Abstract
This work aims to investigate the adsorption performance of orange G (OG) dye from aqueous solutions employing PANI@sawdust biocomposite enrobed by calcium-alginate bio-beads (Alg-PANI@SD). The as-prepared adsorbent was characterized by scanning-electron-microscopy (SEM), X-ray energy-dispersive spectroscopy (EDS), and Fourier transforms infrared (FT-IR) spectroscopy and used to remove orange G dye from aqueous water. Batch tests were performed as a function of adsorbent dosage, pH, contact time, interfering ions, and initial OG dye concentration. Experimental results show that the kinetic model of pseudo-first-order (PFO) and Freundlich isotherm perfectly fit the entire experimental data. Additionally, the prepared composite exhibited an excellent regeneration capacity and reusability for OG dye removal. The results revealed that the as-prepared Alg-PANI@SD bio-beads have the potential to be applied as a low-cost adsorbent for the adsorption of OG dye from aqueous media.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Data Availability
Data and materials are available.
References
Abdellaoui Y, AbouOualid H, Hsini A et al (2021) Synthesis of zirconium-modified Merlinoite from fly ash for enhanced removal of phosphate in aqueous medium: Experimental studies supported by Monte Carlo/SA simulations. Chem Eng J 404:126600. https://doi.org/10.1016/j.cej.2020.126600
Ahmad R, Ansari K (2021a) Enhanced sequestration of methylene blue and crystal violet dye onto green synthesis of pectin modified hybrid (Pect/AILP-Kal) nanocomposite. Process Biochem 111:132–143. https://doi.org/10.1016/j.procbio.2021.10.009
Ahmad R, Ansari K (2021b) Comparative study for adsorption of congo red and methylene blue dye on chitosan modified hybrid nanocomposite. Process Biochem 108:90–102. https://doi.org/10.1016/j.procbio.2021.05.013
Ahmad R, Ansari K (2020) Polyacrylamide-grafted Actinidia deliciosa peels powder (PGADP) for the sequestration of crystal violet dye: isotherms, kinetics and thermodynamic studies. Appl Water Sci 10:195. https://doi.org/10.1007/s13201-020-01263-7
Ahmad R, Mirza A (2018) Adsorptive removal of heavy metals and anionic dye from aqueous solution using novel Xanthan gum-Glutathione/Zeolite bionanocomposite. Groundw Sustain Dev 7:305–312. https://doi.org/10.1016/j.gsd.2018.07.002
Ait Haki M, Imgharn A, Aarab N, et al (2021) Efficient removal of crystal violet dye from aqueous solutions using sodium hydroxide modified avocado shells: kinetics and isotherms modeling. Water Sci Technol wst2021451. https://doi.org/10.2166/wst.2021.451
Akhsassi B, Bouddouch A, Naciri Y et al (2021) Enhanced photocatalytic activity of Zn3(PO4)2/ZnO composite semiconductor prepared by different methods. Chem Phys Lett 783:139046. https://doi.org/10.1016/j.cplett.2021.139046
Amjlef A, Khrach S, Ait El Fakir A et al (2021) Adsorptive properties investigation of natural sand as adsorbent for methylene blue removal from contaminated water. Nanotechnol Environ Eng 6:26. https://doi.org/10.1007/s41204-021-00119-y
Barebita H, Naciri Y, Ferraa S, et al (2020) Investigation of structural and photocatalytic behavior of Bi13B1–2xVxPxO20.95+2x (0 ≤ x ≤ 0.5). Solid State Sci 108:106389. https://doi.org/10.1016/j.solidstatesciences.2020.106389
Brini L, Hsini A, Naciri Y et al (2021) Synthesis and characterization of arginine-doped heliotrope leaves with high clean-up capacity for crystal violet dye from aqueous media. Water Sci Technol 84:2265–2277. https://doi.org/10.2166/wst.2021.446
Chang X, Li M, Liu Q et al (2016) Adsorption–reduction of chromium( vi ) from aqueous solution by phenol–formaldehyde resin microspheres. RSC Adv 6:46879–46888. https://doi.org/10.1039/C6RA07239A
Dąbrowski A, Podkościelny P, Hubicki Z, Barczak M (2005) Adsorption of phenolic compounds by activated carbon—a critical review. Chemosphere 58:1049–1070. https://doi.org/10.1016/j.chemosphere.2004.09.067
El-Gaayda J, Titchou FE, Oukhrib R et al (2021) Natural flocculants for the treatment of wastewaters containing dyes or heavy metals: a state-of-the-art review. J Environ Chem Eng 9:106060. https://doi.org/10.1016/j.jece.2021.106060
Essekri A, Hsini A, Naciri Y et al (2021) Novel citric acid-functionalized brown algae with a high removal efficiency of crystal violet dye from colored wastewaters: insights into equilibrium, adsorption mechanism, and reusability. Int J Phytoremediation 23:336–346. https://doi.org/10.1080/15226514.2020.1813686
Fahoul Y, Tanji K, Zouheir M et al (2022) Novel river sediment@ZnO Co nanocomposite for photocatalytic degradation and COD reduction of crystal violet under visible light. J Mol Struct 1253:132298. https://doi.org/10.1016/j.molstruc.2021.132298
Feng T, Bavumiragira JP, Wambui MA et al (2020) Hierarchical porous induced competent removal of low concentration azo dye molecules by generating a leachy crystalline structure H-MIL-53(Fe). Chin Chem Lett 31:2717–2720. https://doi.org/10.1016/j.cclet.2020.04.044
Ferraa S, Naciri Y, Hsini A et al (2021) Evolution of the physicochemical and photocatalytic properties of BaO embedded in bismuth phosphovanadates glasses. Chem Phys Lett 763:138173. https://doi.org/10.1016/j.cplett.2020.138173
Grzegorzek M, Majewska-Nowak K, Ahmed AE (2020) Removal of fluoride from multicomponent water solutions with the use of monovalent selective ion-exchange membranes. Sci Total Environ 722:137681. https://doi.org/10.1016/j.scitotenv.2020.137681
Gupta VK, Agarwal S, Ahmad R et al (2020) Sequestration of toxic congo red dye from aqueous solution using ecofriendly guar gum/activated carbon nanocomposite. Int J Biol Macromol 158:1310–1318. https://doi.org/10.1016/j.ijbiomac.2020.05.025
Hsini A, Benafqir M, Naciri Y et al (2021a) Synthesis of an arginine-functionalized polyaniline@FeOOH composite with high removal performance of hexavalent chromium ions from water: adsorption behavior, regeneration and process capability studies. Colloids Surf Physicochem Eng Asp 617:126274. https://doi.org/10.1016/j.colsurfa.2021.126274
Hsini A, Naciri Y, Bouziani A et al (2021b) Polyaniline coated tungsten trioxide as an effective adsorbent for the removal of orange G dye from aqueous media. RSC Adv 11:31272–31283. https://doi.org/10.1039/D1RA04135E
Hsini A, Naciri Y, Laabd M et al (2021c) Development of a novel PANI@WO3 hybrid composite and its application as a promising adsorbent for Cr(VI) ions removal. J Environ Chem Eng 9:105885. https://doi.org/10.1016/j.jece.2021.105885
Hsini A, Naciri Y, Laabd M et al (2020) Synthesis and characterization of arginine-doped polyaniline/walnut shell hybrid composite with superior clean-up ability for chromium (VI) from aqueous media: equilibrium, reusability and process optimization. J Mol Liq 316:113832. https://doi.org/10.1016/j.molliq.2020.113832
Imgharn A, Anchoum L, Hsini A et al (2022) Effectiveness of a novel polyaniline@Fe-ZSM-5 hybrid composite for Orange G dye removal from aqueous media: experimental study and advanced statistical physics insights. Chemosphere 295:133786. https://doi.org/10.1016/j.chemosphere.2022.133786
A Imgharnighnih H, Hsini A, et al 2021 Synthesis and characterization of polyaniline-based biocomposites and their application for effective removal of orange G dye using adsorption in dynamic regime Chem Phys Lett 778 138811 https://doi.org/10.1016/j.cplett.2021.138811
Javanbakht V, Shafiei R (2020) Preparation and performance of alginate/basil seed mucilage biocomposite for removal of eriochrome black T dye from aqueous solution. Int J Biol Macromol 152:990–1001. https://doi.org/10.1016/j.ijbiomac.2019.10.185
Joubert M, Bouhadid M, Bégué D et al (2010) Conducting polyaniline composite: From syntheses in waterborne systems to chemical sensor devices. Polymer 51:1716–1722. https://doi.org/10.1016/j.polymer.2010.01.052
Laabd M, Brahmi Y, El Ibrahimi B et al (2021) A novel mesoporous Hydroxyapatite@Montmorillonite hybrid composite for high-performance removal of emerging Ciprofloxacin antibiotic from water: Integrated experimental and Monte Carlo computational assessment. J Mol Liq 338:116705. https://doi.org/10.1016/j.molliq.2021.116705
Laabd M, Imgharn A, Hsini A et al (2022) Efficient detoxification of Cr(VI)-containing effluents by sequential adsorption and reduction using a novel cysteine-doped PANi@faujasite composite: experimental study supported by advanced statistical physics prediction. J Hazard Mater 422:126857. https://doi.org/10.1016/j.jhazmat.2021.126857
Liu D, Sun D (2011) Simulation of indigo carmine dye adsorption on polymer doped sawdust in fixed-bed systems. Desalination Water Treat 27:285–293. https://doi.org/10.5004/dwt.2011.2031
Mahi O, Khaldi K, Belardja MS et al (2021) Development of a new hybrid adsorbent from Opuntia Ficus Indica NaOH-activated with PANI-reinforced and its potential use in orange-G dye removal. J Inorg Organomet Polym Mater 31:2095–2104. https://doi.org/10.1007/s10904-020-01873-3
Miklos DB, Remy C, Jekel M et al (2018) Evaluation of advanced oxidation processes for water and wastewater treatment — a critical review. Water Res 139:118–131. https://doi.org/10.1016/j.watres.2018.03.042
Mimouni I, Bouziani A, Naciri Y et al (2022) Effect of heat treatment on the photocatalytic activity of α-Fe2O3 nanoparticles: towards diclofenac elimination. Environ Sci Pollut Res 29:7984–7996. https://doi.org/10.1007/s11356-021-16146-w
Mirza A, Ahmad R (2020) An efficient sequestration of toxic crystal violet dye from aqueous solution by Alginate/Pectin nanocomposite: a novel and ecofriendly adsorbent. Groundw Sustain Dev 11:100373. https://doi.org/10.1016/j.gsd.2020.100373
J Mittal R Ahmad MO Ejaz et al 2021 A novel, eco-friendly bio-nanocomposite (Alg-Cst/Kal) for the adsorptive removal of crystal violet dye from its aqueous solutions Int J Phytoremediation 1–12 https://doi.org/10.1080/15226514.2021.1977778
Naciri Y, Hsini A, Ajmal Z et al (2020) Recent progress on the enhancement of photocatalytic properties of BiPO4 using π–conjugated materials. Adv Colloid Interface Sci 280:102160. https://doi.org/10.1016/j.cis.2020.102160
Y Naciri A Hsini A Bouziani et al 2021 Photocatalytic oxidation of pollutants in gas-phase via Ag3 PO4-based semiconductor photocatalysts: recent progress, new trends, and future perspectives Crit Rev Environ SciTechnol 1–44 https://doi.org/10.1080/10643389.2021.1877977
Naciri Y, Hsini A, Bouziani A et al (2022) Z-scheme WO3/PANI heterojunctions with enhanced photocatalytic activity under visible light: a depth experimental and DFT studies. Chemosphere 292:133468. https://doi.org/10.1016/j.chemosphere.2021.133468
Pradhan SS, Konwar K, Ghosh TN et al (2020) Multifunctional iron oxide embedded reduced graphene oxide as a versatile adsorbent candidate for effectual arsenic and dye removal. Colloid Interface Sci Commun 39:100319. https://doi.org/10.1016/j.colcom.2020.100319
Rocher V, Siaugue J-M, Cabuil V, Bee A (2008) Removal of organic dyes by magnetic alginate beads. Water Res 42:1290–1298. https://doi.org/10.1016/j.watres.2007.09.024
Salam MA, Kosa SA, Al-Beladi AA (2017) Application of nanoclay for the adsorptive removal of Orange G dye from aqueous solution. J Mol Liq 241:469–477. https://doi.org/10.1016/j.molliq.2017.06.055
Shuang C, Li P, Li A et al (2012) Quaternized magnetic microspheres for the efficient removal of reactive dyes. Water Res 46:4417–4426. https://doi.org/10.1016/j.watres.2012.05.052
Singh V, Chauhan P (2009) Structural and optical characterization of CdS nanoparticles prepared by chemical precipitation method. J Phys Chem Solids 70:1074–1079. https://doi.org/10.1016/j.jpcs.2009.05.024
Tanji K, Zouheir M, Hachhach M et al (2021) Design and simulation of a photocatalysis reactor for rhodamine B degradation using cobalt-doped ZnO film. React Kinet Mech Catal 134:1017–1038. https://doi.org/10.1007/s11144-021-02116-3
K Tanji M Zouheir Y Naciri et al 2022 Visible light photodegradation of blue basic 41 using cobalt doped ZnO: Box-Behnken optimization and DFT calculation J Iran ChemSoc https://doi.org/10.1007/s13738-022-02496-w
Varma AK, Thakur LS, Shankar R, Mondal P (2019) Pyrolysis of wood sawdust: effects of process parameters on products yield and characterization of products. Waste Manag 89:224–235. https://doi.org/10.1016/j.wasman.2019.04.016
Vickers NJ (2017) Animal communication: when I’m calling you, will you answer too? Curr Biol 27:R713–R715. https://doi.org/10.1016/j.cub.2017.05.064
Yeamin MdB, Islam MdM, Chowdhury A-N, Awual MdR (2021) Efficient encapsulation of toxic dyes from wastewater using several biodegradable natural polymers and their composites. J Clean Prod 291:125920. https://doi.org/10.1016/j.jclepro.2021.125920
Zheng X, Zheng H, Zhou Y et al (2019) Enhanced adsorption of orange G from aqueous solutions by quaternary ammonium group-rich magnetic nanoparticles. Colloids Surf Physicochem Eng Asp 580:123746. https://doi.org/10.1016/j.colsurfa.2019.123746
Zheng Y, Liu Y, Wang A (2012) Kapok fiber oriented polyaniline for removal of sulfonated dyes. Ind Eng Chem Res 51:10079–10087. https://doi.org/10.1021/ie300246m
Author information
Authors and Affiliations
Contributions
Abdelaziz Imgharn: conceptualization, methodology, formal analysis, investigation, data curation, writing-original draft. Nouh Aarab: participation in the design. Abdelghani Hsini: writing-review and editing, investigation, methodology. Yassine Naciri: writing — review and editing, investigation, methodology. Mahmoud Elhoudi: investigation, methodology. Mohamed Ait Haki: writing — review and editing. Mohamed Laabd: conceptualization, validation, writing — review and editing, investigation, methodology. Rajae Lakhmiri: supervision. Abdallah Albourine: conceptualization, supervision.
Corresponding author
Ethics declarations
Ethics approval
This study was approved by the research ethics committee of Ibn Zohr University.
Consent to participate
All the authors participated in this article.
Consent for publication
All the authors agreed this article be published.
Competing interests
The authors declare no competing interests.
Additional information
Responsible Editor: Angeles Blanco.
Publisher's note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Imgharn, A., Aarab, N., Hsini, A. et al. Application of calcium alginate-PANI@sawdust wood hydrogel bio-beads for the removal of orange G dye from aqueous solution. Environ Sci Pollut Res 29, 60259–60268 (2022). https://doi.org/10.1007/s11356-022-20162-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-022-20162-9