Abstract
Lithium-ion batteries and supercapacitors are examples of energy storage technologies that have a lot of promise in a variety of applications. Herein, NiO-porous carbon composites were prepared by a green and cost-effective facile synthesis route from banana peel waste materials. The surface morphology and chemical composition of the NiO-porous carbon composite were investigated using a scanning electron microscope (SEM) and energy dispersive x-ray analysis (EDX). The prepared samples were also described through Fourier transform infrared (FTIR) spectroscopy, x-ray powder diffraction (XRD), thermal gravimetric analysis (TGA), and surface area measurements. The electrochemical behavior of prepared materials was studied by cyclic voltammetry (CV), galvanostatic charge-discharge, and electrochemical impedance (EIS) to test their applicable suitability as supercapacitor electrode. PC-NiO (3) composite exhibits a remarkable specific capacitance of 811 F/g at a current density of 1 A/g. The specific capacitance of PC-NiO (3) is 5.3 times more than that of PC material at 1.0 A/g. Furthermore, the PC-NiO (3) composite material still exhibits a specific capacitance of 780 F/g at 5.0 A/g, high rate capability of 84.55% retention at a high current density of 10.0 A/g and superior cycle stability at 1000 cycles. Based on its high specific capacitance, the NiO-porous carbon nanocomposite is one of the most promising electrode materials for supercapacitors, according to the above results.
Similar content being viewed by others
References
Abdelhameed RM, Al Kiey SA, Wassel AR, El-Shahat M (2021) Silver chromate doped Ti-based metal organic framework: synthesis, characterization, and electrochemical and selective photocatalytic reduction properties. New J Chem 45:9526–9537
Abioye AM, Noorden ZA, Ani FN (2017) Synthesis and characterizations of electroless oil palm shell based-activated carbon/nickel oxide nanocomposite electrodes for supercapacitor applications. Electrochim Acta 225:493–502
Abou Hammad A, Abd El-Aziz M, Hasanin M, Kamel S (2019) A novel electromagnetic biodegradable nanocomposite based on cellulose, polyaniline, and cobalt ferrite nanoparticles. Carbohydr Polym 216:54–62
Aly AA, Ahmed MK (2021) Nanofibers of cellulose acetate containing ZnO nanoparticles/graphene oxide for wound healing applications. Int J Pharm 598:120325
Bao N, Shen L, Wang YHA, Ma J, Mazumdar D, Gupta A (2009) Controlled growth of monodisperse self-supported superparamagnetic nanostructures of spherical and rod-like CoFe2O4 nanocrystals. J Am Chem Soc 131:12900–12901
Basta AH, Lotfy VF, Hasanin MS, Trens P, El-Saied H (2019) Efficient treatment of rice byproducts for preparing high-performance activated carbons. J Clean Prod 207:284–295
Cao F, Pan G, Xia X, Tang P, Chen H (2014) Synthesis of hierarchical porous NiO nanotube arrays for supercapacitor application. J Power Sources 264:161–167
Chen J, Peng X, Song L, Zhang L, Liu X, Luo J (2018) Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors. R Soc Open Sci 5:180842
Conway BE (n.d.) Electrochemical supercapacitors: scientific fundamentals and technological applications. Springer Science & Business Media
Dharmaraj N, Prabu P, Nagarajan S, Kim CH, Park JH, Kim HY (2006) Synthesis of nickel oxide nanoparticles using nickel acetate and poly(vinyl acetate) precursor. Mater Sci Eng B 128:111–114
Du D, Hu Z, Liu Y, Deng Y, Liu J (2014) Preparation and characterization of flower-like microspheres of nano-NiO as electrode material for supercapacitor. J Alloys Compd 589:82–87
El-Kader MFHA, Ahmed MK, Elabbasy MT, Afifi M, Menazea AA (2021) Morphological, ultrasonic mechanical and biological properties of hydroxyapatite layers deposited by pulsed laser deposition on alumina substrates. Surf Coat Technol 409:126861
Ferrero G, Fuertes A, Sevilla M (2015) From soybean residue to advanced supercapacitors. Sci Rep 5:16618
Gawali SR, Dubal DP, Deonikar VG, Patil SS, Patil SD, Gomez-Romero P, Patil DR, Pant J (2016) Asymmetric supercapacitor based on nanostructured Ce-doped NiO (Ce: NiO) as positive and reduced graphene oxide (rGO) as negative electrode. ChemistrySelect 1:3471–3478
Gomes Ferreira de Paula F, Campello-Gómez I, PFR O, Rodríguez-Reinoso F, Martínez-Escandell M, Silvestre-Albero J (2019) Structural flexibility in activated carbon materials prepared under harsh activation conditions. Materials 12:1988
Huang K-J, Zhang J-Z, Shi G-W, Liu Y-M (2014) Hydrothermal synthesis of molybdenum disulfide nanosheets as supercapacitors electrode material. Electrochim Acta 132:397–403
Karaman C (2021) Orange peel derived-nitrogen and sulfur Co-doped carbon dots: a nano-booster for enhancing ORR electrocatalytic performance of 3D graphene networks. Electroanalysis 33:1356–1369
Karaman C, Bayram E, Karaman O, Aktaş Z (2020) Preparation of high surface area nitrogen doped graphene for the assessment of morphologic properties and nitrogen content impacts on supercapacitors. J Electroanal Chem 868:114197
Karaman C, Karaman O, Atar N, Yola ML (2021) Tailoring of cobalt phosphide anchored nitrogen and sulfur co-doped three dimensional graphene hybrid: boosted electrocatalytic performance towards hydrogen evolution reaction. Electrochim Acta 380:138262
Kayani ZN, Butt MZ, Riaz S, Naseem S (2018) Synthesis of NiO nanoparticles by sol-gel technique. Mater Sci-Pol 36:547–552
Kötz R, Carlen M (2000) Principles and applications of electrochemical capacitors. Electrochim Acta 45:2483–2498
Kumar A, Dixit CK (2017) Methods for characterization of nanoparticles, Advances in nanomedicine for the delivery of therapeutic nucleic acids. Elsevier, pp:43–58
Lamiel C, Kumar DR, Shim J-J (2017) Microwave-assisted binder-free synthesis of 3D Ni-Co-Mn oxide nanoflakes@ Ni foam electrode for supercapacitor applications. Chem Eng J 316:1091–1102
Lashkenari MS, Ghorbani M, Silakhori N, Karimi-Maleh H (2021) Enhanced electrochemical performance and stability of Pt/Ni electrocatalyst supported on SiO2-PANI nanocomposite: a combined experimental and theoretical study. Mater Chem Phys 262:124290
Lee JW, Hall AS, Kim J-D, Mallouk TE (2012a) A facile and template-free hydrothermal synthesis of Mn3O4 nanorods on graphene sheets for supercapacitor electrodes with long cycle stability. Chem Mater 24:1158–1164
Lee JW, Ko JM, Kim J-D (2012b) Hydrothermal preparation of nitrogen-doped graphene sheets via hexamethylenetetramine for application as supercapacitor electrodes. Electrochim Acta 85:459–466
Lota K, Sierczynska A, Lota G (2011) Supercapacitors based on nickel oxide/carbon materials composites. International Journal of Electrochemistry 2011:1–6
Lu Q, Lattanzi MW, Chen Y, Kou X, Li W, Fan X, Unruh KM, Chen JG, Xiao JQ (2011) Supercapacitor electrodes with high-energy and power densities prepared from monolithic NiO/Ni nanocomposites. Angew Chem Int Ed 50:6847–6850
Miller JR, Simon P (2008) Electrochemical capacitors for energy management. Science Magazine 321:651–652
Mopoung S, Moonsri P, Palas W (2015) Khumpai S (2015): Characterization and properties of activated carbon prepared from tamarind seeds by KOH activation for Fe (III) adsorption from aqueous solution. Sci World J 2015:1–9
Moradlou O, Ansarinejad H, Hosseinzadeh M, Kazemi H (2018) High-performance solid state asymmetric supercapacitor based on electrochemically decorated 3D network-like Co3O4 architecture on NiO nanoworms. J Alloys Compd 755:231–241
Nyholm L, Nyström G, Mihranyan A, Strømme M (2011) Toward flexible polymer and paper-based energy storage devices. Adv Mater 23:3751–3769
Saidur R, Abdelaziz E, Demirbas A, Hossain M, Mekhilef S (2011) A review on biomass as a fuel for boilers. Renew Sust Energ Rev 15:2262–2289
Service RF (2006) New‘supercapacitor’promises to pack more electrical punch. American Association for the Advancement of Science
Shalan AE, Sharmoukh W, Elshazly AN, Elnagar MM, Al Kiey SA, Rashad MM, Allam NK (2020) Dopant-free hole-transporting polymers for efficient, stable, and hysteresis-less perovskite solar cells. Sustain Mater Technol 26:e00226
Sharmoukh W, Al Kiey SA, Ali BA, Menon L, Allam NK (2020) Recent progress in the development of hole-transport materials to boost the power conversion efficiency of perovskite solar cells. Sustainable Materials and Technologies, e00210
Simon P, Gogotsi Y (2010) Materials for electrochemical capacitors, Nanoscience and technology: a collection of reviews from Nature journals. World Scientific, pp:320–329
Subramanian V, Luo C, Stephan AM, Nahm K, Thomas S, Wei B (2007) Supercapacitors from activated carbon derived from banana fibers. J Phys Chem C 111:7527–7531
Thomas P, Lai CW, Johan MRB (2019) Recent developments in biomass-derived carbon as a potential sustainable material for super-capacitor-based energy storage and environmental applications. J Anal Appl Pyrolysis 140:54–85
Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KS (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl Chem 87:1051–1069
Wang H, Zhong Y, Li Q, Yang J, Dai Q (2008) Cationic starch as a precursor to prepare porous activated carbon for application in supercapacitor electrodes. J Phys Chem Solids 69:2420–2425
Wang G, Zhang L, Zhang J (2012) A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev 41:797–828
Wang C, Xu J, Yuen MF, Zhang J, Li Y, Chen X, Zhang W (2014) Hierarchical composite electrodes of nickel oxide nanoflake 3D graphene for high-performance pseudocapacitors. Adv Funct Mater 24:6372–6380
Wang Y, Guo J, Wang T, Shao J, Wang D, Yang Y-W (2015) Mesoporous transition metal oxides for supercapacitors. Nanomaterials 5:1667–1689
Warren R, Sammoura F, Tounsi F, Sanghadasa M, Lin L (2015) Highly active ruthenium oxide coating via ALD and electrochemical activation in supercapacitor applications. J Mater Chem A 3:15568–15575
Wei L, Yushin G (2012) Nanostructured activated carbons from natural precursors for electrical double layer capacitors. Nano Energy 1:552–565
Wei W, Cui X, Chen W, Ivey DG (2011) Manganese oxide-based materials as electrochemical supercapacitor electrodes. Chem Soc Rev 40:1697–1721
Wu ZS, Wang DW, Ren W, Zhao J, Zhou G, Li F, Cheng HM (2010) Anchoring hydrous RuO2 on graphene sheets for high-performance electrochemical capacitors. Adv Funct Mater 20:3595–3602
Zeng Y, Yu M, Meng Y, Fang P, Lu X, Tong Y (2016) Iron-based supercapacitor electrodes: advances and challenges. Adv Energy Mater 6:1601053
Zhao S, Wang C-Y, Chen M-M, Wang J, Shi Z-Q (2009) Potato starch-based activated carbon spheres as electrode material for electrochemical capacitor. J Phys Chem Solids 70:1256–1260
Acknowledgements
The authors thank the National Research Centre (NRC) for the technical support.
Availability of data and materials
All data and materials are available.
Funding
The authors thank the National Research Centre (NRC) for the financial support.
Author information
Authors and Affiliations
Contributions
S.A. Al Kiey and M.S. Hassenin: Conceptualization, formal analysis, writing — review and editing, project administration, funding acquisition, supervision
Corresponding author
Ethics declarations
Ethical approval
Not applicable
Consent to participate
The authors are consent to participate the article.
Consent to publish
The authors are consent to publish the article.
Competing interests
The authors declare no competing interests.
Additional information
Responsible Editor: Weiming Zhang
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Al Kiey, S.A., Hasanin, M.S. Green and facile synthesis of nickel oxide-porous carbon composite as improved electrochemical electrodes for supercapacitor application from banana peel waste. Environ Sci Pollut Res 28, 66888–66900 (2021). https://doi.org/10.1007/s11356-021-15276-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-021-15276-5