Abstract
Several metal (such as aluminum, iron etc.) film systems deposited on liquid (silicone oil) substrates have been successfully fabricated by a thermal evaporation method, and the special mechanical properties and complex ordered surface structures have been systematically studied. The experimental results show that there exists a compressive stress gradient in these films, making cracks nucleate at the film edges and then extend to the central regions gradually. Because the interaction between solid films and liquid substrates in the tangent direction is very small, the metal films can motion freely on the oil surfaces as a whole. In order to release the compressive stress, the broken film pieces collide, crush and superpose each other, which finally results in the formation of ordered bandshaped structures with an anti-symmetric characteristic. Based on the special mechanical properties of these nearly free sustained films, the morphologies and growth behaviors of the ordered structures are analyzed and discussed in detail.
Similar content being viewed by others
References
Zhang Z Y, Lagally M G. Atomistic processes in the early stages of thin-film growth. Science, 1997, 276: 377–383
Grant M L, Swartzentruber B S, Bartelt N C, et al. Diffusion kinetics in the Pd/Cu(001) surface alloy. Phys Rev Lett, 2001, 86(20): 4588–4591
Bowden N, Brittain S, Evans A G, et al. Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer. Nature, 1998, 393: 146–149
Lacour S P, Wangner S, Huang Z, et al. Stretchable gold conductors on elastomeric substrates. Appl Phys Lett, 2003, 82(15): 2404–2406
Ye G X, Michely Th, Weidenhof V, et al. Nucleation, growth and aggregation of Ag clusters on liquid surfaces. Phys Rev Lett, 1998, 81(3): 622–625
Feng C M, Ge H L, Tong M R, et al. Growth behavior and surface morphology of Ag rough thin films deposited on silicone oil surfaces. Thin Solid Films, 1999, 342: 30–34
Cai P G, Yu S J, Ye Q L, et al. An internal stress pattern in free standing films. Phys Lett A, 2003, 312: 119–122
Ye Q L, Yu S J, Jin J S, et al. Formation mechanism and orderly structures of an iron film system deposited on silicone oil surfaces. Chin Phys Lett, 2003, 20(7): 1109–1111
Yu S J, Zhang Y J, Ye Q L, et al. Spontaneous formation of ordered patterns in Al films deposited on silicone oil surfaces. Phys Rev B, 2003, 68(19): 193403
Yang B. Formation mechanism of orderly structures in Au films deposited on silicone oil surfaces. Phys Lett A, 2005, 341: 516–522
Voigt M, Dorsfeld S, Volz A, et al. Nucleation and growth of molecular organic crystals in liquid film under vapor deposition. Phys Rev Lett, 2003, 91(2): 026103
Kessler M A, Werner B T. Self-organization of sorted patterned ground. Science, 2003, 299: 380–383
Tang Z, Kotov N A, Giersig M. Spontaneous organization of single CdTe nanoparticles into luminescent nanowires. Science, 2002, 297: 237–240
Tao X M, Ye G X, Ye Q L, et al. Anomalous electrical conductivity of a gold thin film percolation system. Phys Rev B, 2002, 66(11): 115406
Yoo P J, Lee H H. Evolution of a stress-driven pattern in thin bilayer films: Spinodal wrinkling. Phys Rev Lett, 2003, 91(15): 154502
Moller J, Reiche D, Bobeth M, et al. Observation of boron nitride thin film delamination due to humidity. Surf Coat Technol, 2002, 150: 8–14
Shahrjerdi D, Hekmatshoar B, Rezaee L, et al. Low temperature stress-induced crystallization of germanium on plastic. Thin Solid Films, 2003, 427: 330–334
Herminghaus S, Jacobs K, Mecke K, et al. Spinodal dewetting in liquid crystal and liquid metal films. Science, 1998, 282: 916–919
Yu Y, Nakano M, Ikeda T. Directed bending of a polymer film by light. Nature, 2003, 425: 145
Neda Z, Leung K-T, Jozsa L, et al. Spiral cracks in drying precipitates. Phys Rev Lett, 2002, 88(9): 095502
Royer J Y, Gordon R G. The motion and boundary between the Capricorn and Australian plates. Science, 1997, 277: 1268–1274
You P, Yu G P. Optics (in Chinese). Beijing: High Education Press, 2003, 61–62
Author information
Authors and Affiliations
Corresponding author
About this article
Cite this article
Yu, S., Zhang, Y., Wu, L. et al. Characteristic mechanical properties and complex ordered structures in metal films on liquid substrates. CHINESE SCI BULL 51, 1039–1049 (2006). https://doi.org/10.1007/s11434-006-1039-y
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s11434-006-1039-y