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Synthesis and Characterization of a Novel Waugh-Type Polyoxometalate K1.5(NH4)4.5[MnMo9O32]·4.2H2O

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Abstract

A new molybdomanganate based on the Waugh-type polyoxoanion K1,5(NH4)4,5[MnMo9O32]·4.2H2O (1) has been synthesized in aqueous solution and characterized by single crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis and cyclic voltammetry measurements. The title compound was crystallized in the trigonal system, space group R3 with a = 15.950 (3) Å, b = 15.950 (3) Å, c = 12.447 (2) Å, γ = 120°, V = 2742.3 (9) Å3, Z = 3, R1 = 0.031 and wR2 = 0.088. Left-handed and right-handed [MnMo9O32]6− polyanions enantiomers can be observed in compound (1). The homochiral enantiomers are consolidated by many hydrogen bonds involving ammonium cations and water molecules which are stacked into a 3D framework.

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Authors and Affiliations

  1. Laboratoire des Matériaux et Cristallochimie, Département de Chimie, Faculté des Sciences de Monastir, Avenue de l’environnement, 5019, Monastir, Tunisia

    Donia Zammel & Ichraf Nagazi

  2. Département de Chimie, Institut Supérieur des Sciences Appliquées et de la Technologie, Avenue El Mourouj, 5111, Mahdia, Tunisia

    Amor Haddad

Authors
  1. Donia Zammel
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  2. Ichraf Nagazi
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  3. Amor Haddad
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Correspondence to Ichraf Nagazi.

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Zammel, D., Nagazi, I. & Haddad, A. Synthesis and Characterization of a Novel Waugh-Type Polyoxometalate K1.5(NH4)4.5[MnMo9O32]·4.2H2O. J Clust Sci 26, 1693–1706 (2015). https://doi.org/10.1007/s10876-015-0868-8

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  • DOI: https://doi.org/10.1007/s10876-015-0868-8

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