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Magnetic characteristics of lake sediments in Qiangyong Co Lake, southern Tibetan Plateau and their application to the evaluation of mercury deposition

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Abstract

Heavy metals, one of the most toxic classes of pollutants, are resistant to degradation and harmful to the biological environment. The lakes that have developed on the Tibetan Plateau are ideal regions to investigate historic heavy metal pollution, particularly through the use of the reliable 210Pb dating technique. Environmental magnetism has been successfully applied to estimate heavy metal pollution in different environmental systems due to its characteristics of simple processing steps, good sensitivity, and non-destructibility. However, it has not yet been applied to assess heavy metal pollution in lake sediments on the Tibetan Plateau. A series of environmental magnetic investigations of Qiangyong Co Lake sediments (southern Tibetan Plateau) was therefore conducted to explore the relationship between magnetic minerals and mercury (Hg) concentrations. The results showed that the magnetic mineral species in lake sediments remained stable, with similar levels of four different components from 1899 to 2011. However, the proportion of component 1 (C1, hematite) increased continuously with the corresponding decrease in the proportion of C2 (goethite), while the proportions of C3 and C4 (magnetite) did not change significantly. As a result, the bulk magnetic signals (e.g., SIRM and χlf) were unsuitable for the evaluation of the Hg concentration; however, the proportion of hematite had a strong positive correlation with the Hg concentration. It is possible that the Qiangyong Glacier (the main water supply for Qiangyong Co Lake) has experienced faster melting with global and local warming, and the Hg trapped in cryoconite and ice was released. Hematite, with a large specific surface area, has a strong capacity for absorbing Hg, and both materials are ultimately transported to Qiangyong Co Lake. The proportion of hematite in a sample is therefore a suitable semi-quantitative proxy that can be used to evaluate the Hg concentration in Qiangyong Co Lake sediments. This study confirmed that the variation of magnetic minerals can provide a new method to estimate the variation of Hg concentrations and to study the process of Hg deposition in lakes in the southern Tibetan Plateau on the basis of a detailed environmental magnetic analysis.

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References

  • Ao Hong, Deng Chenglong, 2007. Review in the identification of magnetic minerals. Progress in Geophysics, 22(2): 432–442. (in Chinese)

    Google Scholar 

  • Chen P F, Kang S C, Li C L et al., 2019. Carbonaceous aerosol characteristics on the Third Pole: A primary study based on the Atmospheric Pollution and Cryospheric Change (APCC) network. Environmental Pollution, 253: 49–60.

    Google Scholar 

  • Chen Xi, Zhang Weiguo, Yu Lizhong, 2009. The dependence of magnetic parameters on the mixing proportion of hematite and magnetite. Progress in Geophysics, 24(1): 82–88. (in Chinese)

    Google Scholar 

  • Cong Zhiyuan, Gao Shaopeng, Zhao Wancang et al., 2018. Iron oxides in the cryoconite of glaciers on the Tibetan Plateau: Abundance, speciation and implications. Cryosphere Discussions, 12: 3177–3186.

    Google Scholar 

  • Cong Zhiyuan, Kang Shichang, Zheng Wei et al., 2010. Modern process and historical reconstruction of Pb and Hg in remote areas: A critical review. Acta Geographica Sinica, 65(3): 351–360. (in Chinese)

    Google Scholar 

  • Day R, Fuller M, Schmidt V A, 1977. Hysteresis properties of titanomagnetites: Grain size and compositional dependence. Physics of the Earth and Planetary Interiors, 13(4): 260–267.

    Google Scholar 

  • Deng Chenglong, Zhu Rixiang, Yuan Baoyin, 2002. Rock magnetism of the Holocene eolian in the Loess Plateau: Evidence for pedogenesis. Marine Geology & Quaternary Geology, 11(2): 37–45. (in Chinese)

    Google Scholar 

  • Duan Zongqi, Gao Xing, Liu Qingsong et al., 2011. Magnetic characteristics of insoluble microparticles in ice core (Nojingkangsang) from the southern Tibetan Plateau and its environmental significance. Science China Earth Sciences, 54(11): 1635–1642.

    Google Scholar 

  • Duan Zongqi, Gao Xing, Liu Qingsong, 2012. Anhysteretic remanent magnetization (ARM) and its application to geoscience. Progress in Geophysics, 27(5): 1929–1938. (in Chinese)

    Google Scholar 

  • Dunlop D J, 2002a. Theory and application of the Day plot (Mrs/Ms versus Hcr/Hc) 1. Theoretical curves and tests using titanomagnetite data. Journal of Geophysical Research, 107(B3): EPM1–EPM4–22.

    Google Scholar 

  • Dunlop D J, 2002b. Theory and application of the Day plot (Mrs/Ms versus Hcr/Hc) 2. Application to data for rocks, sediments, and soils. Journal of Geophysical Research, 107(B3): EPM1–EPM5–15.

    Google Scholar 

  • Egli R, 2003. Analysis of the field dependence of remanent magnetization curves. Journal of Geophysical Research, 108: B2, doi: https://doi.org/10.1029/2002JB002023.

    Google Scholar 

  • Gautam P, Blaha U, Appel E, 2005. Magnetic susceptibility of dust-loaded leaves as a proxy of traffic-related heavy metal pollution in Kathmandu city, Nepal. Atmospheric Environment, 39(12): 2201–2211.

    Google Scholar 

  • Guo Bixi, Liu Yongqin, Zhang Fan et al., 2016. Characteristics and risk assessment of heavy metals in core sediments from lakes of Tibet. Environmental Science, 37(2): 490–498. (in Chinese)

    Google Scholar 

  • Guo Chao, Meng Hongwei, Ma Yuzhen et al., 2019. Environmental variations recorded by chemical element in the sediments of Lake Yamzhog Yumco on the southern Tibetan Plateau over the past 2000 years. Acta Geographica Sinica, 74(7): 1345–1362. (in Chinese)

    Google Scholar 

  • Guo Wei, Huo Shouliang, Ding Wenjuan, 2015. Historical record of human impact in a lake of northern China: Magnetic susceptibility, nutrients, heavy metals and OCPs. Ecological Indicators, 57: 74–81.

    Google Scholar 

  • Hanesch M, Scholger R, Rey D, 2003. Mapping dust distribution around an industrial site by measuring magnetic parameters of tree leaves. Atmospheric Environment, 37(36): 5125–5133.

    Google Scholar 

  • Heslop D, Dekkers M J, Kruiver P P et al., 2002. Analysis of isothermal remanent magnetization acquisition curves using the expectation-maximization algorithm. Geophysical Journal International, 148(1): 58–64.

    Google Scholar 

  • Hu P, Liu Q, José Torrent et al., 2013 Characterizing and quantifying iron oxides in Chinese loess/paleosols: Implications for pedogenesis. Earth and Planetary Science Letters, 369/370(3): 271–283.

    Google Scholar 

  • Hu Shouyun, Duan Xuemei, Shen Mingjie et al., 2008. Magnetic response to atmospheric heavy metal pollution recorded by dust-loaded leaves in Shougang industrial area, Western Beijing. Chinese Science Bulletin, 53(10): 1555–1564. (in Chinese)

    Google Scholar 

  • Hu Y Q, Mitsuta Y, 1997. Micrometeorological characteristics and local triggering mechanism of strong dust storm. Scientia Atmospherica Sinica, 21: 581–589. (in Chinese)

    Google Scholar 

  • Huang Jie, Kang Shichang, Ma Ming et al., 2019. Accumulation of atmospheric mercury in glacier cryoconite over western China. Environmental Science & Technology, 53(13): 6632–6639.

    Google Scholar 

  • Huang Jie, Kang Shichang, Zhang Qianggong et al., 2015. Characterizations of wet mercury deposition on a remote high-elevation site in the southeastern Tibetan Plateau. Environmental Pollution, 206: 518–526.

    Google Scholar 

  • Jiang Zhaoxia, Liu Qingsong, 2016. Quantification of hematite and its climatic significances. Quaternary Sciences, 36(3): 676–689. (in Chinese)

    Google Scholar 

  • Kang S C, Huang J, Wang F Y et al., 2016. Atmospheric mercury depositional chronology reconstructed from lake sediments and ice core in the Himalayas and Tibetan Plateau. Environmental Science & Technology, 50(6): 2859–2869.

    Google Scholar 

  • Kang S C, Zhang Q G, Qian Y et al., 2019. Linking atmospheric pollution to cryospheric change in the Third Pole region: Current progress and future prospects. National Science Review, 6(4): 796–809.

    Google Scholar 

  • Kosterov A, 2003. Low-temperature magnetization and AC susceptibility of magnetite: Effect of thermomagnetic history. Geophysical Journal International, 154: 58–71.

    Google Scholar 

  • Li C, Bosch C, Kang S et al., 2016. Sources of black carbon to the Himalayan-Tibetan Plateau glaciers. Nature Communications, 7: 12574, doi: https://doi.org/10.1038/nomms12574.

    Google Scholar 

  • Li Chaoliu, Kang Shichang, Cong Zhiyuan, 2007. Elemental composition of aerosols collected in the glacier area on Nyainqêntanglha Range, Tibetan Plateau, during summer monsoon season. Chinese Science Bulletin, 52(24): 3436–3442.

    Google Scholar 

  • Li Jiule, Xu Baiqing, Lin Shubiao et al., 2011. Glacier and climate changes over the past millennium recorded by proglacial sediment sequence from Qiangyong Lake, Southern Tibetan Plateau. Journal of Earth Sciences and Environment, 33(4): 402–411. (in Chinese)

    Google Scholar 

  • Li Peng, Qiang Xiaoke, Tang Yanrong et al., 2010. Magnetic susceptibility of the dust of street in Xi’an and the implication on pollution. China Environmental Science, 30(3): 309–314. (in Chinese)

    Google Scholar 

  • Liu Q, Roberts A P, Larrasoaña J C et al., 2012. Environmental magnetism: Principles and applications. Reviews of Geophysics, 50(4): RG4002, doi:https://doi.org/10.1029/2012RG000393.

    Google Scholar 

  • Liu Yang, Ma Zongwei, Lv Jianshu et al., 2016. Identifying sources and hazardous risks of heavy metals in top-soils of rapidly urbanizing East China. Journal of Geographical Sciences, 26(6): 735–749.

    Google Scholar 

  • Liu Zhendong, Liu Qingsheng, Wan Hansheng et al., 2006. Relationship between magnetic properties and heavy metals of sediments in Donghu Lake, Wuhan, China. Earth Science-Journal of China University of Geosciences, 31(2): 266–272. (in Chinese)

    Google Scholar 

  • Mamattursun Eziz, Ajigul Mamut, Anwar Mohammad et al., 2017. Assessment of heavy metal pollution and its potential ecological risks of farmland soils of oasis in Bostan Lake basin. Acta Geographica Sinica, 72(9): 1680–1694.

    Google Scholar 

  • Muxworthy A R, McClelland E, 2000. Review of the low-temperature magnetic properties of magnetite from a rock magnetic perspective. Geophysical Journal International, 140: 101–114.

    Google Scholar 

  • Qiu J, 2008. The Third Pole. Nature, 454: 393–396.

    Google Scholar 

  • Roberts A P, Cui Y, Verosub K L, 1995. Wasp-waisted hysteresis loops: Mineral magnetic characteristics and discrimination of components in mixed magnetic systems. Journal of Geophysical Research, 100: 17909–17924, doi: https://doi.org/10.1029/95JB00672.

    Google Scholar 

  • Spiteri C, Kalinski V, Rösler W et al., 2005. Magnetic screening of a pollution hotspot in the Lausitz area, Eastern Germany: Correlation analysis between magnetic proxies and heavy metal contamination in soils. Environmental Geology, 49(1): 1–9.

    Google Scholar 

  • Sun Xi, Liu Heman, Zhou Tong et al., 2016. Preliminary study on soil fertility and heavy metal concentrations of croplands in Nyingchi valley of Tibet. Soils, 48(1): 131–138. (in Chinese)

    Google Scholar 

  • Torrent J, Barrón V, 2008 Diffuse reflectance spectroscopy//Ulery A L, Drees R. Methods of Soil Analysis Part 5: Mineralogical Methods. Madison, WI: Soil Science Society of America, Inc.

    Google Scholar 

  • Verwey E J, 1939. Electronic conduction of magnetite (Fe3O4) and its transition point at low temperature. Nature, 144: 327–328.

    Google Scholar 

  • Wan X, Kang S C, Li Q L et al., 2017. Organic molecular tracers in the atmospheric aerosols from Lumbini, Nepal, in the northern Indo-Gangetic Plain: Influence of biomass burning. Atmospheric Chemistry and Physics, 17: 8867–8885.

    Google Scholar 

  • Wang X P, Ren J, Gong P et al., 2016. Spatial distribution of the persistent organic pollutants across the Tibetan Plateau and its linkage with the climate systems: A 5-year air monitoring study. Atmospheric Chemistry and Physics, 16(11): 6901–6911.

    Google Scholar 

  • Wang X P, Yang H, Gong P et al., 2010. One century sedimentary records of polycyclic aromatic hydrocarbons, mercury and trace elements in the Qinghai Lake, Tibetan Plateau. Environmental Pollution, 158: 3065–3070.

    Google Scholar 

  • Wu G M, Wan X, Gao S P et al., 2018. Humic-like substances (HULIS) in aerosols of Central Tibetan Plateau (Nam Co, 4730 m asl): Abundance, light absorption properties, and sources. Environmental Science & Technology, 52: 7203–7211.

    Google Scholar 

  • Xiao Cunde, Qin Dahe, Yao Tandong et al., 2000. The global pollution revealed by Pb, Cd in the surface snow of Antarctic, Arctic and Qinghai-Xizang Plateau. Chinese Science Bulletin, 45(9): 847–853.

    Google Scholar 

  • Xie Ting, Zhang Shujuan, Yang Ruiqiang, 2014. Contamination levels and source analysis of polycyclic aromatic hydrocarbons and organochlorine pesticides in soils and grasses from lake catchments in the Tibetan Plateau. Environmental Science, 35(7): 2680–2690. (in Chinese)

    Google Scholar 

  • Xu B, Cao J, Hansen J et al., 2009. Black soot and the survival of Tibetan glaciers. Proceedings of the National Academy of Sciences, 106(52): 22114–22118.

    Google Scholar 

  • Yang H D, Battarbee R W, Turner S D et al., 2010. Historical reconstruction of mercury pollution across the Tibetan Plateau using lake sediments. Environmental Science & Technology, 44: 2918–2924.

    Google Scholar 

  • Yao Tandong, Piao Shilong, Shen Miaogen et al., 2017. Chained impacts on modern environment of interaction between Westerlies and Indian Monsoon on Tibetan Plateau. Bulletin of Chinese Academy of Sciences, 32(9): 976–984.

    Google Scholar 

  • Yin Xiufeng, de Foy Benjamin, Wu Kunpeng et al., 2019. Gaseous and particulate pollutants in Lhasa, Tibet during 2013–2017: Spatial variability, temporal variations and implications. Environmental Pollution, 253: 68–77.

    Google Scholar 

  • Zhang Chunxia, Huang Baochun, Liu Qingsong, 2009. Magnetic properties of different pollution receptors around steel plants and their environmental significance. Chinese Journal of Geophysics, 52(11): 2826–2839. (in Chinese)

    Google Scholar 

  • Zhang Chunxia, Huang Baochun, Luo Rensong et al., 2007. Magnetic properties of tree ring samples close to a smelting factory and their environmental significance. Quaternary Sciences, 27(6): 1092–1104. (in Chinese)

    Google Scholar 

  • Zhang F, Yan X D, Zeng C et al., 2012. Influence of traffic activity on heavy metal concentrations of roadside farmland soil in mountainous areas. International Journal of Environmental Research and Public Health, 9(5): 1715–1731.

    Google Scholar 

  • Zhang Q, Huang J, Wang F et al., 2012. Mercury distribution and deposition in glacier snow over western China. Environmental Science & Technology, 46(10): 5404–5413.

    Google Scholar 

  • Zhang Weiling, Zhang Gan, Qi Shihua et al., 2003. A preliminary study of organochlorine pesticides in water and sediments from two Tibetan lakes. Geochimica, 32(4): 363–367. (in Chinese)

    Google Scholar 

  • Zheng Du, Yao Tandong, 2004 Uplifting of Tibetan Plateau with Its Environmental Effects. Beijing: Science Press. (in Chinese)

    Google Scholar 

  • Zhu L P, Lv X M, Wang J et al., 2015. Climate change on the Tibetan Plateau in response to shifting atmospheric circulation since the LGM. Scientific Reports, 5(1): 13318, doi: https://doi.org/10.1038/srep13318.

    Google Scholar 

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Authors and Affiliations

  1. State Key Laboratory of Resources and Environmental Information System, Institute of Geographic Sciences and Natural Resources Research, CAS, Beijing, 100101, China

    Xing Gao & Zongqi Duan

  2. State Key Laboratory of Cryospheric Science, Northwest Institute of Eco-Environment and Resources, CAS, Lanzhou, 730000, China

    Shichang Kang & Pengfei Chen

  3. Department of Ocean Science and Engineering, Southern University of Science and Technology, Shenzhen, Guangdong, 518055, China

    Qingsong Liu

  4. The Geographical Society of China, Beijing, 100101, China

    Zongqi Duan

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  1. Xing Gao
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  2. Shichang Kang
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  4. Pengfei Chen
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  5. Zongqi Duan
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Correspondence to Zongqi Duan.

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Foundation: National Natural Science Foundation of China, No.41506075, No.41430962, No.41574036, No.41705132

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Gao, X., Kang, S., Liu, Q. et al. Magnetic characteristics of lake sediments in Qiangyong Co Lake, southern Tibetan Plateau and their application to the evaluation of mercury deposition. J. Geogr. Sci. 30, 1481–1494 (2020). https://doi.org/10.1007/s11442-020-1794-8

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