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Use of lime mud from paper mill as a heterogeneous catalyst for transesterification

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Abstract

Lime mud (LM), a solid waste from the paper mill, is used as an economic and environmental friendly heterogeneous basic catalyst for transesterification, which is accompanied by characterization of X-ray fluorescence, thermogravimetric-differential thermal analysis, X-ray diffraction, N2 adsorption, and Hammett indicator method. To investigate the performance of the achieved catalyst, which is activated through calcination, the aspects of calcination temperature, reaction time, mole ratio of methanol to oil, catalyst addition percentage, and reaction temperature are concerned. Characterization of catalyst reveals that LM could be activated through calcination to transform the carbonate and hydrate of calcium into the oxide forms and higher calcination temperature could lead to stronger basic strength. However, N2 adsorption results indicate that higher temperature causes the sintering of the catalyst and shrinkage of the catalyst grains. When LM is activated at 800°C (LM-800) and the reaction is carried out at 64°C with a methanol to oil mole ratio of 15:1, catalyst addition percentage of 6%, and reaction time of 2 h, the maximum transesterification conversion of 94.35% could be achieved. Reusability of LM-800 is also investigated compared with laboratory grade CaO in five reaction cycles and the results indicate that the catalysts derived from LM can be used as an economic and efficient catalyst for biodiesel production.

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References

  1. Hu S Y, Wang Y, Han H Y. Utilization of waste freshwater mussel shell as an economic catalyst for biodiesel production. Biomass Bioenergy, 2011, 35: 3627–3635

    Article  Google Scholar 

  2. Zhang X S, Zhao H, Hu Z J, et al. Effect of biodiesel on the particle size distribution in the exhaust of common-rail diesel engine and the mechanism of nanoparticle formation. Sci China Tech Sci, 2009, 52: 2773–2778

    Article  Google Scholar 

  3. Kouzu M, Kasuno T, Tajika M, et al. Active phase of calcium oxide used as solid base catalyst for transesterification of soybean oil with refluxing methanol. Appl Catal A, 2008, 334: 357–365

    Article  Google Scholar 

  4. Liu X J, Piao X L, Wang Y J, et al. Calcium methoxide as a solid base catalyst for the transesterification of soybean oil to biodiesel with methanol. Fuel, 2008, 87: 1076–1082

    Article  Google Scholar 

  5. Viriya-empikul N, Krasae P, Nualpaeng W, et al. Biodiesel production over Ca-based solid catalysts derived from industrial wastes. Fuel, 2012, 92: 239–244

    Article  Google Scholar 

  6. Kumar D, Kumar G, Poonam, et al. Fast, easy ethanolysis of coconut oil for biodiesel production assisted by ultrasonication. Ultrason Sonochem, 2010, 17: 555–559

    Article  Google Scholar 

  7. Arzamendi G, Campo I, Arguiñarena E, et al. Synthesis of biodiesel with heterogeneous NaOH/alumina catalysts: Comparison with homogeneous NaOH. Chem Eng J, 2007, 134: 123–130

    Article  Google Scholar 

  8. Chen K S, Lin Y C, Hsu K H, et al. Improving biodiesel yields from waste cooking oil by using sodium methoxide and a microwave heating system. Energy, 2012, 38: 151–156

    Article  Google Scholar 

  9. Li Q, Zheng J J, Yan Y J. Biodiesel preparation catalyzed by compound-lipase in co-solvent. Fuel Process Technol, 2010, 91: 1229–1234

    Article  Google Scholar 

  10. Wang C W, Chen W, Wang W G, et al. Experimental study on methanol recovery through flashing vaporation in continuous production of biodiesel via supercritical methanol. Energy Convers Manage, 2011, 52: 1454–1458

    Article  Google Scholar 

  11. Liu X J, He H Y, Wang Y J, et al. Transesterification of soybean oil to biodiesel using SrO as a solid base catalyst. Catal Commun, 2007, 8: 1107–1111

    Article  Google Scholar 

  12. Dossin T F, Reyniers M-F, Berger R J, et al. Simulation of heterogeneously MgO-catalyzed transesterification for fine-chemical and biodiesel industrial production. Appl Catal B, 2006, 67: 136–148

    Article  Google Scholar 

  13. Gomes J F P, Puna J F B, Gonçalves L M, et al. Study on the use of MgAl hydrotalcites as solid heterogeneous catalysts for biodiesel production. Energy, 2011, 36: 6770–6778

    Article  Google Scholar 

  14. Ren Y B, He B Q, Yan F, et al. Continuous biodiesel production in a fixed bed reactor packed with anion-exchange resin as heterogeneous catalyst. Bioresour Technol, 2012, 113: 19–22

    Article  Google Scholar 

  15. Kouzu M, Kasuno T, Tajika M, et al. Calcium oxide as a solid base catalyst for transesterification of soybean oil and its application to biodiesel production. Fuel, 2008, 87: 2798–2806

    Article  Google Scholar 

  16. Reddy C R V, Oshel R, Verkade J G. Room-temperature conversion of soybean oil and poultry fat to biodiesel catalyzed by nanocrystalline calcium oxides. Energy Fuels, 2006, 20: 1310–1314

    Article  Google Scholar 

  17. Boey P-L, Maniam G P, Hamid S A. Biodiesel production via transesterification of palm olein using waste mud crab (scylla serrata) shell as a heterogeneous catalyst. Bioresour Technol, 2009, 100: 6362–6368

    Article  Google Scholar 

  18. Chakraborty R, Bepari S, Banerjee A. Application of calcined waste fish (labeo rohita) scale as low-cost heterogeneous catalyst for biodiesel synthesis. Bioresour Technol, 2011, 102: 3610–3618

    Article  Google Scholar 

  19. Nakatani N, Takamori H, Takeda K, et al. Transesterification of soybean oil using combusted oyster shell waste as a catalyst. Bioresour Technol, 2009, 100: 1510–1513

    Article  Google Scholar 

  20. Li Y J, Sun R Y, Liu C T, et al. CO2 capture by carbide slag from chlor-alkali plant in calcination/carbonation cycles. Int J Greenhouse Gas Control, 2012, 9: 117–123

    Article  Google Scholar 

  21. Cheng J, Zhou J H, Liu J Z, et al. Physicochemical characterizations and desulfurization properties in coal combustion of three calcium and sodium industrial wastes. Energy Fuels, 2009, 23: 2506–2516

    Article  Google Scholar 

  22. Sun R Y, Li Y J, Liu C M, et al. Utilization of lime mud from paper mill as CO2 sorbent in calcium looping process. Chem Eng J, 2013, 221: 124–132

    Article  Google Scholar 

  23. Li Y J, Sun RY, Zhao J L, et al. Sulfation behavior of white mud from paper manufacture as SO2 sorbent at fluidized bed combustion temperatures. J Therm Anal Calorim, 2011, 107: 241–248

    Article  Google Scholar 

  24. Han K H, Zhao J L, Zheng B, et al. Sulfur retention performance and modification of alkaline wastes used in coal combustion. J China Coal Soc, 2009, 34: 1697–1702

    Google Scholar 

  25. Modolo R, Benta A, Ferreira V M, et al. Pulp and paper plant wastes valorisation in bituminous mixes. Waste Manage, 2010, 30: 685–696

    Article  Google Scholar 

  26. Niu S L, Li H, Lu C M, et al. Catalytic performance of papermaking white clay in the transesterification of peanut oil with methanol. J Fuel Chem Technol, 2013, 41: 1–6

    Article  Google Scholar 

  27. Li S L, Liu S Q, Li D Z, et al. Determination of biodiesel conversion rate by spectrophotometry. Yunnan Chem Technol, 2009, 36: 71–73

    Google Scholar 

  28. Niu S L, Liu M Q, Lu C M, et al. Thermogravimetric analysis of carbide slag: A potential transesterification catalyst validation. J Therm Anal Calorim, 2013, doi: 10. 1007/s10973-013-3268-z

    Google Scholar 

  29. Zhao G J, Lu C M, Tian Y, B. et al. Test study of thermo analysis for calcination and sulfur fixation performance of calciferous waste material. Boiler Technol, 2007, 38: 69–73

    Google Scholar 

  30. Kouzu M, Hidaka J-S. Transesterification of vegetable oil into biodiesel catalyzed by CaO: A review. Fuel, 2012, 93: 1–12

    Article  Google Scholar 

  31. Roschat W, Kacha M, Yoosuk B, et al. Biodiesel production based on heterogeneous process catalyzed by solid waste coral fragment. Fuel, 2012, 98: 194–202

    Article  Google Scholar 

  32. Obadiah A, Swaroopa G A, Kumar S V, et al. Biodiesel production from Palm oil using calcined waste animal bone as catalyst. Bioresour Technol, 2012, 116: 512–516

    Article  Google Scholar 

  33. Taufiq-Yap Y H, Lee H V, Hussein M Z, et al. Calcium-based mixed oxide catalysts for methanolysis of Jatropha curcas oil to biodiesel. Biomass Bioenergy, 2011, 35: 827–834

    Article  Google Scholar 

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Authors and Affiliations

  1. School of Energy and Power Engineering, National Engineering Laboratory for Coal-Burning Pollutants Emission Reduction, Shandong University, Jinan, 250061, China

    Hui Li, ShengLi Niu, ChunMei Lu, MengQi Liu & MengJia Huo

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  1. Hui Li
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  2. ShengLi Niu
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  3. ChunMei Lu
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  4. MengQi Liu
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  5. MengJia Huo
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Correspondence to ChunMei Lu.

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Li, H., Niu, S., Lu, C. et al. Use of lime mud from paper mill as a heterogeneous catalyst for transesterification. Sci. China Technol. Sci. 57, 438–444 (2014). https://doi.org/10.1007/s11431-013-5440-x

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  • DOI: https://doi.org/10.1007/s11431-013-5440-x

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