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Critical insights into the effects of plastic pyrolysis oil on emission and performance characteristics of CI engine

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Abstract

Pyrolysis is an encouraging solution considering the facts of energy demand and waste plastic management as it produces liquid fuel for compression ignition engine application. This study provides critical insights into the effects of waste plastic oil on the emission and performance characteristics of compression ignition engines. Though most of the studies have shown a negative influence, promising outcomes have been noticed in a few specific cases. A maximum of 71%, 80%, 76%, 71%, 21%, and 13% decrease in nitrogen oxide emission, carbon monoxide emission, unburnt hydrocarbon emission, smoke emission, exhaust gas temperature, and brake-specific fuel consumption, respectively, have been noticed with waste plastic oil or its blends at certain operating conditions. Nevertheless, the presence of long carbon chains, higher aromatic content, and non-homogeneous air-fuel mixture owing to the wide product distribution in plastic oil are the few reasons which affected the emission and performance characteristics of the engines. More rigorous investigations are needed to improve the quality of the fuel and to establish correlations between the fuel properties and pyrolysis parameters. In addition, the effects of incorporating exhaust gas recirculation, emulsification process, and use of additives with waste plastic oil need to be explored more for reducing the emissions with satisfactory engine performance, and in this regard, the use of bio-additives with waste plastic oil can provide a new direction to this research field. Further, studies on the economic feasibility and the impact of waste plastic oil on engine materials are also required.

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Abbreviations

BSFC:

Brake-specific fuel consumption

CI:

Compression ignition

CO:

Carbon monoxide

CV:

Calorific value

DEE:

Diethyl ether

EGR:

Exhaust gas recirculation

EGT:

Exhaust gas temperature

HC:

Unburnt hydrocarbon

HDPE:

High-density polyethylene

HRR:

Heat release rate

ID:

Ignition delay

LDPE:

Low-density polyethylene

MP:

Mixed plastic

MPW:

Medical plastic waste

MSW:

Municipal solid plastic waste

NOx :

Oxides of nitrogen

PE:

Polyethylene

WPO:

Waste plastic oil

TiO2 :

Titanium oxide

P2.5:

2.5% MP-derived oil + 97.5% diesel

P7.5:

7.5% MP-derived oil + 92.5% diesel

P12.5:

12.5% MP-derived oil + 87.5% diesel

P100:

100% MP-derived oil

B20:

20% PE-derived oil + 80% diesel

D50WPO40B10:

50% diesel + 40% WPO derived from MSW+ 10% n-butanol

D50WPO30B20:

50% diesel + 30% WPO derived from MSW + 20% n-butanol

D50WPO20B30:

50% diesel + 20% WPO derived from MSW + 30% n-butanol

WPOEGR10%:

100% MSW-derived oil with EGR (10%)

WPOEGR20%:

100% MSW-derived oil with EGR (20%)

WPOEGR30%:

100% MSW-derived oil with EGR (30%)

WPO70P30 EGR10%:

70% MSW-derived + 30% n-pentanol oil with EGR (10%)

WPO70P30 EGR20%:

70% MSW-derived + 30% n-pentanol oil with EGR (20%)

WPO70P30 EGR30%:

70% MSW-derived + 30% n-pentanol oil with EGR (30%)

WPPO:

100% WPO derived from MP

WD05:

95% WPPO + 5% DEE

WD10:

90% WPPO + 10% DEE

PO:

Plastic oil derived from HDPE

PO25:

25% PO + 75% diesel

PO50:

50% PO + 50% diesel

PO75:

75% PO + 25% diesel

PD5:

5% DEE + 95% PO

PD10:

10% DEE + 90% PO

PD15:

15% DEE + 85% PO

PPO:

Plastic pyrolyzed oil from MP

PPO25:

25% PPO + 75% diesel

PPO50:

50% PPO + 50% diesel

PPO75:

75% PPO + 25% diesel

PPO90:

90% PPO + 10% diesel

PPO100:

100% PPO

LDPE700:

LDPE-derived oil at 700°C

PPO700:

Plastic pyrolyzed oil from MP (at 700°C)

PPO700-75:

75% PPO700 + 25% diesel

PPO900:

Plastic pyrolyzed oil from MP (at 900°C)

PPO900-75:

75% PPO900 + 25% diesel

PW10:

10% water + 90% WPO derived from MP

PW20:

20% water + 80% WPO derived from MP

PW30:

30% water + 70% WPO derived from MP

WPF10D90:

10% WPO (from MP) + 90% diesel

WPF20D80:

20% WPO (from MP) + 80% diesel

WPF30D70:

30% WPO (from MP) + 70% diesel

WPF100:

100% WPO (from MP)

10%BWPO:

10% WPO derived from HDPE + 90% diesel

20%BWPO:

20% WPO derived from HDPE + 80% diesel

30%BWPO:

30% WPO derived from HDPE + 70% diesel

40%BWPO:

40% WPO derived from HDPE + 60% diesel

WPO10%EGR:

WPO with application of EGR (10%)

WPO20%EGR:

WPO with application of EGR (20%)

WPO10:

10% WPO + 90% diesel

WPO30:

30% WPO + 70% diesel

WPO50:

50% WPO + 50% diesel

WPO70:

70% WPO + 30% diesel

PF10:

10% WPO (from MP) + 90% diesel

PF20:

20% WPO (from MP) + 80% diesel

PF30:

30% WPO (from MP) + 70% diesel

10%BWPO:

10% WPO derived from PP + 90% diesel

20%BWPO:

20% WPO derived from PP + 80% diesel

30%BWPO:

30% WPO derived from PP + 70% diesel

40%BWPO:

40% WPO derived from PP + 60% diesel

50%BWPO:

50% WPO derived from PP + 50% diesel

B20AOME10WPO:

10 % WPO (from MP) + 90 % B20 algae biodiesel

PJ10:

10% jatropha methyl ester + 90% WPO (from MP)

PJ20:

20% jatropha methyl ester + 80% WPO (from MP)

PE10%:

10% LDPE-derived oil + 90% diesel

10WPO:

10% WPO (from MPW) + 90% diesel

20WPO:

20% WPO (from MPW) + 80% diesel

30WPO:

30% WPO (from MPW) + 70% diesel

PP700:

Plastic pyrolyzed oil from PP (at 700°C)

PP700-75:

75% PP700 + 25% diesel

PP900:

Plastic pyrolyzed oil from PP (at 900°C)

PP900-75:

75% PP900 + 25% diesel

PPO (LDPE):

Plastic pyrolytic oil derived from LDPE

D80PO20:

80% diesel + 20% PPO (LDPE)

D70B20P10:

70% diesel + 20% biodiesel + 10% WPO

D60B20P20:

60% diesel + 20% biodiesel + 20% WPO

ULDP:

Used low-density derived polyethylene

ULDP20:

80% diesel + 20% ULDP

ULDP40:

60% diesel + 40% ULDP

ULDP60:

60% diesel + 60% ULDP

ULDP80:

20% diesel + 80% ULDP

5PPO:

5% PP-derived oil + 95% diesel

10PPO:

10% PP-derived oil + 90% diesel

15PPO:

15% PP-derived oil + 85% diesel

50%HDPE:

50% HDPE oil + 50% diesel

PPO (PE):

WPO derived from PE

PPO (PE) + 25 ppm TiO2 :

25 ppm added with PPO (PE)

PPO (PE) + 50 ppm TiO2 :

50 ppm added with PPO (PE)

PPO (PE) + 75 ppm TiO2 :

75 ppm added with PPO (PE)

PPO (PE) + 100 ppm TiO2 :

100 ppm added with PPO (PE)

PO15%:

85% diesel + 15% WPO derived from mixture of LDPE and HDPE

PO30%:

85% diesel + 30% WPO derived from mixture of LDPE and HDPE

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DS: literature review and writing the original draft of the manuscript; AS: critical review, expert view, and supervision of the manuscript; BR: supervision of the manuscript. All the authors contributed to the research article and approved the final version.

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Correspondence to Dipankar Saha.

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Responsible Editor: Philippe Garrigues

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Saha, D., Sinha, A. & Roy, B. Critical insights into the effects of plastic pyrolysis oil on emission and performance characteristics of CI engine. Environ Sci Pollut Res 28, 44598–44621 (2021). https://doi.org/10.1007/s11356-021-14919-x

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  • DOI: https://doi.org/10.1007/s11356-021-14919-x

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