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Supported noble metal nanoparticles as photo/sono-catalysts for synthesis of chemicals and degradation of pollutants

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  • Special Topic · Inorganic Solid State Chemistry and Energy Materials
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Abstract

This review summarizes the utilization of supported noble metal nanoparticles (such as Au/TiO2, Au/ZrO2, Ag/AgCl) as efficient photo/sono-catalysts for the selective synthesis of chemicals and degradation of environmental pollutants. Supported noble metal nanoparticles could efficiently catalyze the conversion of solar energy into chemical energy. Under UV/visible light irradiation, important chemical transformations such as the oxidation of alcohols to carbonyl compounds, the oxidation of thiol to disulfide, the oxidation of benzene to phenol, and the reduction of nitroaromatic compounds to form aromatic azo compounds, are effectively achieved by supported noble metal nanoparticles. Under ultrasound irradiation, supported noble metal nanoparticles could efficiently catalyze the production of hydrogen from water. Moreover, various pollutants, including aldehydes, alcohols, acids, phenolic compounds, and dyes, can be effectively decomposed over supported noble metal nanoparticles under UV/visible light irradiation. Under ultrasound irradiation, pollutant molecules can also be completely degraded with supported noble metal nanoparticles as catalysts.

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Authors and Affiliations

  1. Beijing National Laboratory for Molecular Sciences; Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China

    Bo Wen, JiaHai Ma, ChunCheng Chen, WanHong Ma & JinCai Zhao

  2. College of Chemistry and Chemical Engineering, Graduate University of Chinese Academy of Sciences, Beijing, 100049, China

    JiaHai Ma

  3. Chemistry Discipline, Queensland University of Technology, Brisbane, Qld, 4001, Australia

    HuaiYong Zhu

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  1. Bo Wen
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  2. JiaHai Ma
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  6. JinCai Zhao
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Correspondence to JinCai Zhao.

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Wen, B., Ma, J., Chen, C. et al. Supported noble metal nanoparticles as photo/sono-catalysts for synthesis of chemicals and degradation of pollutants. Sci. China Chem. 54, 887–897 (2011). https://doi.org/10.1007/s11426-011-4292-0

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  • DOI: https://doi.org/10.1007/s11426-011-4292-0

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