., 1997, 29(12): 1037–1039
Shen Zhiquan, Li Weishi, Zhang Yifeng, Ring-opening polymerization of chloromethyl thiirane with SO2/TiO2/Nd as initiator, Macromol. Rapid Commun., 1997, 18(9): 769–773
Li Weishi, Zhang Fuyao, Shen Zhiquan, Zhang Yifeng, Determination of Mark-Houwink equation constants of poly(chloromethyl thiirane), Acta Polymerica Sinica, 1997, (4): 393–399 (in Chinese)
Li Weishi, Shen Zhiquan, Zhang Yifeng, Activity and mechanism of rare earth solid superacid for initiating ring-opening polymerization of chloromethyl thiirane, Euro. Polym. J., 2001, 37: 1185–1190
Sun Weilin, Shen Zhiquan, Zhang Yifeng, Studies on the copolymerization of chloromethyl thiirane with epichlorohydrin by rare earth coordination catalysts, Chem. J. Chin. Univ., 1996, 17(10): 1638–1643 (in Chinese)
Sun Weilin, Shen Zhiquan, Zhang Yifeng, Studies on the copolymerization of chloromethyl thiirane with propylene oxide by rare earth coordination catalysts, Chem. J. Chin. Univ., 1996, 17(1): 137–141 (in Chinese)
Sun Weilin, Shen Zhiquan, Zhang Yifeng, Study on chelating resins containing polythioether main chain III. Synthesis and adsorption properties of chelating resin bearing thiosulfate or azide group, Gongneng Gaofenzi Xuebao, 1996, 9(3): 324–328 (in Chinese)
Sun Weilin, Shen Zhiquan, Zhang Yifeng, Study on chelating resins containing polythioether main chain IV. Synthesis and adsorption properties of chelating esin bearing thiocyanate, Gongneng Gaofenzi Xuebao, 1996, 9(4): 516–522 (in Chinese)
Sun Weilin, Shen Zhiquan, Zhang Yifeng, Study on chelating resins containing polythioether main chain II. Synthesis and adsorption properties of chelating resin bearing 2-aminothiazol, Acta Polymerica Sinica, 1996, (2): 216–221
Sun Weilin, Shen Zhiquan, Zhang Yifeng, Study on chelating resins containing polythioether main chain I. Synthesis and adsorption properties of chelating resin bearing 4-aminoantipyrine or ethylxanthic acid, Ion Exchange and Adsorption, 1997, 13(1): 23–29
Li Weishi, Shen Zhiquan, Zhang Yifeng, Studies on new type chelating resins I. Synthesis and sorption properties of chelating resins having polythioether backbone and primary amino group, Chem. J. Chin. Univ., 1998, 19(2): 322–325 (in Chinese)
Li Weishi, Shen Zhiquan, Zhang Yifeng, Synthesis of functional resins from poly(chloromethyl thiirane) and their sorption properties for noble metal, J. Macromol. Sci.-Pure & Appl. Chem., 1998, A35(6): 955–964
Li Weishi, Shen Zhiquan, Sun Weilin, Zhang Yifeng, Studies on ring-opening polymerization of chloromethyl thiirane with rare earth catalysts and functional resins synthesized therewith, Chin. J. Chem., 2002, 20: 299–303
Tan Chung-sung, Hsu Tsung-ju, Alternating copolymerization of carbon dioxide and propylene oxide with a rare earth metal coordination catalyst, Macromolecules, 1997, 30: 3147–3150
Liu Binyuan, Zhao Xiaojiang, Wang Xianhong, Wang Fusong, J. Polym. Sci. Polym. Chem. Ed., 2001, 39(16): 2751–2754
Zhang Lifang, Shen Zhiquan, Yu Cuiping, Fan Ling, Ring-opening polymerization of D,L-lactide by rare earth 2,6-dimethylaryloxide, Polym. Intern., 2004, 53(8): 1013–1016
Zhang Lifang, Shen Zhiquan, Yu Cuiping, Fan Ling, Characteristics and mechanism of L-lactide polymerization by lanthanide 2,6-dimethylaryloxide, J. Mol. Cat. A-Chem., 2004, 214(2): 199–202
Yu Cuiping, Zhang Lifang, Tu Kehua, Shen Zhiquan, Ring-opening polymerization of (D,L)-lactide by the single component rare earth tris(4-tert-butylphenolate)s, Polym. Bull., 2004, 52(5): 329–337
Yu Cuiping, Zhang Lifang, Ni Xufeng, Shen Zhiquan, Tu Kehua, Ring-opening polymerization of L-lactide by rare-earth tris(4-tert-butylphenolate) single-component initiators J. Polym. Sci. Part A-Polym. Chem., 2004, 42(24): 6209–6215
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Shen Youqing, Shen Zhiquan, Zhang Fuyao, Zhang Yifeng, Ring-opening polymerization of ɛ-caprolactone by rare earth alkoxide/CCl4 systems, Polym. J., 1995, 27(1): 59–64
Shen Youqing, Shen Zhiquan, Zhang Yifeng, Huang Qiaohong, Random copolymerization of ɛ-caprolactone and trimethylene carbonate with rare earth catalysts, J. Appl. Polym. Sci., 1997, 69(10): 2131–2139
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Ling Jun, Shen Zhiquan, Lanthanum tri(2,6-di-tert-butyl-4-methylphenolate) as a novel versatile initiator for homo-and copolymerization of cyclic carbonates and lactones, Macromol. Chem. & Phys., 2002, 203: 735–738
Yu Cuiping, Zhang Lifang, Shen. Zhiquan, Ring-opening polymerization of ɛ-caprolactone using rare earth tris(4-tertbutylphenolate)s as a single component initiator, Euro. Polym. J., 2003, 39(10): 2035–2039
Zhang Lifang, Yu Cuiping, Shen Zhiquan, Characteristics, kinetics and mechanism of ɛ-caprolactone polymerization by lanthanide tris(2,6-dimethylphenolate)s, Polym. Bull., 2003, 51: 47–53
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Peng Fei, Ling Jun, Shen Zhiquan, Zhu Weiwei, Correlation between phenol structure and catalytic activity of samarium(III) phenolates in polymerization of epsilon-caprolactone Part 2. Tertbutyl’s electronic and steric effects, J. Mol. Cat. A: Chem., 2005, 230: 135–141
Shen Youqing, Shen Zhiquan, Zhang Yifeng, Huang Qiaohong, A comparison of polymerization characteristics and mechanisms of ɛ-caprolactone and trimethylene carbonate with rare earth halides, J. Polym. Sci., Part A: Polym. Chem., 1997, 35(8): 1339–1352
Huang Qiaohong, Shen Zhiquan, Zhang Yifeng, Shen Youqing, Shen Lianfang, Yuan Hanzhen, Ring-opening copolymerization of trimethylene carbonate and D,L-lactide by rare earth chloride, Polym. J., 1998, 30(3): 168–170
Ge Ling, Shen Zhiquan, Zhang Yifeng, Huang Qiaohong, Ring-opening polymerization of trimethylene carbonate by calix[8]arene neodymium, Chin. J. Polym. Sci., 2000, 18(1): 77–80
Ling Jun, Shen Zhiquan, Chen Wanli, Algorithm and application of Monte Carlo simulation for multi-dispersive copolymerization system, Sci. in China (Series B), 2002, 45(3): 243–250
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Translated from Gaofenzi Tongbao (Polymer Bulletin) 2005, (4) (in Chinese)
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Shen, Z. Exploitation of rare earth catalysts in polymer syntheses. Front. Chem. China 1, 247–259 (2006). https://doi.org/10.1007/s11458-006-0031-z
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DOI: https://doi.org/10.1007/s11458-006-0031-z