Abstract
Four new coordination compounds, [Zn(dba)(bpy)] n (1), {[Zn(dba)(phen)]·2H2O} n (2), [Cd(dba)(bpy)(H2O)2] (3) and [Cd2(dba)2(phen)2] n (4) (H2dba = 2,5-dihydroxy-p-benzenediacetic acid, bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline) have been prepared via solvothermal method and characterized by single-crystal X-ray diffraction, infrared spectroscopy, elemental analysis and powder X-ray diffraction. 1 and 2 possess 1D infinite chain structures. Complex 3 exhibits a mononuclear structure. Complex 4 owns binuclear symmetry units, which were bridged via the dba ligands forming a 2D framework. The fluorescence properties of 1–4 have been studied.
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Supported by the National Natural Science Foundation of China (Grant No. 20631030), the Natural Science Foundation of Tianjin (Grant No. 08ZCGHHZ01100), and the Specialized Research Fund for the Doctoral Program of Higher Education (Grant No. 20060055039) of China
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Zhao, L., Ren, P., Zhang, Z. et al. Synthesis, crystal structures and fluorescence properties of four mixed-ligands Zn(II) and Cd(II) coordination compounds. Sci. China Ser. B-Chem. 52, 1479–1484 (2009). https://doi.org/10.1007/s11426-009-0204-y
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DOI: https://doi.org/10.1007/s11426-009-0204-y