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Liquid metal corrosion sculpture to fabricate quickly complex patterns on aluminum

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Abstract

A liquid metal enabled corrosion sculpture technique for quickly fabricating complex patterns on aluminum substrate is proposed and experimentally demonstrated. According to the conceptual investigation, it is clarified that the width and the depth of a printed track are dominated by sculpture time and working temperature. The printed size can reach small values of 38 μm through controlling the sculpture time for 60 s. As the sculpture time was increased from 5 to 25 min at 20°C, the depth of the fabricated pattern was improved from 13.3 to 25.6 μm. The sculptured depth of the pattern would increase from 13.3 to 106.9 μm when the sculpture time was fixed at 5 min and the temperature was raised from 20 to 60°C. To investigate the sculpture behavior in detail, the phases and microstructure of sculpture surface were quantitatively measured via a group of microscope imaging system with fundamental mechanisms interpreted. The present liquid metal sculpture method on aluminum substrate adds a new valuable soft tool for current metal engraving technology family.

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References

  1. Altintas Y, Aksöz S, Keşlioğlu K, et al. Determination of thermodynamic properties of aluminum based binary and ternary alloys. J Alloy Compd, 2015, 649: 453–460

    Article  Google Scholar 

  2. Littman H, Iii M H M. Tensile properties and fracture locations of friction-stir welded joints of 6061-T6 aluminum alloy. J Mater Sci Lett, 2003, 22: 1061-1063

    Article  Google Scholar 

  3. Barlat F, Maeda Y, Chung K, et al. Yield function development for aluminum alloy sheets. J Mech Phys Solids, 1997, 45: 1727–1763

    Article  Google Scholar 

  4. Sajjadi S A, Ezatpour H R, Torabi Parizi M. Comparison of microstructure and mechanical properties of A356 aluminum alloy/Al2O3 composites fabricated by stir and compo-casting processes. Mater Des, 2012, 34: 106–111

    Article  Google Scholar 

  5. Liu X, Tarn T J, Huang F, et al. Recent advances in inkjet printing synthesis of functional metal oxides. Particuology, 2015, 19: 1–13

    Article  Google Scholar 

  6. Mishra A K, Balasubramaniam R. Corrosion inhibition of aluminum by rare earth chlorides. Mater Chem Phys, 2007, 103: 385–393

    Article  Google Scholar 

  7. Haselhuhn A S, Wijnen B, Anzalone G C, et al. In situ formation of substrate release mechanisms for gas metal arc weld metal 3D printing. J Mater Process Tech, 2015, 226: 50–59

    Article  Google Scholar 

  8. Green D E, Neale K W, Mac Ewen S R, et al. Experimental investigation of the biaxial behaviour of an aluminum sheet. Int J Plasticity, 2004, 20: 1677–1706

    Article  MATH  Google Scholar 

  9. Zhang X Q, Li H, Yu X L, et al. Investigation on effect of laser shock processing on fatigue crack initiation and its growth in aluminum alloy plate. Mater Des (1980–2015), 2015, 65: 425–431

    Article  Google Scholar 

  10. Lee S H, Cho B, Yoon S, et al. Printing of sub-100-nm metal nanodot arrays by carbon nanopost stamps. ACS Nano, 2011, 5: 5543–5551

    Article  Google Scholar 

  11. Hwang S Y, Park H H, Kang S M, et al. Fabrication of nanopatterned metal sheet using photolithography and electroplating. Thin Solid Films, 2013, 546: 132–135

    Article  Google Scholar 

  12. Byeon K J, Leea H. Recent progress in direct patterning technologies based on nano-imprint lithography. Eur Phys J Appl Phys, 2012, 59: 10001

    Article  Google Scholar 

  13. Liu T, Burger C, Chu B. Nanofabrication in polymer matrices. Prog Polymer Sci, 2003, 28: 5–26

    Article  Google Scholar 

  14. Zhang J, Fouad M, Yavuz M, et al. Charging effect reduction in electron beam lithography with nA beam current. Microelectronic Eng, 2011, 88: 2196–2199

    Article  Google Scholar 

  15. Vieu C, Carcenac F, Pépin A, et al. Electron beam lithography: Resolution limits and applications. Appl Surface Sci, 2000, 164: 111–117

    Article  Google Scholar 

  16. Tirpanci S, Bürgler D E, Schneider C M, et al. Charging effect reduction in electron beam lithography and observation of single nanopillars on highly insulating substrates. Microelectron Eng, 2015, 140: 33–37

    Article  Google Scholar 

  17. Kathuria Y P. Laser microprocessing of metallic stent for medical therapy. J Mater Process Tech, 2005, 170: 545–550

    Article  Google Scholar 

  18. Madhukar Y K, Mullick S, Nath A K. An investigation on co-axial water-jet assisted fiber laser cutting of metal sheets. Opt Laser Eng, 2016, 77: 203–218

    Article  Google Scholar 

  19. Fu C H, Liu J F, Guo A. Statistical characteristics of surface integrity by fiber laser cutting of Nitinol vascular stents. Appl Surface Sci, 2015, 353: 291–299

    Article  Google Scholar 

  20. Chen Y, Han X, Okada M, et al. Integrative 3D modelling of complex carving surface. Comp-Aided Des, 2008, 40: 123–132

    Article  Google Scholar 

  21. Zhang Q, Gao Y, Liu J. Atomized spraying of liquid metal droplets on desired substrate surfaces as a generalized way for ubiquitous printed electronics. Appl Phys A, 2014, 116: 1091–1097

    Article  Google Scholar 

  22. Wang L, Liu J. Ink spraying based liquid metal printed electronics for directly making smart home appliances. ECS J Solid State Sci Tech, 2015, 4: P3057–P3062

    Article  Google Scholar 

  23. Sivan V, Tang S Y, O’Mullane A P, et al. Liquid metal marbles. Adv Funct Mater, 2013, 23: 144–152

    Article  Google Scholar 

  24. Kurata Y. Corrosion behavior of Si-enriched steels for nuclear applications in liquid lead-bismuth. J Nucl Mater, 2013, 437: 401–408

    Article  Google Scholar 

  25. Rajagopalan M, Bhatia M A, Tschopp M A, et al. Atomic-scale analysis of liquid-gallium embrittlement of aluminum grain boundaries. Acta Mater, 2014, 73: 312–325

    Article  Google Scholar 

  26. Nichols H, Rostoker W. On the mechanism of crack initiation in embrittlement by liquid metals. Acta Metall, 1961, 9: 504–509

    Article  Google Scholar 

  27. Hagström J, Mishin O V, Hutchinson B. Gallium enhanced microscopy for revealing grain boundaries and dislocation subboundaries in aluminium alloys. Scripta Mater, 2003, 49: 1035–1040

    Article  Google Scholar 

  28. Tuck C D S. The Electrochemical Behavior of Al-Ga Alloys in Alkaline and Neutral Electrolytes. J Electrochem Soc, 1987, 134: 2970

    Article  Google Scholar 

  29. Parmuzina A V, Kravchenko O V. Activation of aluminum metal to evolve hydrogen from water. Int J Hydrogen Energ, 2008, 33: 3073–3076

    Article  Google Scholar 

  30. Deng Y G, Liu J. Corrosion development between liquid gallium and four typical metal substrates used in chip cooling device. Appl Phys A, 2009, 95: 907–915

    Article  Google Scholar 

  31. Trenikhin M V, Bubnov A V, Nizovskii A I, et al. Chemical interaction of the In-Ga eutectic with Al and Al-base alloys. Inorg Mater, 2006, 42: 256–260

    Article  Google Scholar 

  32. Laidler K J. The development of the Arrhenius equation. J Chem Educ, 1984, 61: 494–498

    Article  Google Scholar 

  33. Krumpelt M, Kumar R, Myles K M. Fundamentals of fuel cell system in integration. J Power Sources, 1994, 49: 37–51

    Article  Google Scholar 

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Lu, J., Yi, L., Wang, L. et al. Liquid metal corrosion sculpture to fabricate quickly complex patterns on aluminum. Sci. China Technol. Sci. 60, 65–70 (2017). https://doi.org/10.1007/s11431-016-0433-9

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  • DOI: https://doi.org/10.1007/s11431-016-0433-9

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