Skip to main content
Log in

Mechanical properties of individual core-shell-structured SnO2@C nanofibers investigated by atomic force microscopy and finite element method

  • Article
  • Published:
Science China Technological Sciences Aims and scope Submit manuscript

Abstract

Although SnO2-based nanomaterials used to be considered as being extraordinarily versatile for application to nanosensors, microelectronic devices, lithium-ion batteries, supercapacitors and other devices, the functionalities of SnO2-based nanomaterials are severely limited by their intrinsic vulnerabilities. Facile electrospinning was used to prepare SnO2 nanofibers coated with a protective carbon layer. The mechanical properties of individual core-shell-structured SnO2@C nanofibers were investigated by atomic force microscopy and the finite element method. The elastic moduli of the carbon-coated SnO2 nanofibers remarkably increased, suggesting that coating SnO2 nanofibers with carbon could be an effective method of improving their mechanical properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Yin Y, Talapin D. The chemistry of functional nanomaterials. Chem Soc Rev, 2013, 42: 2484–2487

    Article  Google Scholar 

  2. Wen B, Sader J E, Boland J J. Mechanical properties of ZnO nanowires. Phys Rev Lett, 2008, 101: 175502

    Article  Google Scholar 

  3. Wang Z L. Characterizing the structure and properties of individual wire-like nanoentities. Adv Mater, 2000, 12: 1295–1298

    Article  Google Scholar 

  4. Zhang Y, Yan X, Yang Y, et al. Scanning probe study on the piezotronic effect in ZnO nanomaterials and nanodevices. Adv Mater, 2012, 24: 4647–4655

    Article  Google Scholar 

  5. Wang Z L, Poncharal P, de Heer W A. Measuring physical and mechanical properties of individual carbon nanotubes by in situ TEM. J Phys Chem Solids, 2000, 61: 1025–1030

    Article  Google Scholar 

  6. Neuman K C, Nagy A. Single-molecule force spectroscopy: Optical tweezers, magnetic tweezers and atomic force microscopy. Nat Methods, 2008, 5: 491–505

    Article  Google Scholar 

  7. Qian L H, Wang K, Li Y, et al. Co sensor based on au-decorated SnO2 nanobelt. Mater Chem Phys, 2006, 100: 82–84

    Article  Google Scholar 

  8. Ding Y, Zhang P, Long Z, et al. The ionic conductivity and mechanical property of electrospun P(VdF-HFP)/pmma membranes for lithium ion batteries. J Membrane Sci, 2009, 329: 56–59

    Article  Google Scholar 

  9. Ding Y, Zhang P, Jiang Y, et al. Mechanical properties of nylon-6/ SiO2 nanofibers prepared by electrospinning. Mater Lett, 2009, 63: 34–36

    Article  Google Scholar 

  10. Choi S J, Jang B H, Lee S J, et al. Selective detection of acetone and hydrogen sulfide for the diagnosis of diabetes and halitosis using SnO2 nanofibers functionalized with reduced graphene oxide nanosheets. ACS Appl Mater Interfaces, 2014, 6: 2588–2597

    Article  Google Scholar 

  11. Ab Kadir R, Li Z, Sadek A Z, et al. Electrospun granular hollow SnO2 nanofibers hydrogen gas sensors operating at low temperatures. J Phys Chem C, 2014, 118: 3129–3139

    Article  Google Scholar 

  12. Kim D, Lee D, Kim J, et al. Electrospun Ni-added SnO2-carbon nanofiber composite anode for high-performance lithium-ion batteries. ACS Appl Mater Interfaces, 2012, 4: 5408–5415

    Article  Google Scholar 

  13. Huang B, Li X, Pei Y, et al. Novel carbon-encapsulated porous SnO2 anode for lithium-ion batteries with much improved cyclic stability. Small, 2016, 12: 1945–1955

    Article  Google Scholar 

  14. Liu X, Li Z, Jiang Y H, et al. Mechanical properties of a single SnO2 fiber prepared from the electrospinning method. J Sol-Gel Sci Technol, 2017, 84: 152–157

    Article  Google Scholar 

  15. Yang G, Tsubaki N, Shamoto J, et al. Confinement effect and synergistic function of H-ZSM-5/Cu-ZnO-Al2O3 capsule catalyst for one-step controlled synthesis. J Am Chem Soc, 2010, 132: 8129–8136

    Article  Google Scholar 

  16. Kumacheva E, Golding R K, Allard M, et al. Colloid crystal growth on mesoscopically patterned surfaces: Effect of confinement. Adv Mater, 2002, 14: 221–224

    Article  Google Scholar 

  17. Lu A H, Li W C, Matoussevitch N, et al. Highly stable carbon-protected cobalt nanoparticles and graphite shells. Chem Commun, 2005, 19: 98–100

    Article  Google Scholar 

  18. Yuge R, Bandow S, Yudasaka M, et al. Boron- and nitrogen-doped single-walled carbon nanohorns with graphite-like thin sheets prepared by CO2 laser ablation method. Carbon, 2017, 111: 675–680

    Article  Google Scholar 

  19. Jiang Z, Wan W, Wei W, et al. Gentle way to build reduced titanium dioxide nanodots integrated with graphite-like carbon spheres: From DFT calculation to experimental measurement. Appl Catal B-Environ, 2017, 204: 283–295

    Article  Google Scholar 

  20. Ding Y, Zhang P, Long Z, et al. The elastic module of Ag nanowires prepared from electrochemical deposition. J Alloys Compd, 2009, 474: 223–225

    Article  Google Scholar 

  21. Adamcik J, Berquand A, Mezzenga R. Single-step direct measurement of amyloid fibrils stiffness by peak force quantitative nanomechanical atomic force microscopy. Appl Phys Lett, 2011, 98: 193701

    Article  Google Scholar 

  22. Namazu T, Isono Y, Tanaka T. Evaluation of size effect on mechanical properties of single crystal silicon by nanoscale bending test using AFM. J Microelectromech Syst, 2000, 9: 450–459

    Article  Google Scholar 

  23. Erdem I, Kart H H, Cagin T. High pressure phase transitions in SnO2 polymorphs by first-principles calculations. J Alloys Compd, 2014, 587: 638–645

    Article  Google Scholar 

  24. Gao Q, Jiang H, Li M, et al. Improved mechanical properties of SnO2: F thin film by structural modification. Ceramics Int, 2014, 40: 2557–2564

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Fu Xu or YanHuai Ding.

Electronic supplementary material

11431_2017_9274_MOESM1_ESM.doc

Mechanical properties of individual core-shell-structured SnO2@C nanofibers investigated by atomic force microscopy and finite element method

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, X., Li, K., Duan, X. et al. Mechanical properties of individual core-shell-structured SnO2@C nanofibers investigated by atomic force microscopy and finite element method. Sci. China Technol. Sci. 61, 1144–1149 (2018). https://doi.org/10.1007/s11431-017-9274-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11431-017-9274-6

Keywords

Navigation