Abstract
The present study described the synthesis and characterization of MOF-76(Tb) for hydrogen storage and humidity sensing applications. The structure and morphology of as-synthesized material were studied using powder X-ray diffraction, scanning, and transmission electron microscopy. The crystal structure of MOF-76(Tb) consists of terbium(III) and benzene-1,3,5-tricarboxylate(-III) ions, one coordinated aqua ligand and one crystallization N,N´-dimethylformamide molecule. The polymeric framework of MOF-76(Tb) contains 1D sinusoidally shaped channels with sizes of 6.6 × 6.6 Å propagating along c crystallographic axis. The thermogravimetric analysis of the prepared material exhibited thermal stability up to 600 °C. At 77 K and pressure up to 20 bar; 0.6 wt.% hydrogen storage capacity for MOF-76(Tb) was observed. Finally, the humidity sensing measurements (water adsorption experiments) were performed, and the results indicate that MOF-76(Tb) is not a suitable material for moisture sensing applications.
Graphical abstract
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Data Availability
The data are available on request.
References
Almáši M (2022) Current development in MOFs for hydrogen storage. Metal-Organic Framework-Based Nanomaterials for Energy Conversion and Storage, 631–661. https://doi.org/10.1016/b978-0-323-91179-5.00020-6
Almáši M, Király N, Zeleňák V, Vilková M, Bourrelly S (2021) Zinc (II) and Cadmium (II)amorphous metal-organic frameworks (aMOFs): study of activation process and high-pressure adsorption of greenhouse gases. RSC Adv 11:20137–20150. https://doi.org/10.1039/D1RA02938J
Almáši M, Sharma A, Zelenka T (2021) Anionic zinc(II) metal-organic framework post-synthetically modified by alkali-ion exchange: synthesis, characterization and hydrogen adsorption properties. Inorg Chim Acta 526:120505. https://doi.org/10.1016/j.ica.2021
Almáši M, Zeleňák V, Gyepes R, Zauška Ľ, Bourrelly S (2020) A series of four novel alkaline earth metal-organic frameworks constructed of Ca(II), Sr(II), Ba(II) ions and tetrahedral MTB linker: Structural diversity, stability study and low/high-pressure gas adsorption. RSC Adv 10:32323–32334. https://doi.org/10.1039/D0RA05145D
Almáši M, Zeleňák V, Kuchár J, Bourrelly S, Llewellyn P (2016) New members of MOF-76 family containing Ho(III) and Tm(III) ions: characterization, stability and gas adsorption properties. Colloids Surf A: Physicochem Eng Aspects 496:114–124. https://doi.org/10.1016/j.colsurfa.2015.10.048
Almáši M, Zeleňák V, Opanasenko M, Čejka J (2014) A novel nickel metal-organic framework with fluorite-like structure: gas adsorption properties and catalytic activity in Knoevenagel condensation. Dalton Trans 43:3730–3738. https://doi.org/10.1039/C3DT52698D
Almáši M, Zeleňák V, Opanasenko M, Čejka J (2018) Efficient and reusable Pb(II) metal-organic framework for Knoevenagel condensation. Catal Lett 148:2263–2273. https://doi.org/10.1007/s10562-018-2471-8
Almáši M, Zeleňák V, Opanasenko M, Císařová I (2015) Ce(III) and Lu(III) metal-organic frameworks with Lewis acid metal sites: preparation, sorption properties and catalytic activity in Knoevenagel condensation. Catal Today 243:184–194. https://doi.org/10.1016/j.cattod.2014.07.028
Almáši M, Zeleňák V, Zeleňáková A (2017) Magnetic and structural studies into the effect of solvent exchange process in metal-organic framework MOF-76(Gd). Acta Phys Pol A 131:991–993. https://doi.org/10.12693/APhysPolA.131.991
Bano YS, Tariq SR, Ilyas A, Aslam M, Bilad MR, Nizami AS, Khan AL (2020) Synergistic solution of CO2 capture by novel lanthanide-based MOF-76 yttrium nanocrystals in mixed-matrix membranes. Energ Envir 31: 692-712. 10.1177%2F0958305X19882413
Balderas-Xicohtencatl R, Schmieder P, Denysenko D, Volkmer D, Hirscher M (2018) High volumetric hydrogen storage capacity using interpenetrated metal-organic frameworks. Energy Tech 6:510–512. https://doi.org/10.1002/ente.201800155
Bellosta von Colbe J, Ares JR, Barale J, Baricco M, Buckley C, Capurso G, Gallandat N, Grant DM, Guzik MN, Jacob I, Jensen EH, Jensen T, Jepsen J, Klassen T, Lototskyy MV, Manickam K, Montone A, Puszkiel J, Sartori S et al (2019) Application of hydrides in hydrogen storage and compression: achievements, outlook and perspectives. Int J Hydrog Energy 44:7780–7808. https://doi.org/10.1016/j.ijhydene.2019.01.104
Branderburg K, Putz H. (n.d.) DIAMOND – Crystal and molecular structure visualization, Version 4.5, Crystal Impact GbR, Germany.
Broom DP, Webb CJ, Fanourgakis GS, Froudakisc GE, Trikalitis PN, Hirscher M (2019) Concepts for improving hydrogen storage in nanoporous materials. Int J Hydrog Energy 44:7768–7779. https://doi.org/10.1016/j.ijhydene.2019.01.224
Capková D, Almáši M, Kazda T, Čech O, Király N, Čudek P, Fedorková AS, Hornebecq V (2020) Metal-organic framework MIL-101(Fe)–NH2 as an efficient host for sulphur storage in long-cycle Li–S batteries. Electrochim Acta 354:136640. https://doi.org/10.1016/j.electacta.2020.136640
Capkova D, Kazda T, Cech O, Kiraly N, Zelenka T, Cudek P, Sharma A, Hornebecq V, Strakova Fedorokova A, Almasi M (2022) Inflence of metal-organic framework MOF-76(Gd) activation/carbonization on yhe cycle performance stability in Li-S battery. J Ener Stor 51:104419. https://doi.org/10.1016/j.est.2022.104419
Chen B, Wang L, Zapata F, Qian G, Lobkovsky EB (2008) A luminescent microporous metal−organic framework for the recognition and sensing of anions. J Am Chem Soc 130:6718–6719. https://doi.org/10.1021/ja802035e
Chen B, Yang Y, Zapata F, Lin G, Qian G, Lobkovsky EB (2007) Luminescent open metal sites within a metal–organic framework for sensing small molecules. Adv Mater 19:1693–1696. https://doi.org/10.1002/adma.200601838
Cheng P, Hang, Hu Y (2014) H2O-functionalized zeolitic Zn(2-methylimidazole)2 framework (ZIF-8) for H2 storage. J Phys Chem C 38:21866–21872. https://doi.org/10.1021/jp507030g
Chevinly AS, Mobtaker HG, Yousefi T, Shirani AS, Aghayan H (2017) {[Ce(BTC)(H2O)]·DMF}n metal organic framework as a new adsorbent for removal of neodymium ions. Inorg Chim Acta 455:34–40. https://doi.org/10.1016/j.ica.2016.09.046
Coelho AA (2018) TOPAS and TOPAS-Academic: an optimization program integrating computer algebra and crystallographic objects written in C++. J Appl Crystallogr 51:210–218. https://doi.org/10.1107/S1600576718000183
Cychosz Katie A, Thommes M (2018) Progress in the physisorption characterization of nanoporous gas storage materials. Engineering 4:559–566. https://doi.org/10.1016/j.eng.2018.06.001
Do HH, Le QV, Nguyen TV, Huynh KA, Tekalgne MA, Tran VA, Lee TH, Cho JH, Shokouhimehr M, Ahn SH, Jang HW, Kim SY (2021) Synthesis of MoSx/Ni-metal-organic framework-74 composites as efficient electrocatalysts for hydrogen evolution reactions. Int J Energy Res 45:9638–9647. https://doi.org/10.1002/er.6385
Duan TW, Yang B (2014) Hybrids based on lanthanide ions activated yttrium metal–organic frameworks: functional assembly, polymer film preparation and luminescence tuning. J Mater Chem C 2:5098–5104. https://doi.org/10.1039/C4TC00414K
Eskandari H, Amirzehni M, Asadollahzadeh H, Hassanzadeh J, Eslami PA (2019) MIP-capped terbium MOF-76 for the selective fluorometric detection of cefixime after its preconcentration with magnetic graphene oxide. Sensors Actuators B Chem 275:145–154. https://doi.org/10.1016/j.snb.2018.08.050
Eskandari H, Amirzehni M, Hassanzadeh J, Vahid B (2020) Mesoporous MIP-capped luminescent MOF as specific and sensitive analytical probe: application for chlorpyrifos. Microchim Acta 187:673. https://doi.org/10.1007/s00604-020-04654-4
Ethiraj J, Bonino F, Vitillo JG, Lomachenko KA, Lamberti C, Reinsch H, Lillerud KP, Bordiga S (2016) Solvent-driven gate opening in MOF-76-Ce: Effect on CO2 adsorption. ChemSusChem 9:713–719. https://doi.org/10.1002/cssc.201501574
Fonseca RRF, Gaspar RDL, Raimundo IM Jr, Luz PP (2018) Photoluminescent Tb3+-based metal-organic framework as a sensor for detection of methanol in ethanol fuel. J Rare Earths 37:225–231. https://doi.org/10.1016/j.jre.2018.07.006
Formalik F, Neimark Alexender V, Rogacka J, Firlej L, Kuchta B (2020) Pore opening and breathing transitions in metal-organic framework. J Colloid Interface Sci 578:77–88. https://doi.org/10.1016/j.jcis.2020.05.105
Garg A, Almáši M, Paul DR, Poonia E, Luthra JR, Sharma A (2021) Metal-organic framework MOF-76(Nd): Synthesis, characterization and study of hydrogen storage and humidity sensing. Front Energy Res 8:604735. https://doi.org/10.3389/fenrg.2020.604735
Gomez D, Colon Y, Zhang X, Wang T, Chen Y, Hupp J, Yildirim T, Farah O, Zhang J, Snurr R (2016) Evaluating topologically diverse metal-organic frameworks for cryo adsorbed hydrogen storage. Energy Environ Sci 9:3279–3289. https://doi.org/10.1039/C6EE02104B
Grunker R, Bon V, Muller P, Stoeck U, Krause S, Mueller U, Senkovska, Kaskel S (2014) A new metal-organic framework with ultra-high surface area. Chem Commun 50:3450–3452. https://doi.org/10.1039/C4CC00113C
Guo X, Zhu G, Li Z, Sun F, Yang Z, Qiu S (2006) A lanthanide metal–organic framework with high thermal stability and available Lewis-acid metal sites. Chem Commun 30:3172–3174. https://doi.org/10.1039/B605428E
Gustafsson M, Bartoszewicz A, Martín-Matute B, Sun J, Grins J, Zhao T, Li Z, Zhu G, Zou X (2010) Family of highly stable lanthanide metal−organic frameworks: structural evolution and catalytic activity. Chem Mater 22:3316–3322. https://doi.org/10.1021/cm100503q
Gustafsson M, Li Z, Zhu G, Qiu S, Grins J, Zou X (2008) A porous chiral lanthanide metal-organic framework with high thermal stability. Zeolites and Related Materials: Trends, Targets and Challenges Proceedings of 4th International FEZA Conference, 451. https://doi.org/10.1021/cm100503q
Hammersley AP, Svensson SO, Hanfland M, Fitch AN, Häusermann D (1996) Detector software: From real detector to idealized image or two-theta scan. High Pressure Res 14:235–248. https://doi.org/10.1080/08957959608201408
Hirscher M, Panella B (2007) Hydrogen storage in metal organic frameworks. Scripta Mat 56:809. https://doi.org/10.1080/08957959608201408
Hirscher M, Yartys VA, Bariccoc M, Bellosta von Colbe J, Blanchard D, Bowman RC Jr, Broom DP, Buckley CE, Chang F, Chen P, Cho YW, Crivello JC, Cuevas F, David WIF, de Jongh PE, Denys RV, Dornheim M, Felderhoff M, Filinchuk Y et al (2020) Materials for hydrogen-based energy storage - past, recent progress and future outlook. J Alloys Compd 827:153548. https://doi.org/10.1016/j.jallcom.2019.153548
Hongda L, Min C, Gaoxia Z, Ling L, Li D, Bo L, Sa X, Guang Fu W, Xiao Feng Y (2022) Modified UiO-66 as photocatalysts for boosting the carbon-neutral energy cycle and solving environmental remediation issues. Coord Chem Rev 458:214428. https://doi.org/10.1016/j.ccr.2022.214428
Hosseini MS, Zeinali S (2019) Capacitive humidity sensing using a metal–organic framework nanoporous thin film fabricated through electrochemical in situ growth. J Mater Sci Mater Electron 30:3701–3710. https://doi.org/10.1007/s10854-018-00652-8
Ibarra I, Yang S, Lin X, Blake A, Rizkallah P, Nowell H, David C, Neil H, Peter S (2011) Highly porous and robust scandium-based metal-organic frameworks for hydrogen storage. Chem Commun 47:8304–8306. https://doi.org/10.1039/C1CC11168J
Jena P (2011) Materials for hydrogen storage: past, present, and future. J Phys Chem Lett 2:206–211. https://doi.org/10.1021/jz1015372
Kajiwara T, Higuchi M, Watanabe D, Higashimura H, Yamada T, Kitagawa H (2014) A systematic study on the stability of porous coordination polymers against ammonia. Chem Eur J 20:15611–15617. https://doi.org/10.1002/chem.201403542
Kiyonaga T, Higuchi M, Kajiwara T, Takashima Y, Duan J, Nagashimac K, Kitagawa S (2015) Dependence of crystal size on the catalytic performance of a porous coordination polymer. Chem Commun 51:2728–2730. https://doi.org/10.1039/C4CC07562E
Kökçam-Demir L, Goldman A, Esrafili L, Gharib M, Morsali A, Weingart O, Janiak C (2020) Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications. Chem Soc Rev 49:2751–2798. https://doi.org/10.1039/c9cs00609e
Kraus W, Nolze G (1996) POWDER CELL - a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns. J Appl Crystallogr 29:301–303. https://doi.org/10.1107/S0021889895014920
Lang X, Wang X, Liu Y, Cai K, Li L, Zhang Q (2021) Cobalt-based metal organic framework (Co-MOFs)/graphene oxide composites as high-performance anode active materials for lithium-ion batteries. Int J Energy Res 45:4811–4820. https://doi.org/10.1002/er.6080
Langmi H, Ren J, North B, Mathe M, Bessarabov D (2014) Hydrogen storage in metal-organic framewoks: a review. Electrochim Acta 128:393–399. https://doi.org/10.1016/j.electacta.2013.10.190
Lee J, Li J, Jagielli J (2005) Gas sorption properties of microporous metal organic frameworks. J Solid State Chem 178:2527–2532. https://doi.org/10.1016/j.jssc.2005.07.002
Lee T, Lee HL, Tsai MH, Cheng SL, Lee SW, Hu JC, Chen LT (2013) A biomimetic tongue by photoluminescent metal–organic frameworks. Biosens Bioelectron 43:56–62. https://doi.org/10.1016/j.bios.2012.11.014
Li J, Yuan X, Wu Y, Ma X, Li F, Zhang B, Wang Y, Lei Z, Zhang Z (2018) From powder to cloth: Facile fabrication of dense MOF-76(Tb) coating onto natural silk fiber for feasible detection of copper ions. Chem Eng J 350:637–644. https://doi.org/10.1016/j.cej.2018.05.144
Li Z, Liu K (2012) Crystal structure of aqua(benzene-1,3,5-tricarboxylato)-lutetium(III), Lu(H2O)(C9H3O6). Z Kristallogr – New Cryst Struct 227:91–92. https://doi.org/10.1524/ncrs.2012.0041
Lian X, Yan B (2016) A lanthanide metal–organic framework (MOF-76) for adsorbing dyes and fluorescence detecting aromatic pollutants. RSC Adv 6:11570–11576. https://doi.org/10.1039/C5RA23681A
Lin X, Telepeni I, Blake A, Daily A, Brown C, Simmons J, Zoppi M, Walker G, Thomas K, Mays T, Hubberstey P, Champness N, Schroder M (2009) High capacity hydrogen adsorption in Cu(II) tetracarboxylate framework materials: The role of pore size, ligand functionalzation, and exposed metal sites. J Am Chem Soc 6:2159–2171. https://doi.org/10.1021/ja806624j
Liu S, Lia X, Zhang H (2020) Synergistic effects of MOF-76 on layered double hydroxides with superior activity for extractive catalytic oxidative desulfurization. New J Chem 44:6269–6276. https://doi.org/10.1039/D0NJ00612B
Meek ST, Greathouse JA, Allendorf MD (2011) Metal-organic frameworks: a rapidly growing class of versatile nanoporous materials. Adv Mater 2:249–267. https://doi.org/10.1002/adma.201002854
Moon H, Kobayashi N, Suh M (2006) Porous metal-organic framework with coordinatively unsaturated Mn sites: Sorption properties of various gasses. Inorg Chem 21:8672–8676. https://doi.org/10.1021/ic0611948
Murialdo M, Weadock NJ, Liu Y, Ahn CC, Baker SE, Landskron K, Fultz B (2019) High-pressure hydrogen adsorption on a porous electron-rich covalent organonitridic framework. ACS Omega 4:444–448. https://doi.org/10.1021/acsomega.8b03206
Nasution TI, Nainggolan I, Dalimunthe D, Balyan M, Cuana R, Khanifah S (2018) Humidity detection using chitosan film-based sensor. IOP Conf Series: Mat Sci Eng 309:012080. https://doi.org/10.1088/1757-899X/309/1/012080
Origin, (n.d.) Version 8.0, OriginLab Corporation, Northampton, USA.
OMNIC, (n.d.) Version 8.2.0.387, Thermo Fisher Scientific Inc., USA.
Park H, Lim D, Yang W, Oh T, Suh M (2011) A highly porous metal-organic framework: Structural transformation of a guest-free MOF depending on activation method and temperature. Chem Eur J 17:7251–7260. https://doi.org/10.1002/chem.201003376
Rallapalli P, Raj M, Senthilkumar S, Somani R, Bajaj H (2015) HF-free synthesis of MIL-101(Cr) and its hydrogen adsorption studies. Environ Prog Sustain Energy 35:461–468. https://doi.org/10.1002/ep.12239
Rauf S, Vijjapu MT, Andrés MA, Gascón I, Roubeau O, Eddaoudi M, Salama KN (2020) Highly selective metal–organic framework textile humidity sensor. ACS Appl Mater Interfaces 12:29999–30006. https://doi.org/10.1021/acsami.0c0753
Rood J, Noll B, Henderson K (2006) Synthesis, structural characterization, gas sorption and guest-exchange studies of the lightweight, porous Metal-Organic Framework α-[Mg3(O2CH)6]. Inorg Chem 45:5521–5528. https://doi.org/10.1021/ic060543v
Rosi NL, Kim J, Eddaoudi M, Chen B, O'Keeffe M, Yaghi OM (2005) Rod packings and metal−organic frameworks constructed from rod-shaped secondary building units. J Am Chem Soc 127:1504–1518. https://doi.org/10.1021/ja045123o
Rowsell J, Millward A, Park K, Yaghi O (2004) Hydrogen sorption in functionalized metal-organic frameworks. J Am Chem Soc 18:5666–5667. https://doi.org/10.1021/ja049408c
Santos PF, Luz PP (2020) Synthesis of a Ce-based MOF-76 with high yield: a study of reaction parameters based on a factorial design. J Braz Chem Soc 31:566. https://doi.org/10.21577/0103-5053.20190218
Santos PF, Ribeiro J, Luz PP (2020) Physicochemical and electrochemical characterization of Ce/carbonaceous matrices-based composites. Solid State Sci 110:106479. https://doi.org/10.1016/j.solidstatesciences.2020.106479
Senkovska I, Kaskel S (2006) Solvent-induced pore-size adjustment in the Metal-Organic Framework [Mg3(ndc)3(dmf)4] (ndc-napthelenedicarboxyalte). Eur J Inorg Chem 2006:4564–4569. https://doi.org/10.1002/ejic.200600635
Shengyu Z, Shen W, Shijin Z, Hongbo X, Jiupeng Z, Jing W, Yao L (2020) An electrochromic supercapacitor based on an MOF derived hierarchical-porous NiO film. Nanoscale 12:8934–8941. https://doi.org/10.1039/D0NR01152E
Shultz A, Farah O, Hupp J, Nguyen T (2009) A catalytically active, permanently microporous MOF with metalloprphyrin struts. J Am Chem Soc 131:4204–4205. https://doi.org/10.1021/ja900203f
Singh K, Kukkar D, Singh R, Kukkar P, Bajaj N, Singh J, Rawat M, Kumar A, Kim KH (2020) In situ green synthesis of Au/Ag nanostructures on a metal-organic framework surface for photocatalytic reduction of p-nitrophenol. J Ind Eng Chem 81:196–205. https://doi.org/10.1016/j.jiec.2019.09.008
Suh MP, Park HJ, Prasad TK, Lim DW (2011) Hydrogen storage in metal-organic frameworks. Chem Rev 112:782–835. https://doi.org/10.1021/cr200274s
Sule R, Mishra AK, Nkambule TT (2021) Recent advancement in consolidation of MOFs as absorbents for hydrogen storage. Int J Energy Res 45:12481–12499. https://doi.org/10.1002/er.6608
Sumida K, Brown C, Herm Z, Chavan S, Bordiga S, Long J (2011) Hydrogen storage properties and neutron scattering studies of Mg2(dobdc)- a metal organic framework with open Mg2+ adsorption sites. Chem Commun 47:1157–1159. https://doi.org/10.1039/C0CC03453C
Sumida K, Hill M, Horike S, Daily A, Long J (2009) Synthesis and hydrogen storage properties of Be12(OH)12(1,3,5-benzenetribenzoate)4. J Am Chem Soc 131:15120–15121. https://doi.org/10.1021/ja9072707
Sumida K, Rogow DL, Mason JA, McDonald TM, Bloch ED, Herm ZR, Bae TH, Long JR (2012) Carbon dioxide capture in metal-organic frameworks. Chem Rev 112:724. https://doi.org/10.1002/er.6608
Weiss A, Reimer N, Stock N, Tiemann M, Wagne T (2015) Surface-modified CAU-10 MOF materials as humidity sensors: impedance spectroscopic study on water uptake. Phys Chem Chem Phys 17:21634–21642. https://doi.org/10.1039/c5cp01988e
Wu D, Zhang Z, Chen X, Meng L, Li C, Li G, Chen X, Shi Z, Feng S (2019) A non-luminescent Eu-MOF-based “turn-on” sensor towards an anthrax biomarker through single-crystal to single-crystal phase transition. Chem Commun 55:14918–14921. https://doi.org/10.1039/C9CC08206A
Xie LH, Wang Y, Liu XM, Lin JB, Zhang JP, Chen XM (2011) Crystallographic studies into the role of exposed rare earth metal ion for guest sorption. CrystEngComm 13:5849–5857. https://doi.org/10.1039/C1CE05468F
Xu G, Meng Z, Liu Y, Guo X, Deng K, Ding L, Lu R (2019) Porous MOF-205 with multiple modifications for efficiently storing hydrogen and methane as well as separating carbon dioxide from hydrogen and methane. Int J Energy Res 43:7517–7528. https://doi.org/10.1002/er.4631
Xuan J, Qunyan Z, Lei F, Xin L, Haiyan Z, Mia H, Zhoufang Z, Yandong W, Ying L, Likui W, Xuefeng L, Gang S (2021) Light-trapping SERS substrate with regular bioinspired arrays for detecting trace dyes. ACS Appl Mater Interfaces 13:11535–11542. https://doi.org/10.1021/acsami.1c00702
Yang J, Yue Q, Li GD, Cao JJ, Li GH, Chen JS (2006) Structures, photoluminescence, up-conversion, and magnetism of 2D and 3D rare-earth coordination polymers with multicarboxylate linkages. Inorg Chem 45:2857–2865. https://doi.org/10.1021/ic051557o
Yang L, Chensi T, Min C, Ming C, Sha C, Lei L, Yashi C, Huan Y, Yukui F, Ling L (2021) Polyoxometalate metal-organic framework composites as effective photocatalysts. ACS Catal 11:13374–13396. https://doi.org/10.1021/acscatal.1c03866
Yang L, Hao C, Min C, Zhifeng L, Danlian H, Gaoxia Z, Binbin S, Qinghua L, Songhao L, Ting W, Sa X (2021) The application of Zeolitic imidazolate frameworks (ZIFs) and their derivatives based materials for photocatalytic hydrogen evolution and pollutants treatment. Chem Eng J 417:127914. https://doi.org/10.1016/j.cej.2020.127914
Yang W, Bai ZQ, Shi WQ, Yuan LY, Tian T, Chai ZF, Wang H, Sun ZM (2013) MOF-76: from a luminescent probe to highly efficient UVI sorption material. Chem Commun 49:10415–10417. https://doi.org/10.1039/C3CC44983A
Yang WT, Feng J, Song SY, Zhang HJ (2012) Microwave-assisted modular fabrication of nanoscale luminescent metal-organic framework for molecular sensing. ChemPhysChem 13:2734–2738. https://doi.org/10.1002/cphc.201200265
Yang Y, Zhao L, Sun M, Wei P, Li G, Li Y (2020) Highly sensitive luminescent detection toward polytypic antibiotics by a water-stable and white-light-emitting MOF-76 derivative. Dyes Pigments 180:108444. https://doi.org/10.1016/j.dyepig.2020.108444
Ying L, Lei F, Jianhua L, Xin L, Jun C, Likui W, Dianpeng Q, Xuefeng L, Gnag S (2021) Fabrication of an insect-like compound-eye SERS substrate with 3D Ag nano-bowls and its application in optical sensor. Sensors Actuators B Chem 330:129357. https://doi.org/10.1016/j.snb.2020.129357
Yu H, Gao S, Cheng X, Wang P, Zhang X, Xu Y, Zhao H, Hou L (2019) Morphology controllable Fe2O3 nanostructures derived from Fe-based metal-organic frameworks for enhanced humidity sensing performances. Sensors Actuators B Chem 297:126744. https://doi.org/10.1016/j.snb.2019.126744
Yuan W, Lei F, Haiyan Z, Hongyan M, Ying L, Xuefeng L, Gng S (2021) Noncontact metal-spinropyran-metal nanostructured substrates with Ag and Au@SiO2 nanoparticles deposited in nanohole arrays for surface-enhanced fluorescence and trace detection of metal ions. ACS Appl Nano Mat 4:3780–3789. https://doi.org/10.1021/acsanm.1c00208
Zeleňák V, Almáši M, Zeleňáková A, Hrubovčák P, Tarasenko R, Bourelly S, Llewellyn P (2019) Large and tunable magnetocaloric effect in gadolinium-organic framework: tuning by solvent exchange. Sci Rep 9:15572. https://doi.org/10.1016/j.snb.2019.126744
Zhang C, Xu Y, Lv C, Zhou X, Wang Y, Xing W, Meng Q, Kong Y, Chen G (2019) Mimicking π backdonation in Ce-MOFs for solar-driven ammonia synthesis. ACS Appl Mater Interfaces 11:29917–29923. https://doi.org/10.1021/acsami.9b08682
Zhang J, Sun L, Chen C, Liu M, Dong W, Guo W, Ruan S (2017) High performance humidity sensor based on metal organic framework MIL-101(Cr) nanoparticles. J Alloys Compd 695:520–525. https://doi.org/10.1016/j.jallcom.2016.11.129
Zhou Q, Yang F, Xin B, Zeng G, Zhou X, Liu K, Ma D, Li G, Shi Z, Fenga S (2013) Reversible switching of slow magnetic relaxation in a classic lanthanide metal–organic framework system. Chem Commun 49:8244–8246. https://doi.org/10.1039/C3CC43747G
Funding
M.A. thanks to the VEGA projects No. 1/0865/21, KEGA project No. 006UPJŠ-4/2021, APVV projects No. 18-0197, SK-CZ-RD-21-0068 and UPJS project No. 2022-2123. A.S. acknowledges the SERB SRG project No. 2021/002019.
Author information
Authors and Affiliations
Contributions
Akash Garg: conceptualization, methodology, investigation, roles/writing—original draft, writing—review and editing. Robin Saini, Devina Rattan Paul: conceptualization, methodology, roles/writing-original draft. Miroslav Almáši, Anshu Sharma, Ankur Jain, Indra Prabh Jain: supervision, project administration, conceptualization, methodology, roles/writing—original draft; writing—review and editing. All authors read and approved the final manuscript.
Corresponding author
Ethics declarations
Ethics approval
For this type of study, formal consent is not required.
Consent to participate
Not applicable.
Consent for publication
Not applicable.
Competing interests
The authors declare that they have no competing interests.
Additional information
Responsible Editor: George Z. Kyzas
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Garg, A., Almáši, M., Saini, R. et al. A highly stable terbium(III) metal-organic framework MOF-76(Tb) for hydrogen storage and humidity sensing. Environ Sci Pollut Res 30, 98548–98562 (2023). https://doi.org/10.1007/s11356-022-21290-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-022-21290-y