Skip to main content
Log in

Preparation of patterned SiC and SiCN microstructures

  • Published:
Science in China Series E Aims and scope Submit manuscript

Abstract

Patterned SiC and SiCN microstructures were successfully fabricated on the silicon substrates by using polydimethylsiloxane (PDMS) elastometric stamp as template, polycarbosilane (PCS) and polysilazane (PSZ) as preceramic polymers. The preparing process was followed by precursor infiltration, the curing of the precursor, demolding of the template and pyrolysis of the cured preceramic polymer pattern. It shows that the dimensions of the ceramic patterns can be tailored by using the PDMS molds with different dimensions. The produced ceramic microstructures can be potentially applied in high temperature and high pressure environments due to the advanced properties of the SiC and SiCN ceramics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Cark, R. A., Hieptas, P. B., Ewing, A. G., Electrochemical analysis in picoliter microvials, Anal. Chem., 1997, 69: 259–263.

    Google Scholar 

  2. Brambley, D., Martin, B., Prewett, P. D., Microlithography: An overview, Adv. Mater. Opt. Electron., 1994, 4: 55–75.

    Article  Google Scholar 

  3. Mouradian, S., Lab-on-a-chip: Applications in proteomics, Current Opin. in Chem. Bio., 2002, 6: 51–56.

    Google Scholar 

  4. Weigl, B. H., Bardell, R. L., Cabrera, C. R., Lab-on-a-chip for drug development, Adv. Drug. Delivery Rev., 2003, 55: 349–377.

    Article  Google Scholar 

  5. Okazaki, S., Resolution limits of optical lithography, J. Vac. Sci. Technol. B, 1991, 9: 2829–2833.

    Article  Google Scholar 

  6. Moreau, W. M., Semiconductor Lithography: Principles and Materials, New York: Plenum, 1988.

    Google Scholar 

  7. Lee, W., Le, J. K., Non-lithographic approach to the fabrication of polymeric nanostructures with a close-packed 2D hexagonal array, Adv. Mater, 2002, 14: 1187–1190.

    Google Scholar 

  8. Pease, R. F. W., Nanolithography and its prospects as a manufacturing technology, J. Vac. Sci. Technol. B, 1992, 10: 278–285.

    Article  Google Scholar 

  9. Cerrina, F., Marrian, C., A path to nanolithography, MRS Bull., 1996, 21: 56–62.

    Google Scholar 

  10. Whitesides, G. M., Laibinis, P. E., Wet chemical approaches to the characterization of organic surfaces: self-assembled monolayers, wetting, and the physical-organic chemistry of the solid-liquid interface, Langmui, 1990, 6: 87–96.

    Google Scholar 

  11. Xia, Y., Kim, E., Zhao, X. M. et al., Complex optical surfaces formed by replica molding against elastomeric masters, Science, 1996, 273: 347–349.

    Google Scholar 

  12. Kumar, A., Whitesides, G. M., Features of gold having micrometer to centimeter dimensions can be formed through a combination of stamping with an elastomeric stamp and an alkanethiol “ink” followed by chemical etching, Appl. Phys. Lett., 1993, 63: 2002–2004.

    Google Scholar 

  13. Kim, E., Xia, Y., Whitesides, G. M., Polymer microstructures formed by moulding in microcapillaries, Nature, 1995, 376: 581–584.

    Google Scholar 

  14. Zhao, X. M., Xia, Y., Whitesides, G. M., Fabrication of three dimensional microstructures: Microtransfer molding, Adv. Mater., 1996, 8: 837–840.

    Google Scholar 

  15. King, E., Xia, Y., Zhao, X. M. et al., Solvent-assisted microcontact molding: A convenient method for fabricating three-dimensional structures on surfaces of polymers, Adv. Mater., 1997, 9: 651–654.

    Article  Google Scholar 

  16. Duffy, D. C., McDonald, J. C., Schueller, O. J. et al., Rapid prototyping of microfluidic systems in poly(dimethylsiloxane), Anal. Chem., 1998, 70: 4974–4984.

    Article  Google Scholar 

  17. Yajima, S., Hasegawa, Y., Hayashi, J. et al., Synthesis of continuous silicon carbide fiber with high tensile strength and high young’s modulus, J. Mater. Sci., 1978, 13: 2569–2576.

    Google Scholar 

  18. Wang, H., Li, X. D., Peng, P. et al., Thermostatic pyrolysis process of cured polycarbosilane fiber, Korea J. Chem. Eng., 2003, 20(3): 587–591.

    Google Scholar 

  19. Ziegler, G., Kleebe, H. J., Motz, G. et al., Synthesis, microstructure and properties of SiCN ceramics prepared from tailored polymers, Mater. Chem. Phys., 1999, 2056: 1–9.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Wang Hao or Kim Dong-pyo.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, H., Sung, Ik., Li, X. et al. Preparation of patterned SiC and SiCN microstructures. SCI CHINA SER E 49, 164–171 (2006). https://doi.org/10.1007/s11431-006-0164-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11431-006-0164-9

Keywords

Navigation