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Hydrothermal syntheses and structural characterizations of three polyoxomolybdates frameworks linked by M(HL)2 units (M = Co, Ni, Zn; L = 3-(2-pyridyl)pyrazole)

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Abstract

Three polyoxomolybdate compounds, namely {[MII(HL)2]2(Mo8O26)} n (M = Co (1), Ni (2), Zn (3)) (HL, 3-(2-pyridyl)pyrazole), were designed and synthesized under the hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, and TGA. Single-crystal X-ray diffraction analysis results reveal that compounds 1–3 own the isostructural chain structure consisting of the β-[Mo8O26]4− anions, which are linked by M(HL) 2+2 units via the terminal oxygen atoms. TGA curves show that the organic ligands separate from the related compounds above ca. 673 K.

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Authors and Affiliations

  1. Advanced Material Institute of Research, Department of Chemistry and Chemical Engineering, Qilu Normal University, Jinan, 250013, China

    XiuTang Zhang, PeiHai Wei, CongWen Shi & Bo Hu

  2. School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, China

    DaoFeng Sun & ZhongHai Ni

  3. State Key Laboratory of Structural Chemistry; Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China

    XiaoYuan Wu

  4. College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, 252059, China

    XiuTang Zhang, JianMin Dou & DaCheng Li

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  1. XiuTang Zhang
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  2. XiaoYuan Wu
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Correspondence to XiuTang Zhang.

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Zhang, X., Wu, X., Sun, D. et al. Hydrothermal syntheses and structural characterizations of three polyoxomolybdates frameworks linked by M(HL)2 units (M = Co, Ni, Zn; L = 3-(2-pyridyl)pyrazole). Sci. China Chem. 53, 2285–2290 (2010). https://doi.org/10.1007/s11426-010-4018-8

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  • DOI: https://doi.org/10.1007/s11426-010-4018-8

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