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The synthesis and characterization of organometallic copolymers with Mn-Re binuclear transition-metal group in the side chain

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Abstract

Novel organometallic copolymers with Mn-Re binuclear transition-metal groups in the side chain are synthesized and characterized. The structure and properties of the copolymers are characterized by GPC, DSC, TG, NMR, FT-IR, UV-Vis spectra and elemental analysis. The glass transition temperature and UV-Vis spectra properties of these three organometallic copolymers are found to be different from the normal polystyrene. New synthetic strategy for the synthesis of organometallic copolymer is developed.

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Authors and Affiliations

  1. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, China

    Xu Zhi, Feng Gang, Bai Zhifeng, Ma Yongqiang, Chang Weixing & Li Jing

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  1. Xu Zhi
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  2. Feng Gang
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  3. Bai Zhifeng
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  4. Ma Yongqiang
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  5. Chang Weixing
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  6. Li Jing
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Correspondence to Li Jing.

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Xu, Z., Feng, G., Bai, Z. et al. The synthesis and characterization of organometallic copolymers with Mn-Re binuclear transition-metal group in the side chain. SCI CHINA SER B 49, 430–436 (2006). https://doi.org/10.1007/s11426-006-2000-2

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  • DOI: https://doi.org/10.1007/s11426-006-2000-2

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