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Strength development and self-desiccation of saline cemented paste backfill

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Abstract

Given that many mines around the world are located in areas where fresh water is scarce, and companies are being held to increasingly stringent sustainability and environmental responsibility standards, many mines are looking to use locally available saline groundwater or seawater as mixing water in cemented paste backfill (CPB). However, the impacts of this decision on key engineering properties of CPB (e.g. strength and self-desiccation) that affect its mechanical stability need to be better understood to allow confident selection of this practical and more sustainable solution. Thus, the effect of mixing water salinity and binder type on the strength (unconfined compressive strength, UCS) development and self-desiccation (measured by suction and volumetric water content) of CPB is explored in this research. NaCl concentrations from 0 to 300 g/L were used in CPB made with silica tailings and Portland cement type I (PC). Concentrations of 10 and 35 g/L were found to moderately increase UCS, while a concentration of 100 g/L had comparable UCS to non-saline CPB and a concentration of 300 g/L was found to significantly decrease UCS over all curing times. The overall trend is 10 g/L > 35 g/L > 0 g/L > 100 g/L > 300 g/L. The UCS of the 60-day-old CPB with a NaCl of 300 g/L is significantly lower, registering a 26% decrease compared to the UCS of the 60-day-old CPB without salt. In contrast, the UCS of the 60-day-old CPBs containing 10 g/L and 35 g/L of salt exhibits a notable improvement, being 15% and 10% higher, respectively, than the UCS of the 60-day-old CPB without salt. Water content and suction monitoring were conducted up to 28 days of curing time, and it was found that suction only slightly contributed to UCS gain of the saline CPB, and high salt contents (100 and 300 g/L) significantly inhibited the self-desiccation ability of CPB due to inhibition of cement hydration by the excessive amount of salt. The increase in strength of both saline and non-saline samples was attributed primarily to the increase in cement hydration products, while the increased strength of the samples with salinities of 10 and 35 g/L was mainly attributed to the enhancement of the binder hydration due to the low amount of salt and the presence of Friedel’s salt in the pores. The effect of PC replacement by 25 to 75% with slag on CPB with 35 g/L mixing water salinity was also studied. Slag replacement of 50% and higher resulted in significantly higher UCS over most curing times. Suction likely moderately contributed to UCS of the saline CPB with slag, in addition to the presence of Friedel’s salt in the pores and the acceleration of cement and slag hydration by the presence of NaCl.

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Acknowledgements

The authors also thank Lafarge Canada for providing the Slag used in this research.

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Natural Sciences and Engineering Research Council of Canada

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  1. Department of Civil Engineering, University of Ottawa, 161 Colonel By, Ottawa, ON, K1N 6N5, Canada

    Elizabeth Alexandra Carnogursky, Mamadou Fall & Sada Haruna

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  1. Elizabeth Alexandra Carnogursky
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Contributions

Elizabeth A. Carnogursky: investigation, methodology, and writing — original draft preparation. Mamadou Fall: conceptualization, methodology, resources, writing — review and editing, supervision, project administration, and funding acquisition. Sada Haruna: investigation, methodology, and review and editing.

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Correspondence to Mamadou Fall.

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Carnogursky, E.A., Fall, M. & Haruna, S. Strength development and self-desiccation of saline cemented paste backfill. Environ Sci Pollut Res 31, 14894–14911 (2024). https://doi.org/10.1007/s11356-024-32200-9

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