Abstract
Flexible sensors can be widely applied in the area of lightweight, wearable and intelligent electronic devices. In aerospace, for example, flexible sensors are suitable for measuring pressure in complex aircraft structures. In recent years, flexible sensors have been well developed; however, most of them lack circuit parts, meaning that the sensors have to be connected to an external electrical source. Additionally, the current traditional design limits their flexibility. Thus, this article proposes a self-powered flexible sensor based on PVDF nanofiber film, which is created through an efficient blow spinning method. The piezoelectric PVDF nanofiber films were prepared, and the flexible pressure sensor was assembled. The PVDF nanofiber film sensor showed good sensitivity and stability, and it can be applied for the detection of human physiological signals.
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Han S T, Peng H, Sun Q, et al. An overview of the development of flexible sensors. Adv Mater, 2017, 29: 1700375
An B W, Heo S, Ji S, et al. Transparent and flexible fingerprint sensor array with multiplexed detection of tactile pressure and skin temperature. Nat Commun, 2018, 9: 1–10
Yan S, Zhang G, Jiang H, et al. Highly stretchable room-temperature self-healing conductors based on wrinkled graphene films for flexible electronics. ACS Appl Mater Interfaces, 2019, 11: 10736–10744
Visser C W, Amato D N, Mueller J, et al. Architected polymer foams via direct bubble writing. Adv Mater, 2019, 31: 1904668
Chen W, Yan X. Progress in achieving high-performance piezoresistive and capacitive flexible pressure sensors: A review. J Mater Sci Tech, 2020, 43: 175–188
Xu S, Qin Y, Xu C, et al. Self-powered nanowire devices. Nat Nanotech, 2010, 5: 366–373
Wang S, Shi K, Chai B, et al. Core-shell structured silk Fibroin/PVDF piezoelectric nanofibers for energy harvesting and self-powered sensing. Nano Mater Sci, 2022, 4: 126–132
Shi K, Sun B, Huang X, et al. Synergistic effect of graphene nanosheet and BaTiO3 nanoparticles on performance enhancement of electrospun PVDF nanofiber mat for flexible piezoelectric nanogenerators. Nano Energy, 2018, 52: 153–162
Whiter R A, Narayan V, Kar-Narayan S. A scalable nanogenerator based on self-poled piezoelectric polymer nanowires with high energy conversion efficiency. Adv Energy Mater, 2014, 4: 1400519
Kim H, Torres F, Villagran D, et al. 3D printing of BaTiO3/PVDF composites with electric in situ poling for pressure sensor applications. Macromol Mater Eng, 2017, 302: 1700229
Fixter L, Williamson C. State of the art review-structural health monitoring. Smart Materials, Surfaces, and Structures Network, 2006
Wu Y, Ma Y, Zheng H, et al. Piezoelectric materials for flexible and wearable electronics: A review. Mater Des, 2021, 211: 110164
Zhao Z, Dai Y, Dou S X, et al. Flexible nanogenerators for wearable electronic applications based on piezoelectric materials. Mater Today Energy, 2021, 20: 100690
Jin L, Ma S, Deng W, et al. Polarization-free high-crystallization β-PVDF piezoelectric nanogenerator toward self-powered 3D acceleration sensor. Nano Energy, 2018, 50: 632–638
Deng W, Yang T, Jin L, et al. Cowpea-structured PVDF/ZnO nanofibers based flexible self-powered piezoelectric bending motion sensor towards remote control of gestures. Nano Energy, 2019, 55: 516–525
Chen X, Shao J, An N, et al. Self-powered flexible pressure sensors with vertically well-aligned piezoelectric nanowire arrays for monitoring vital signs. J Mater Chem C, 2015, 3: 11806–11814
Persano L, Dagdeviren C, Su Y, et al. High performance piezoelectric devices based on aligned arrays of nanofibers of poly(vinylidenefluoride-co-trifluoroethylene). Nat Commun, 2013, 4: 1
Alluri N R, Chandrasekhar A, Jeong J H, et al. Enhanced electroactive β-phase of the sonication-process-derived PVDF-activated carbon composite film for efficient energy conversion and a battery-free acceleration sensor. J Mater Chem C, 2017, 5: 4833–4844
Lund A, Gustafsson C, Bertilsson H, et al. Enhancement of β phase crystals formation with the use of nanofillers in PVDF films and fibres. Compos Sci Tech, 2011, 71: 222–229
Singh H H, Singh S, Khare N. Enhanced β-phase in PVDF polymer nanocomposite and its application for nanogenerator. Polym Adv Technol, 2018, 29: 143–150
Imura Y, Hogan R, Jaffe M. Dry spinning of synthetic polymer fibers. In: Zhang D, ed. Advances in Filament Yarn Spinning of Textiles and Polymers. Amsterdam: Elsevier, 2014. 187–202
Zhang X, Lu Y. Centrifugal spinning: An alternative approach to fabricate nanofibers at high speed and low cost. Polym Rev, 2014, 54: 677–701
Bai X, Liao S, Huang Y, et al. Continuous draw spinning of extra-long silver submicron fibers with micrometer patterning capability. Nano Lett, 2017, 17: 1883–1891
Sarkar K, Gomez C, Zambrano S, et al. Electrospinning to forcespinning. Mater Today, 2010, 13: 12–14
Xue J, Wu T, Dai Y, et al. Electrospinning and electrospun nanofibers: Methods, materials, and applications. Chem Rev, 2019, 119: 5298–5415
Song J, Li Z, Wu H. Blowspinning: A new choice for nanofibers. ACS Appl Mater Interfaces, 2020, 12: 33447–33464
Medeiros E S, Glenn G M, Klamczynski A P, et al. Solution blow spinning: A new method to produce micro- and nanofibers from polymer solutions. J Appl Polym Sci, 2009, 113: 2322–2330
Wang H, Zhang X, Wang N, et al. Ultralight, scalable, and high-temperature-resilient ceramic nanofiber sponges. Sci Adv, 2017, 3: e1603170
Wu C M, Chou M H, Zeng W Y. Piezoelectric response of aligned electrospun polyvinylidene fluoride/carbon nanotube nanofibrous membranes. Nanomaterials, 2018, 8: 420
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This work was supported by the National Natural Science Foundation of China (Grant No. 52103305).
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He, W., Dai, Z., Zou, K. et al. Flexible piezoelectric PVDF nanofiber film sensor by blow spinning. Sci. China Technol. Sci. 66, 863–868 (2023). https://doi.org/10.1007/s11431-022-2267-8
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DOI: https://doi.org/10.1007/s11431-022-2267-8