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Cyanide-bridged WVMnIII single-chain magnet based on an octacoordinate [W(CN)6(phen)]− anion

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  • Special Topic · Molecular Magnetism
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Abstract

Reaction of unique [W(CN)6(phen)− with a magnetically anisotropic Mn Schiff base yielded a WV(5d)-MnIII(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.

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Authors and Affiliations

  1. Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul, 136-713, Korea

    JinWuk Lee, KwangSoo Lim, JungHee Yoon, DaeWon Ryu, BongHo Koo & ChangSeop Hong

  2. Nano-Bio System Research Team, Korea Basic Science Institute, Seoul, 136-713, Korea

    EuiKwan Koh

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  1. JinWuk Lee
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  2. KwangSoo Lim
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  3. JungHee Yoon
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Correspondence to ChangSeop Hong.

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Lee, J., Lim, K., Yoon, J. et al. Cyanide-bridged WVMnIII single-chain magnet based on an octacoordinate [W(CN)6(phen)]− anion. Sci. China Chem. 55, 1012–1017 (2012). https://doi.org/10.1007/s11426-012-4539-4

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  • DOI: https://doi.org/10.1007/s11426-012-4539-4

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