Skip to main content
SpringerLink
Log in

Hydrothermal synthesis, structure, fluorescence property of a novel 3D metal-organic framework with high thermal stability

  • Articles
  • Special Topic · Coordination Polymer
  • Published:
Science China Chemistry Aims and scope Submit manuscript

Abstract

A novel 3D metal-organic framework (MOF) with remarkable thermal stability, Ni(BIC)2·2.5H2O (JUC-86) (HBIC = 1-H-benzimidazole-5-carboxylic acid and JUC = Jilin University China), has been synthesized under hydrothermal conditions. It crystallizes in tetragonal symmetry with P43212 space group. The 3D structure consists of channels assembled from triple helices with a 4.5 × 4.5 Å2 aperture, which are formed by the parallel alignment of three infinite helical chains. The thermogravimetric analysis (TGA) and powder X-ray diffractions (PXRD) indicate JUC-86 with high thermal stability (up to 350 °C).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ockwig NW, Delgado-Friedrichs O, O’Keeffe M, Yaghi OM. Reticular chemistry: Occurrence and taxonomy of nets, and grammar for the design of frameworks. Acc Chem Res, 2005, 38: 176–182

    Article  CAS  Google Scholar 

  2. Férey G, Mellot-Drazneiks C, Serre C, Millange F, Dutour J, Surblé S, Margiolaki I. A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science, 2005, 309: 2040–2042

    Article  Google Scholar 

  3. Bureekaew S, Shimomura S, Kitagawa S. Chemistry and application of flexible porous coordination polymers. Sci Technol Adv Mater, 2008, 9: 1–12

    Article  Google Scholar 

  4. Chen Q, Lin JB, Xue W, Zeng MH, Chen XM. A porous coordination polymer assembled from 8-connected {CoII 3(OH)} clusters and isonicotinate: Multiple active metal sites, apical ligand substitution, H2 adsorption, and magnetism. Inorg Chem, 2011, 50: 2321–2328

    Article  CAS  Google Scholar 

  5. Xiang SC, Zhou W, Gallegos JM, Liu Y, Chen BL. Exceptionally high acetylene uptake in a microporous metal-organic framework with open metal sites. J Am Chem Soc, 2009, 131: 12415–12419

    Article  CAS  Google Scholar 

  6. Zhang SM, Chang Z, Hu TL, Bu XH. New three-dimensional porous metal organic framework with tetrazole functionalized aromatic carboxylic acid: synthesis, structure, and gas adsorption properties. Inorg Chem, 2010, 49: 11581–11586

    Article  CAS  Google Scholar 

  7. Ma LQ, Jin A, Xie ZG, Lin WB. Freeze drying significantly increases permanent porosity and hydrogen uptake in 4, 4-connected metal-organic frameworks. Angew Chem Int Ed, 2009, 121: 10089–10092

    Google Scholar 

  8. Li JR, Kuppler RJ, Zhou HC. Selective gas adsorption and separation in metal-organic frameworksw. Chem Soc Rev, 2009, 38: 1477–1504

    Article  CAS  Google Scholar 

  9. Zhao JP, Hu BW, Zhang XF, Yang Q, Fallah MSE, Ribas J, Bu XH. One pot synthesis of heterometallic 3d-3d azide coordination architectures: effect of the single-ion anisotropy. Inorg Chem, 2010, 49: 11325–11332

    Article  CAS  Google Scholar 

  10. Zheng YZ, Tong ML, Zhang WX, Chen XM. Assembling magnetic nanowires into networks: a layered CoII carboxylate coordination polymer exhibiting single-chain-magnet behavior. Angew Chem Int Ed, 2006, 45: 6310–6314

    Article  CAS  Google Scholar 

  11. Xue M, Zhu GS, Zhang YJ, Fang QR, Hewitt IJ, Qiu SL. Rational design and control of the dimensions of channels in a series of 3D pillared metal-organic frameworks: Synthesis, structures, adsorption, and luminescence properties. Crystal Growth & Design, 2008, 8: 427–434

    Article  CAS  Google Scholar 

  12. Cao GJ, Zheng ST, Zhao N, Sun JK, Yang GY. Metal-organogermanate frameworks built by two kinds of infinite Ge-O chains with high thermostability and luminescent properties. Inorg Chem, 2010, 49: 10211–10213

    Article  CAS  Google Scholar 

  13. Cui P, Chen Z, Gao DL, Zhao B, Shi W, Cheng P. Syntheses, structures, and photoluminescence of a series of three-dimensional Cd(II) frameworks with a flexible ligand,1,5-bis(5-tetrazolo)-3-oxapentane. Crystal Growth & Design, 2010, 10: 4370–4378

    Article  CAS  Google Scholar 

  14. Fu H, Li YG, Lu Y, Chen WL, Wu Q, Meng JX, Wang XL, Zhang ZM, Wang EB. Polyoxometalate-based metal-organic frameworks assembled under the ionothermal conditions. Crystal Growth & Design, 2011, 11: 458–465

    Article  CAS  Google Scholar 

  15. Férey G. Hybrid porous solids: Past, present, future. Chem Soc Rev, 2008, 37: 191–214

    Article  Google Scholar 

  16. Serre C, Millange F, Thouvenot C, Noguès M, Marsolier G, Louër D, Férey G. Very large breathing effect in the first nanoporous chromium( III)-based solids: MIL-53 or CrIII(OH)·{O2C-C6H4-CO2}· {HO2C-C6H4-CO2H}·H2Oy. J Am Chem Soc, 2002, 124: 13519–13526

    Article  CAS  Google Scholar 

  17. Loiseau T, Serre C, Huguenard C, Fink G, Taulelle F, Henry M, Bataille T, Férey G. A rationale for the large breathing of the porous aluminum terephthalate (MIL-53) upon hydration. Chem Eur J, 2004, 10: 1373–1382

    Article  CAS  Google Scholar 

  18. Volkringer C, Meddouri M, Loiseau T, Guillou N, Marrot J, Férey G, Haouas M, Taulelle F, Audebrand N, Latroche M. The kagomé topology of the gallium and indium metal-organic framework types with a MIL-68 structure: Synthesis, XRD, solid-state NMR characterizations, and hydrogen adsorption. Inorg Chem, 2008, 47: 11892–11901

    Article  CAS  Google Scholar 

  19. Park KS, Ni Z, Côté AP, Choi JY, Huang R, Uribe-Romo FJ, Chae HK, O’Keeffe M, Yaghi OM. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. Proc Nal Acad Soc, 2006, 103: 10186–10191

    Article  CAS  Google Scholar 

  20. Hayashi H, Côté AP, Furukawa H, O’Keeffe M, Yaghi OM. Zeolite a imidazolate frameworks. Nat Mater, 2007, 6: 501–506

    Article  CAS  Google Scholar 

  21. Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O’Keeffe M, Yaghi OM. High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture. Science, 2008, 319: 939–943

    Article  CAS  Google Scholar 

  22. Morris W, Leung B, Furukawa H, Yaghi OK, He N, Hayashi H, Houndonougbo Y, Asta M, Laird BB, Yaghi OM. A combined experimental-computational investigation of carbon dioxide capture in a series of isoreticular zeolitic imidazolate frameworks. J Am Chem Soc, 2010, 132: 11006–11008

    Article  CAS  Google Scholar 

  23. Eddaoudi M, Moler DB, Li H, Chen BL, Reineke TM, O’Keeffe M, Yaghi OM. Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks. Acc Chem Res, 2001, 34: 319–330

    Article  CAS  Google Scholar 

  24. Fang QR, Zhu GS, Shi X, Wu G, Tian G, Wang RW, Qiu SL. Synthesis, structure and fluorescence of a novel three-dimensional inorganic-organic hybrid polymer constructed from trimetallic clusters and mixed carboxylate ligands. J Solid State Chem, 2004, 177: 1060–1066

    Article  CAS  Google Scholar 

  25. Liu Z, Chen Y, Liu P, Wang J, Huang MH. Cadmium(II) and cobalt( II) complexes generated from benzimidazole-5-carboxylate: self-assembly by hydrogen bonding and π-π interactions. J Solid State Chem, 2005, 178: 2306–2312

    Article  CAS  Google Scholar 

  26. Guo ZG, Yuan DQ, Bi WH, Li XJ, Wang YQ, Cao R. A novel antiferromagnetic nickel coordination framework with 1-H-benzimidazole-5-carboxylic acid. J Mol Struct, 2006, 782: 106–109

    Article  CAS  Google Scholar 

  27. Guo ZG, Li XJ, Gao SY, Li YF, Cao R. A new three-dimensional supramolecular network, [Cd(Hbic)2(H2O)]·(4,4′-bpy)·H2O (H2bic = 1-H-benzimidazole-5-carboxylic acid; 4,4′-bpy = 4,4′-bipyridine): synthesis, crystal structure and luminescence property. J Mol Struct, 2007, 846: 123–127

    Article  CAS  Google Scholar 

  28. Guo ZG, Cao R, Li XJ, Yuan DQ, Bi WH, Zhu XD, Li YF. A series of cadmium(II) coordination polymers synthesized at different pH values. Eur J Inorg Chem, 2007, 742: 742–748

    Article  Google Scholar 

  29. Meng WW, Chen JX. Synthesis and crystal structures of new nickel( II) and manganese(II) coordination polymers containing 5-benzimidazolecarboxylate ligand. Chinese J Inorg Chem, 2008, 24: 1610–1614

    CAS  Google Scholar 

  30. Peng G, Qiu YC, Liu ZH, Liu B, Deng H. Spontaneous assembly of d-f coordination frameworks: syntheses, structures, and photoluminescence. Crystal Growth & Design, 2010, 10: 114–121

    Article  CAS  Google Scholar 

  31. Sheldrick GM. SADABS, Program for Empirical Absorption Correction For Area Detector Data. Göttingen: University of Göttingen, 1996

    Google Scholar 

  32. Sheldrick GM. SHELXS 97, Program for Crystal Structure Refinement. Göttingen: University of Göttingen, 1997

    Google Scholar 

  33. Spek AL. Single-crystal structure validation with the program PLATON. J Appl Crystallogr, 2003, 36: 7–13

    Article  CAS  Google Scholar 

  34. Bonino F, Chavan S, Vitillo JG, Groppo E, Agostini G, Lamberti C, Dietzel PDC, Prestipino C, Bordiga S. Local structure of CPO-27-Ni metallorganic framework upon dehydration and coordination of NO. Chem Mater, 2008, 20: 4957–4968

    Article  CAS  Google Scholar 

  35. Feng Y, Yang EC, Fu M, Zhao XJ. An unusual linear trinuclear NiII-based MOF with an unprecedented μ 4-κ 2N1,N5:κ 1N2:κ 1N6 binding mode by 5-(pyrazinyl)tetrazolate ligand. Z Anorg Allg Chem, 2010, 636: 253–257

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun, 130012, China

    Lei Wu, Ming Xue, Lin Huang & ShiLun Qiu

Authors
  1. Lei Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ming Xue
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Lin Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. ShiLun Qiu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to ShiLun Qiu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wu, L., Xue, M., Huang, L. et al. Hydrothermal synthesis, structure, fluorescence property of a novel 3D metal-organic framework with high thermal stability. Sci. China Chem. 54, 1441–1445 (2011). https://doi.org/10.1007/s11426-011-4321-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11426-011-4321-z

Keywords

Search

Navigation