Abstract
Magnetic nanoparticles have emerged as a promising tool for wastewater treatment due to their unique properties. In this regard, Co0.33Mg0.33Ni0.33SmxFe2-xO4 (0.00 \(\le\) x \(\le\) 0.08) nanoparticles were prepared to examine their magnetic separation efficiency (MSE), photocatalytic, antibacterial, and antibiofilm performances. Pure nanoparticles, having the highest saturation magnetization (Ms = 31.87 emu/g), exhibit the highest MSE, where 95.6% of nanoparticles were separated after 20 min of applying a magnetic field of 150 mT. The catalytic performance of the prepared samples is examined by the photodegradation of rhodamine B (RhB) dye exposed to direct sunlight radiation. Improved photocatalytic activity is exhibited by Co0.33Mg0.33Ni0.33Sm0.04Fe1.96O4 nanoparticles, labeled as Sm0.04, where the rate of the degradation reaction is enhanced by 4.1 times compared to pure nanoparticles. Rising the pH and reaction temperature improves the rate of the photodegradation reaction of RhB. The incorporation of 15 wt% reduced graphene oxide (rGO) with Sm0.04 enhanced the rate of the reaction by 1.7 and 2.4 times compared with pure Sm0.04 sample and rGO, respectively. The antibacterial and antibiofilm activities against Escherichia coli, Leclercia adecarboxylata, Staphylococcus aureus, and Enterococcus faecium are assessed by the minimum inhibitory concentration (MIC) and the minimum bactericidal concentration (MBC) broth microdilution, the agar well diffusion, the time-kill assays, the biofilm formation, and destruction assays. The bacteria used in these assessments are isolated from wastewater. The nanoparticles exhibit a bacteriostatic activity, with a better effect against the Gram-positive isolates. Co0.33Mg0.33Ni0.33SmxFe2O4 (x = 0.00) nanoparticles have the best effect. The effect is exerted after 2–3 h of incubation. Gram-positive biofilms are more sensitive to nanoparticles.
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References
Adnan RM, Mezher M, Abdallah AM, Awad R, Khalil MI (2022) Synthesis, characterization, and antibacterial activity of Mg-doped CuO nanoparticles. Molecules 28(1):103. https://doi.org/10.3390/molecules28010103
Adnan R, Abdallah A, Mezher M, Noun M, Khalil M, Awad R (2023) Impact of Mg-doping on the structural, optical, and magnetic properties of CuO nanoparticles and their antibiofilm activity. Phys Scr 98(5):055935. https://doi.org/10.1088/1402-4896/acccba
Ajeesha T, Ashwini A, George M, Manikandan A, Mary JA, Slimani Y, Almessiere MA, Baykal A (2021) Nickel substituted MgFe2O4 nanoparticles via co-precipitation method for photocatalytic applications. Physica B 606:412660. https://doi.org/10.1016/j.physb.2020.412660
Amiri M, Salavati-Niasari M, Akbari A, Gholami T (2017) Removal of malachite green (a toxic dye) from water by cobalt ferrite silica magnetic nanocomposite: herbal and green sol-gel autocombustion synthesis. Int J Hydrogen Energy 42(39):24846–24860. https://doi.org/10.1016/j.ijhydene.2017.08.077
Aridi A, Awad R, Khalaf A (2021) Synthesis and characterization of ZnFe2O4/Mn2O3 nanocomposites. Appl Phys A 127:206. https://doi.org/10.1007/s00339-021-04362-7
Aridi A, Naoufal D, El-Rassy H, Awad R (2022) Photocatalytic activity of ZnFe2O4/NiO nanocomposites carried out under UV irradiation. Ceram Int 48(20):30905–30916. https://doi.org/10.1016/j.ceramint.2022.07.046
Bandgar SS, Hingangavkar GM, Kore EK, Selvaraj M, Mulik RN, Patil VB (2024) Excellence evaluation of samarium doped Mn-Zn ferrite nanocrystals for room temperature HCl detection. Mater Chem Phys 314:128861. https://doi.org/10.1016/j.matchemphys.2023.128861
Basma H, Al Boukhari J, Abd Al Nabi M, Aridi A, Sayed Hassan R, Naoufal D, Roumie M, Awad R (2022) Enhancement of the magnetic and optical properties of Ni0.5Zn0.5Fe2O4 nanoparticles by ruthenium doping. Appl Phys A 128(5):409. https://doi.org/10.1007/s00339-022-05552-7
Borges ME, Sierra M, Cuevas E, García R, Esparza P (2016) Photocatalysis with solar energy: sunlight-responsive photocatalyst based on TiO2 loaded on a natural material for wastewater treatment. Sol Energy 135:527–535. https://doi.org/10.1016/j.solener.2016.06.022
Bramhaiah K, Bhattacharyya S (2022) Challenges and future prospects of graphene-based hybrids for solar fuel generation: moving towards next generation photocatalysts. Mater Adv 3(1):142–172. https://doi.org/10.1039/D1MA00748C
Briton BGH, Duclaux L, Richardson Y, Yao KB, Reinert L, Soneda Y (2019) Effectiveness of the dispersion of iron nanoparticles within micropores and mesopores of activated carbon for Rhodamine B removal in wastewater by the heterogeneous Fenton process. Appl Water Sci 9(7):1–14. https://doi.org/10.1007/s13201-019-1047-0
Ciobanu CS, Iconaru SL, Le Coustumer P, Constantin LV, Predoi D (2012) Antibacterial activity of silver-doped hydroxyapatite nanoparticles against gram-positive and gram-negative bacteria. Nanoscale Res Lett 7:1–9. https://doi.org/10.1186/1556-276X-7-324
Das KC, Dhar SS (2020) Rapid catalytic degradation of malachite green by MgFe2O4 nanoparticles in presence of H2O2. J Alloy Compd 828:154462. https://doi.org/10.1016/j.jallcom.2020.154462
Dharmaraja C, Nicholas PE, Ramya P, Premkumar II, Vijayan V, Senthilkumar N (2021) Investigation on photocatalytic activity of ZnS/NiFe2O4 NCs under sunlight irradiation via a novel two-step synthesis approach. Inorg Chem Commun 126:108481. https://doi.org/10.1016/j.inoche.2021.108481
Dippong T, Levei EA, Cadar O (2021) Recent advances in synthesis and applications of MFe2O4 (M= Co, Cu, Mn, Ni, Zn) nanoparticles. Nanomaterials 11(6):1560. https://doi.org/10.3390/nano11061560
Dutta RK, Nenavathu BP, Talukdar S (2014) Anomalous antibacterial activity and dye degradation by selenium doped ZnO nanoparticles. Colloids Surf, B 114:218–224. https://doi.org/10.1016/j.colsurfb.2013.10.007
El-Khawaga AM, Elsayed MA, Fahim YA, Shalaby RE (2023) Promising photocatalytic and antimicrobial activity of novel capsaicin coated cobalt ferrite nanocatalyst. Sci Rep 13(1):5353. https://doi.org/10.1038/s41598-023-32323-y
Famuyide IM, Aro AO, Fasina FO, Eloff JN, McGaw LJ (2019) Antibacterial and antibiofilm activity of acetone leaf extracts of nine under-investigated south African Eugenia and Syzygium (Myrtaceae) species and their selectivity indices. BMC Complement Altern Med 19(1):1–13. https://doi.org/10.1186/s12906-019-2547-z
Fan X, Liu X, Wang Y (2023) Low-cost and resource-efficient monolithic photocatalyst with enhanced solar light utilization for the photocatalytic treatment of organic wastewater. Chemosphere 312:137052. https://doi.org/10.1016/j.chemosphere.2022.137052
Hariani PL, Said M, Rachmat A, Riyanti F, Pratiwi HC, Rizki WT (2021) Preparation of NiFe2O4 nanoparticles by solution combustion method as photocatalyst of Congo red. Bull Chem React Eng Catal 16(3):481–490. https://doi.org/10.9767/bcrec.16.3.10848.481-490
Iseppi R, Tardugno R, Brighenti V, Benvenuti S, Sabia C, Pellati F, Messi P (2020) Phytochemical composition and in vitro antimicrobial activity of essential oils from the lamiaceae family against Streptococcus agalactiae and Candida albicans biofilms. Antibiotics 9(9):592. https://doi.org/10.3390/antibiotics9090592
Jamdar M, Monsef R, Ganduh SH, Dawi EA, Jasim LS, Salavati-Niasari M (2024) Unraveling the potential of sonochemically achieved DyMnO3/Dy2O3 nanocomposites as highly efficient visible-light-driven photocatalysts in decolorization of organic contamination. Ecotoxicol Environ Saf 269:115801. https://doi.org/10.1016/j.ecoenv.2023.115801
Jiang Z, Chen K, Zhang Y, Wang Y, Wang F, Zhang G, Dionysiou DD (2020) Magnetically recoverable MgFe2O4/conjugated polyvinyl chloride derivative nanocomposite with higher visible-light photocatalytic activity for treating Cr (VI)-polluted water. Sep Purif Technol 236:116272. https://doi.org/10.1016/j.seppur.2019.116272
Kefeni KK, Mamba BB (2020) Photocatalytic application of spinel ferrite nanoparticles and nanocomposites in wastewater treatment. Sustain Mater Technol 23:e00140. https://doi.org/10.1016/j.susmat.2019.e00140
Leong SS, Ahmad Z, Low SC, Camacho J, Faraudo J, Lim J (2020) Unified view of magnetic nanoparticle separation under magnetophoresis. Langmuir 36(28):8033–8055. https://doi.org/10.1021/acs.langmuir.0c00839
Liang X, Zhang S, Gadd GM, McGrath J, Rooney DW, Zhao Q (2022) Fungal-derived selenium nanoparticles and their potential applications in electroless silver coatings for preventing pin-tract infections. Regen Biomater 9:13. https://doi.org/10.1093/rb/rbac013
Lim Y, Lee D-K, Kim SM, Park W, Cho SY, Sim U (2019) Low dimensional carbon-based catalysts for efficient photocatalytic and photo/electrochemical water splitting reactions. Materials 13(1):114. https://doi.org/10.3390/ma13010114
Mahdikhah V, Saadatkia S, Sheibani S, Ataie A (2020) Outstanding photocatalytic activity of CoFe2O4/rGO nanocomposite in degradation of organic dyes. Opt Mater 108:110193. https://doi.org/10.1016/j.optmat.2020.110193
Maksoud MA, El-Sayyad GS, El-Bastawisy HS, Fathy RM (2021) Antibacterial and antibiofilm activities of silver-decorated zinc ferrite nanoparticles synthesized by a gamma irradiation-coupled sol–gel method against some pathogenic bacteria from medical operating room surfaces. RSC Adv 11(45):28361–28374. https://doi.org/10.1039/D1RA04785J
Mali SN, Pandey A (2023) Synthesis, Computational analysis, antimicrobial, antioxidant, trypan blue exclusion assay, β-hematin assay and anti-inflammatory studies of some hydrazones (part-I). Curr Comput Aided Drug Des 19(2):108–122. https://doi.org/10.2174/1573409918666220929145824
Mali SN, Sawant S, Chaudhari HK, Mandewale MC (2019) In silico appraisal, synthesis, antibacterial screening and DNA cleavage for 1, 2, 5-thiadiazole derivative. Curr Comput Aided Drug Des 15(5):445–455. https://doi.org/10.2174/1573409915666190206142756
Mariosi FR, Venturini J, da CasViegas A, Bergmann CP (2020) Lanthanum-doped spinel cobalt ferrite (CoFe2O4) nanoparticles for environmental applications. Ceram Int 46(3):2772–2779. https://doi.org/10.1016/j.ceramint.2019.09.266
Matar M, Rabaa M, Moussa RM, Hassan RS, Yaacoub N, Awad R (2023) Structural, magnetic, and Mössbauer investigation of Mg-Ni-Co ferrites doped by Sm3+ sions. Phys Scr 98(12):125934. https://doi.org/10.1088/1402-4896/ad06f7
Mehmood CT, Zhong Z, Zhou H, Zhang C, Xiao Y (2020) Immobilizing a visible light-responsive photocatalyst on a recyclable polymeric composite for floating and suspended applications in water treatment. RSC Adv 10(60):36349–36362. https://doi.org/10.1039/D0RA06864K
Mezher M, El Hajj R, Khalil M (2022) Investigating the antimicrobial activity of essential oils against pathogens isolated from sewage sludge of southern Lebanese villages. Germs 12(3):1–19. https://doi.org/10.18683/germs.2022.1355
Mubeen K, Irshad A, Safeen A, Aziz U, Safeen K, Ghani T, Khan K, Ali Z, ulHaq I, Shah A (2023) Band structure tuning of ZnO/CuO composites for enhanced photocatalytic activity. Journal of Saudi Chemical Society 27(3):101639. https://doi.org/10.1016/j.jscs.2023.101639
Nagaraja R, Kottam N, Girija C, Nagabhushana B (2012) Photocatalytic degradation of Rhodamine B dye under UV/solar light using ZnO nanopowder synthesized by solution combustion route. Powder Technol 215:91–97. https://doi.org/10.1016/j.powtec.2011.09.014
Nie L, Hou M, Wang T, Sun M, Hou R (2020) Nanostructured selenium-doped biphasic calcium phosphate with in situ incorporation of silver for antibacterial applications. Sci Rep 10(1):1–14. https://doi.org/10.1038/s41598-020-70776-7
Omelyanchik A, Levada K, Pshenichnikov S, Abdolrahim M, Baricic M, Kapitunova A, Galieva A, Sukhikh S, Astakhova L, Antipov S, Fabiano B (2020) Green synthesis of Co-Zn spinel ferrite nanoparticles: magnetic and intrinsic antimicrobial properties. Materials 13(21):5014. https://doi.org/10.3390/ma13215014
Ponomarev V, Shvindina N, Permyakova E, Slukin P, Ignatov S, Sirota B, Voevodin A, Shtansky D (2019) Structure and antibacterial properties of Ag-doped micropattern surfaces produced by photolithography method. Colloids Surf, B 173:719–724. https://doi.org/10.1016/j.colsurfb.2018.10.040
Rabaa M, Aridi A, Younes G, Awad R (2023a) Samarium doped Mg0.33Ni0.33Co0.33Fe2O4 nanoparticles for the removal of As (III) and Pb (II) heavy metal ions. J Water Environ Nanotechnol. 8(4):357–368. https://doi.org/10.22090/jwent.2023.04.003
Rabaa M, Mezher M, Aridi A, Naoufal D, Khalil M, Awad R (2023b) Improved photocatalytic and antibacterial activity of Mg0.33Ni0.33Co0.33GdxFe2‐xO4 nanoparticles synthesized via the co‐precipitation method. ChemistrySelect 8(29):e202301951. https://doi.org/10.1002/slct.202301951
Rabaa M, Mezher M, Aridi A, Naoufal D, Khalil MI, Awad R, Abdeen W (2023c) Influence of lanthanum doping on the photocatalytic and antibacterial capacities of Mg0.33Ni0.33Co0.33Fe2O4 nanoparticles. Catalysts 13(4):693. https://doi.org/10.3390/catal13040693
Rahman A, Zulfiqar S, Haq AU, Alsafari IA, Qazi UY, Warsi MF, Shahid M (2021) Cd-Gd-doped nickel spinel ferrite nanoparticles and their nanocomposites with reduced graphene oxide for catalysis and antibacterial activity studies. Ceram Int 47(7):9513–9521. https://doi.org/10.1016/j.ceramint.2020.12.085
Revathi J, Abel MJ, Archana V, Sumithra T, Thiruneelakandan R (2020a) Synthesis and characterization of CoFe2O4 and Ni-doped CoFe2O4 nanoparticles by chemical Co-precipitation technique for photo-degradation of organic dyestuffs under direct sunlight. Physica B 587:412136. https://doi.org/10.1016/j.physb.2020.412136
Revathi J, Abel MJ, Pearline CL, Sumithra T, Inbaraj PFH (2020b) Influence of Zn2+ in CoFe2O4 nanoparticles on its photocatalytic activity under solar light irradiation. Inorg Chem Commun 121:108186. https://doi.org/10.1016/j.inoche.2020.108186
Sabbar MH, Mubarak T, Ahmad NS (2023) Synthesis and characterizations of nano magnetic particles (Co-Ni Fe2O4) ferrite by co-precipitation and biomedical application. Int J Nanoelectron Mater 16(1):1–12
Sadeghzadeh-Attar A (2020) Photocatalytic degradation evaluation of N-Fe codoped aligned TiO2 nanorods based on the effect of annealing temperature. J Adv Ceram 9(1):107–122. https://doi.org/10.1007/s40145-019-0353-1
Saigl ZM (2021) Various adsorbents for removal of rhodamine b dye: a review. Indones J Chem 21(4):1039–1056
Saleem I, Rana NF, Tanweer T, Arif W, Shafique I, Alotaibi AS, Almukhlifi HA, Alshareef SA, Menaa F (2022) Effectiveness of Se/ZnO NPs in enhancing the antibacterial activity of resin-based dental composites. Materials 15(21):7827. https://doi.org/10.3390/ma15217827
Sharma RP, Raut SD, Jadhav VV, Mulani RM, Kadam AS, Mane RS (2022) Assessment of antibacterial and anti-biofilm effects of zinc ferrite nanoparticles against Klebsiella pneumoniae. Folia Microbiol 67(5):747–755. https://doi.org/10.1007/s12223-022-00969-2
Shi S, Xu C, Dong Q, Wang Y, Zhu S, Zhang X, Chow YT, Wang X, Zhu L, Zhang G, Xu D (2021) High saturation magnetization MnO2/PDA/Fe3O4 fibers for efficient Pb (II) adsorption and rapid magnetic separation. Appl Surf Sci 541:148379. https://doi.org/10.1016/j.apsusc.2020.148379
Shukla S, Khan R, Daverey A (2021) Synthesis and characterization of magnetic nanoparticles, and their applications in wastewater treatment: a review. Environ Technol Innov 24:101924. https://doi.org/10.1016/j.eti.2021.101924
Song J, Zhang J, Zada A, Ma Y, Qi K (2022) CoFe2O4/NiFe2O4 S-scheme composite for photocatalytic decomposition of antibiotic contaminants. Ceram Int 49(8):12327–12333. https://doi.org/10.1016/j.ceramint.2022.12.088
Suhail F, Mashkour MS, Saeb D (2015) The study on photo degradation of crystal violet by polarographic technique. Int J Basic Appl Sci 15:12–21
Sundararajan M, Bonisha B, Ubaidullah M, Shaikh SMF, Revathi S, Thiripurasundari D, Dhiwahar AT, Pandit B, Dash CS, Shahazad M (2022) Enhanced visible light photocatalytic degradation of rhodamine B using Ni1-xCaxFe2O4 (0≤ x≤ 0.5) nanoparticles: performance, kinetics and mechanism. Mater Res Bull 154:111911. https://doi.org/10.1016/j.materresbull.2022.111911
Teymourinia H, Salavati-Niasari M, Amiri O, Safardoust-Hojaghan H (2017) Synthesis of graphene quantum dots from corn powder and their application in reduce charge recombination and increase free charge carriers. J Mol Liq 242:447–455. https://doi.org/10.1016/j.molliq.2017.07.052
Valdez-Salas B, Beltrán-Partida E, Zlatev R, Stoytcheva M, Gonzalez-Mendoza D, Salvador-Carlos J, Moreno-Ulloa A, Cheng N (2021) Structure-activity relationship of diameter controlled Ag@ Cu nanoparticles in broad-spectrum antibacterial mechanism. Mater Sci Eng, C 119:111501. https://doi.org/10.1016/j.msec.2020.111501
Van Tran C, La DD, Hoai PNT, Ninh HD, Hong PNT, Vu THT, Nadda AK, Nguyen XC, Nguyen DD, Ngo HH (2021) New TiO2-doped Cu–Mg spinel-ferrite-based photocatalyst for degrading highly toxic rhodamine B dye in wastewater. J Hazard Mater 420:126636. https://doi.org/10.1016/j.jhazmat.2021.126636
Vasireddy L, Bingle LE, Davies MS (2018) Antimicrobial activity of essential oils against multidrug-resistant clinical isolates of the Burkholderia cepacia complex. PLoS ONE 13(8):e0201835. https://doi.org/10.1371/journal.pone.0201835
Velayutham L, Parvathiraja C, Anitha DC, Mahalakshmi K, Jenila M, Alasmary FA, Almalki AS, Iqbal A, Lai WC (2022) Photocatalytic and antibacterial activity of CoFe2O4 nanoparticles from Hibiscus rosa-sinensis plant extract. Nanomaterials 12(20):3668. https://doi.org/10.3390/nano12203668
Venkata Subbaiah M, Wen HY, Gollakota AR, Wen JC, Shu CM, Lin KYA, Vijaya Y, Kim DS, Wen JH (2023) Carboxylate-functionalized dragon fruit peel powder as an effective adsorbent for the removal of Rhodamine B (cationic dye) from aqueous solution: adsorption behavior and mechanism. Int J Phytorem 25(2):146–160. https://doi.org/10.1080/15226514.2022.2064817
Verma P, Samanta SK, Mishra S (2020) Photon-independent NaOH/H2O2-based degradation of rhodamine-B dye in aqueous medium: kinetics, and impacts of various inorganic salts, antioxidants, and urea. J Environ Chem Eng 8(4):103851. https://doi.org/10.1016/j.jece.2020.103851
Wang K, Fu J, Wang S, Gao M, Zhu J, Wang Z, Xu Q (2018) Polydopamine-coated magnetic nanochains as efficient dye adsorbent with good recyclability and magnetic separability. J Colloid Interface Sci 516:263–273. https://doi.org/10.1016/j.jcis.2018.01.067
Wang W, Li D, Huang X, Yang H, Qiu Z, Zou L, Liang Q, Shi Y, Wu Y, Wu S, Yang C (2019) Study on antibacterial and quorum-sensing inhibition activities of Cinnamomum camphora leaf essential oil. Molecules 24(20):3792. https://doi.org/10.3390/molecules24203792
Witte K, Müller K, Grüttner C, Westphal F, Johansson C (2017) Particle size-and concentration-dependent separation of magnetic nanoparticles. J Magn Magn Mater 427:320–324. https://doi.org/10.1016/j.jmmm.2016.11.006
Wong JKH, Tan HK, Lau SY, Yap PS, Danquah MK (2019) Potential and challenges of enzyme incorporated nanotechnology in dye wastewater treatment: a review. J Environ Chem Eng 7(4):103261. https://doi.org/10.1016/j.jece.2019.103261
Yang L, Liu B, Liu T, Ma X, Li H, Yin S, Sato T, Wang Y (2017) A P25/(NH4)xWO3 hybrid photocatalyst with broad spectrum photocatalytic properties under UV, visible, and near-infrared irradiation. Sci Rep 7(1):45715. https://doi.org/10.1038/srep45715
Yao C, Wang X, Zhao W, Li T, He Y, Ran X, Guo L (2020) Probing the facet-dependent intermediate in the visible-light degradation of RhB by carbon-coated anatase TiO2 nanoparticles. J Alloy Compd 846:156335. https://doi.org/10.1016/j.jallcom.2020.156335
Zahid M, Nadeem N, Hanif MA, Bhatti IA, Bhatti HN, Mustafa G (2019) Metal ferrites and their graphene-based nanocomposites: synthesis, characterization, and applications in wastewater treatment. In: Abd-Elsalam K, Mohamed M, Prasad R (eds) Magnetic Nanostructures . Nanotechnology in the Life Sciences. Springer, Cham. https://doi.org/10.1007/978-3-030-16439-3_10
Zhang Y, Hu M, Zhang W, Zhang X (2022) Construction of tellurium-doped mesoporous bioactive glass nanoparticles for bone cancer therapy by promoting ROS-mediated apoptosis and antibacterial activity. J Colloid Interface Sci 610:719–730. https://doi.org/10.1016/j.jcis.2021.11.122
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All authors contributed to the study conception and design. Conceptualization: Daoud Naoufal, Mahmoud I. Khalil, and Ramadan Awad; data curation: Amani Aridi, Mariam Rabaa, and Malak Mezher; formal analysis, investigation, and methodology: Amani Aridi, Mariam Rabaa, Malak Mezher, Daoud Naoufal, Mahmoud I. Khalil, and Ramadan Awad; resources: Daoud Naoufal, Mahmoud I. Khalil, and Ramadan Awad; software: Amani Aridi and Malak Mezher; supervision: Daoud Naoufal, Mahmoud I. Khalil, and Ramadan Awad; writing—original draft, Amani Aridi, Mariam Rabaa, and Malak Mezher; writing—review and editing: Amani Aridi, Mariam Rabaa, Malak Mezher, Daoud Naoufal, Mahmoud I. Khalil, and Ramadan Awad. All authors have read and agreed to the published version of the manuscript.
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Aridi, A., Rabaa, M., Mezher, M. et al. Magnetic separation, sunlight-driven photocatalytic activity, and antibacterial studies of Sm-doped Co0.33Mg0.33Ni0.33Fe2O4 nanoparticles. Environ Sci Pollut Res (2024). https://doi.org/10.1007/s11356-024-33641-y
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DOI: https://doi.org/10.1007/s11356-024-33641-y