Abstract
The temporal decay of the oxidation of methane (CH4-O2 reaction) over palladium supported on silica is determined experimentally at different temperatures, comparing the results with those of various classical models which show the behavior of the adsorbed phase as the cause of the phenomenon. This effect is visualized through Monte Carlo simulations of the CH4-O2 reaction on a mixed lattice whose partial poisoning, due to the configuration of the OH groups on the surface of the adsorbate, is translated into a gradual decay of the reaction’s activity.
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References
Taylor KC. Nitric oxide catalysis in automotive exhaust systems. Catal Rev Sci Eng, 1993, 35: 457–481
Shelef M, Graham G. Why rhodium in automotive three-way catalysts? Catal Rev Sci Eng, 1986, 36: 433–457
Schmitz RA. Intrinsically unstable behavior during the oxidation of carbon monoxide on platinum. Catal Rev Sci Eng, 1986, 28: 89–164
Gelin P, Primet M. Complete oxidation of methane at low temperature over noble metal based catalysts: A review. Appl Catal B-Environ, 2002, 39: 1–37
Choudhary TV, Banerjee S, Choudhary VR. Catalysts for combustion of methane and lower alkanes. Appl Catal A-Gen, 2002, 234: 1–23
Persson K, Jansson K, Jaras SG. Characterization and microstructure of Pd and bimetallic Pd-Pt catalysts during methane oxidation. J Catal, 2007, 245: 401–414
Demoulin O, Navez M, Ruiz P. Origin of transient species present on the surface of a PdO/Al2O3 catalyst during the methane combustion reaction. Catal Today, 2006, 12: 153–156
Okumura K, Shinohara E, Niwa M. Loaded on high silica beta support active for the total oxidation of diluted methane in the presence of water vapor. Catal Today, 2006, 117: 577–583
Persson K, Pfefferle LD, Schwartz W, Ersson A, Järås SG. Stability of palladium-based catalysts during catalytic combustion of methane: The influence of water. Appl Catal B-Environ, 2007, 74: 242–250
Ciuparu D, Lyubovsky RL, Altman E, Pfefferle LD. Catalytic combustion of methane over palladium-based catalysts. Catal Rev, 2002, 44: 593–649
Cortés J, Valencia E, Araya P. Two-site mechanism for the oxidation reaction of methane on oxidized palladium. J Phys Chem C, 2010, 114: 11441–11447
Cortés J, Valencia E, Aguila G, Orellana E, Araya P. Time decay of the activity of the reduction reaction of NO by CO on a Pd/Al2O3 catalyst. Catal Lett, 2008, 126: 63–71
Eley DD, Rideal EK. The catalisis of the parahydrogen conversión by tungsten. Proc R Soc London A, 1941, A178: 429–451
Ogunye AF, Ray WH. Optimization of cyclic tubular reactors with catalyst decay. Ind Eng Chem Process Des Dev, 1971, 10: 410–416
Pease RN, Steward LY. The catalytic combination of ethylene and hydrogen in the presence of metallic copper III carbon monoxide as a catalyst poison. J Am Chem Soc, 1925, 47: 1235–1240
Ogunye AF, Ray WH. Optimization of a vinyl chloride monomer reactor. Ind Eng Chem Process Des Dev, 1970, 9: 619–624
Voorhies Jr A. Carbon formation in catalytic cracking. Ind Eng Chem Res, 1945, 37: 318–322
Araya P, Guerrero S, Robertson J, Gracia FG. Methane combustion over Pd/SiO2 catalysts with different degrees of hydrophobicity. Appl Catal A-Gen, 2005, 283: 225–233
Maffucci L, Lengo P, Di Serio M, Santacesaria E. A rapid method for the evaluation of the dispersion of palladium in supported catalysts. J Catal, 1997, 172: 485–487
Cortés J, Puschmann H, Valencia E. On the pair approximation method in a nonreactive catalytic system. J Chem Phys, 1996, 105: 6026–6031
Cortés J, Puschmann H, Valencia E. Mean field hierarchical equations model for the A+BC catalitic reaction. J Chem Phys, 1998, 109: 6086–6091
Cortés J, Valencia E. Brosilow-Ziff model for the CO-NO surface reaction on disordered two and three-dimensional substrates. Phys Rev E, 2003, 68: 16111–16119
Cortés J, Valencia E, Herrera J, Araya P. Mechanism and kinetics parameters of the reduction reaction of NO by CO on Pd/Al2O3 Catalyst. J Phys Chem C, 2007, 111: 7063–7071
Cortés J, Valencia E, Araya P. Monte Carlo simulation studies of the catalytic combustion of methane. Catal Lett, 2006, 112: 121–128
Garbowski E, Feumi-Jantou Ch, Mouaddib N, Primet M. Catalytic combustion of methane over palladium supported on alumina catalysts. Evidence for reconstruction of particles. Appl Catal A-Gen, 1994, 109: 277–291
van Giezen JC, van den Berg FR, Kleinen JL, van Dillen AJ, Geus JW. The effect of water on the activity of supported palladium catalysts in the catalytic combustion of methane. Catal Today, 1999, 47: 287–293
Monteiro RS, Zemlyanov D, Storey JM, Ribeiro FH. Turnover rate and reaction orders for the complete oxidation of me thane on a palladium foil in excess dioxygen. J Catal, 2001, 199: 291–301
van Giezen JC, van den Berg FR, Kleinen JL, van Dillen AJ, Geus JW. The effect of water on the activity of supported palladium catalysts in the catalytic combustion of methane. Catalysis Today, 1999, 47: 287–293
Au-Yeung J, Chen K, Bell AT, Iglesia E. Isotopic studies of methane oxidation pathways on PdO catalysts. J Catal, 1999, 188: 132–139
Fujimoto K, Ribeiro FH, Avalos-Borja M, Iglesia E. Structure and reactivity of PdOx/ZrO2 catalysts for methane oxidation at low temperatures. J Catal, 1998, 179: 431–442
Carstens JN, Su SC, Bell AT. Factors affecting the catalytic activity of Pd/ZrO2 for the combustion of methane. J Catal, 1998, 176: 136–142
Araya P, Guerrero S, Robertson J, Gracia FJ. Methane combustion over Pd/SiO2 catalysts with different degrees of hydrophobicity. Appl Catal A-Gen, 2005, 283: 225–233
Hurtado P, Ordoñez S, Sastre H, Díez FV. Development of a kinetic model for the oxidation of methane over Pd/Al2O3 at dry and wet conditions. Appl Catal B-Eviron, 2004, 51: 229–238
Cortés J, Valencia E. Configuration of adsorbed phases and their evolution to adsorbed states in the CH4-O2 catalytic reaction. B Chem Soc Jpn, 2009, 82: 683–688
Brosilow BJ, Ziff RM. Comment on NO-CO reaction on square and hexagonal surfaces: A Monte Carlo simulation. J Catal, 1992, 136: 275–278
Meng B, Weinberg WH, Evans JW. Transitions in the kinetics and steady states of irreversible A+BC surface-reaction models. Phys Rev E, 1993, 48: 3577–3588
Cortés J, Valencia E. Brosilow-Ziff model for the CO-NO surface reaction on disordered two and three-dimensional substrates. Phys Rev E, 2003, 68: 16111–16119
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Cortés, J., Valencia, E., Pineda, M. et al. Temporal decay of the catalytic oxidation of methane over palladium supported on silica. Sci. China Chem. 56, 1601–1607 (2013). https://doi.org/10.1007/s11426-013-4969-7
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DOI: https://doi.org/10.1007/s11426-013-4969-7