Abstract
The anthropogenic carbon dioxide (CO2) denseness in the earth’s atmosphere is increasing day-to-day by combusting fossil fuels for power generation. And, it is the most important greenhouse gas (GHG) responsible for 64% of global warming. Solvent-based carbon capture gained more attention towards researchers because of its easiness to integrate with the coal-fired power plant without significant modifications. During CO2 absorption, the physical property of the solvent gets changed. A change in the solvent’s physicochemical property affects further CO2 absorption, thereby increasing the carbon-capture energy demand. The present experimental study encompasses CO2 absorption studies using 30 wt% aqueous monoethanolamine (MEA), 2-amino-2-methyl-1-propanol (AMP) and piperazine (PZ) followed by the detailed analysis of physicochemical properties (pH, carbon loading (α), viscosity (μ), density (ρ) and surface tension (σ)) of various CO2-loaded solutions. The results revealed that these properties are exhibiting interdependent eccentrics. Furthermore, an empirical model was developed to predict the carbon loading of the tested solvents. This model includes the tested physicochemical properties, reaction mixture temperature, diffusivity and change in the mass of solvent during carbon loading. In addition, an empirical model for viscosity as a function of temperature, carbon loading and molecular weight of solvents was developed. These models appear to predict the carbon loading and the viscosity well with greater accuracy.
Similar content being viewed by others
References
Alvarez E, Rendo R, Sanjuro B, Sanchez-vilas M, Navaza JM (1998) Surface tension of binary mixtures of water + N-methyldiethanolamine and ternary mixtures of this amine and water with monoethanolamine, diethanolamine, and 2-amino-2-methyl-1-propanol from 25 to 50 °C. J Chem Eng Data 43:1027–1029. https://doi.org/10.1021/je980106y
Amundsen TG, Oi LE, Eimers DA (2009) Density and viscosity of monoethanolamine + water + carbon dioxide from (25 to 80) °C. J Chem Eng Data 54:3096–3100. https://doi.org/10.1021/je900188m
Arachchige USPR, Aryal N, Eimer DA, Melaaen MC (2014) Viscosities of pure and aqueous solutions of monoethanolamine (MEA), diethanolamine (DEA) and N-methyldiethanolamine (MDEA). Ann Trans Nordic Rheol Soc 22.
Balchandani S, Mandal B, Dharaskar S, Kumar A, Bandyopadhyay S (2019) Thermally induced characterization and modeling of physicochemical, acoustic, rheological, and thermodynamic properties of novel blends of (HEF + AEP) and (HEF + AMP) for CO2/H2S absorption. Environ Sci Pollut Res 26:32209–32223. https://doi.org/10.1007/s11356-019-06305-5
Deng Q, Alvarado R, Toledo E, Caraguay L (2020) Greenhouse gas emissions, non-renewable energy consumption, and output in South America: the role of the productive structure. Environ Sci Pollut Res 27:1–15. https://doi.org/10.1007/s11356-020-07693-9
DiGuilio RM, Lee RJ, Schaeffer ST, Brasher LL, Teja AS (1992) Densities and viscosities of the ethanolamines. J Chem Eng Data 37:239–242. https://doi.org/10.1021/je00006a028
Fu D, Chen L, Qin L (2012) Experiment and model for the viscosity of carbonated MDEA–MEA aqueous solutions. Fluid Phase Equilib 310:42–47. https://doi.org/10.1016/j.fluid.2012.01.029
Fu D, Li Z, Liu F (2014) Experiments and model for the viscosity of carbonated 2-amino-2-methyl-1-propanol and piperazine aqueous solution. J Chem Thermodynamics 68:20–24. https://doi.org/10.1016/j.jct.2013.08.025
Garcia M, Knuutila HK, Gu S (2017) ASPEN PLUS simulation model for CO2 removal with MEA: validation of desorption model with experimental data. J Environ Chem Eng 5:4693–4701. https://doi.org/10.1016/j.jece.2017.08.024
Ghadiri M, Marjani A, Shirazian S (2017) Development of a mechanistic model for prediction of CO2 capture from gas mixtures by amine solutions in porous membranes. Environ Sci Pollut Res 24:14508–14515. https://doi.org/10.1007/s11356-017-9048-8
Guo H, Hui L, Shen S (2019) Monoethanolamine + 2-methoxyethanol mixtures for CO2 capture: density, viscosity and CO2 solubility. J Chem Thermodynamics 132:155–163. https://doi.org/10.1016/j.jct.2018.12.028
Han J, Jin J, Eimer DA, Melaaen MC (2012) Density of water (1) + monoethanolamine (2) + CO2 (3) from (298.15 to 413.15) K and surface tension of water (1) + monoethanolamine (2) from (303.15 to 333.15) K. J Chem Eng Data 57:1095–1103. https://doi.org/10.1021/je2010038
Hartono A, Mba EO, Svendsen HF (2014) Physical properties of partially CO2 loaded aqueous monoethanolamine (MEA). J Chem Eng Data 59:1808–1816. https://doi.org/10.1021/je401081e
Idris Z, Kummamuru NB, Eimer DA (2017) Viscosity measurement of unloaded and CO2-loaded aqueous monoethanolamine at higher concentrations. J Mol Liq 243:638–645. https://doi.org/10.1016/j.molliq.2017.08.089
James T, Yeh H, Pennline W (2004) Third annual conference on carbon capture & sequestration. DOE/NETL, Alexandria
Jayarathna SA, Jayarathna CK, Kottage DA, Dayarathna S, Eimer DA, Melaaen MC (2013) Density and surface tension measurements of partially carbonated aqueous monoethanolamine solutions. J Chem Eng Data 58:343–348. https://doi.org/10.1021/je300920t
Ji L, Miksche SJ, Rimpf LM, Farthing GA (2009) 8th annual conference on carbon capture and sequestration. DOE/NETL Pittsburgh, Pennsylvania
Liu J, Wang S, Qi G, Zhao B, Chen C (2011) Kinetics and mass transfer of carbon dioxide absorption into aqueous ammonia. Energy Procedia 4:525–532. https://doi.org/10.1016/j.egypro.2011.01.084
Lv B, Guo B, Zhou Z, Jin G (2015) Mechanisms of CO2 capture into monoethanolamine solution with different CO2 loading during the absorption/desorption processes. Environ Sci Technol 49:10728–10735. https://doi.org/10.1021/acs.est.5b02356
Mandal BP, Bandyopadhyay SS (2006) Absorption of carbon dioxide into aqueous blends of 2-amino-2-methyl-1-propanol and monoethanolamine. Chem Eng Sci 61:5440–5447. https://doi.org/10.1016/j.ces.2006.04.002
Masiren EE, Harun N, Ibrahim WHW, Adam F (2016) Effect of temperature on diffusivity of monoethanolamine (MEA) on absorption process for CO2 capture. Int J Eng Technol Sci 5:43–51. https://doi.org/10.15282/ijets.5.2016.1.6.1045
Matin NS, Steckel JA, Thompson J, Sarma M, Liu K (2017) Application of surface tension model for prediction of interfacial speciation of CO2-loaded aqueous solutions of monoethanolamine. Ind Eng Chem Res 56:5747–5755. https://doi.org/10.1021/acs.iecr.7b00041
Muhammad A, Mutalib MIA, Murugesan T, Shafeeq A (2009) Thermophysical properties of aqueous piperazine and aqueous (N-methyldiethanolamine + piperazine) solutions at temperatures (298.15 to 338.15) K. J Chem Eng Data 54:2317–2232. https://doi.org/10.1021/je9000069
Murshid G, Shariff AM, Keong LK, Bustam MA (2011) Physical properties of aqueous solutions of piperazine and (2-amino-2-methyl-1-propanol + piperazine) from (298.15 to 333.15) K. J Chem Eng Data 56:2660–2663. https://doi.org/10.1021/je10125806
Naims H (2016) Economics of carbon dioxide capture and utilization—a supply and demand perspective. Environ Sci Pollut Res 23:22226–22241. https://doi.org/10.1007/s11356-016-6810-2
Nakagaki T, Tanaka I, Furukawa Y, Sato H, Yamanaka Y (2014) Experimental evaluation of effect of oxidative degradation of aqueous monoethanolamine on heat of CO2 absorption, vapor liquid equilibrium and CO2 absorption rate. Energy Procedia 63:2384–2393. https://doi.org/10.1016/j.egypro.2014.11.260
Narimani M, Amjad-Iranagh S, Modarress H (2017) CO2 absorption into aqueous solutions of monoethanolamine, piperazine and their blends: quantum mechanics and molecular dynamics studies. J Mol Liq 233:173–183. https://doi.org/10.1016/j.molliq.2017.03.015
Nilavuckkarasi RK, Muthumari P, Ambedkar B, Moniha M (2020) Carbon-rich solvent regeneration in solvent-based post-combustion CO2 capture process (PCCC): process intensification by megasonics. Chem Eng Process Process Intensif 151:107913. https://doi.org/10.1016/j.cep.2020.107913
Park SH, Lee KB, Hyun JC, Kim SH (2002) Correlation and prediction of the solubility of carbon dioxide in aqueous alkanolamine and mixed alkanolamine solutions. Ind Eng Chem Res 41:1658–1665. https://doi.org/10.1021/ie010252o
Ramachandran N, Aboudheir A, Idem R, Tontiwachwuthikul P (2007) Kinetics of the absorption of CO2 into mixed aqueous loaded solutions of monoethanolamine and methyldiethanolamine. Ind Eng Chem Res 45:2608–2616. https://doi.org/10.1021/ie0505716
Rebolledo-Libreros ME, Trejo A (2006) Density and viscosity of aqueous blends of three alkanolamines: N-Methyldiethanolamine, diethanolamine, and 2-Amino-2-methyl-1-propanol in the range of (303 to 343) K. J Chem Eng Data 51:702–707. https://doi.org/10.1021/je050462y
Sabouni R, Kazemian H, Rohani S (2014) Carbon dioxide capturing technologies: a review focusing on metal organic framework materials (MOFs). Environ Sci Pollut Res 21:5427–5449. https://doi.org/10.1007/s11356-013-2406-2
Saha AK, Bandyopadhyay SS, Biswas AK (1995) Kinetics of absorption of CO2 into aqueous solutions of 2-amino-2-methyl-1-propanol. Chem Eng Sci 50:3587–3598. https://doi.org/10.1016/0009-2509(95)00187-A
Samanta A, Bandyopadhyay SS (2006) Density and viscosity of aqueous solutions of piperazine and (2-amino-2-methyl-1-propanol + piperazine) from 298 to 333 K. J Chem Eng Data 51:467–470. https://doi.org/10.1021/je050378i
Shokouhi M, Jalili AH, Samani F, Hosseini-Jenab M (2015) Experimental investigation of the density and viscosity of CO2-loaded aqueous alkanolamine solutions. Fluid Phase Equilib 404:96–108. https://doi.org/10.1016/j.fluid.2015.06.034
Snijder ED, te Riele MJ, Versteeg GF, Van Swaaij WPM (1993) Diffusion coefficients of several aqueous alkanolamine solutions. J Chem Eng Data 38:475–480. https://doi.org/10.1021/je00011a037
Stec M, Spietz T, Więcław-Solny L, Tatarczuk A, Wilk A, Sobolewski A (2016) Density of unloaded and CO2-loaded aqueous solutions of piperazine and 2-amino-2-methyl-1-propanol and their mixtures from 293.15 to 333.15 K. Phys Chem Liq 54:475–486. https://doi.org/10.1080/00319104.2015.1115328
Vazquez G, Alvarez E, Navaza JM, Rendo R, Romero E (1997) Surface tension of binary mixtures of water + monoethanolamine and water + 2-amino-2-methyl-1-propanol and tertiary mixtures of these amines with water from 25°C to 50°C. J Chem Eng Data 42:57–59. https://doi.org/10.1021/je960238w
Versteeg GF, Van Swaaij WP (1988) Solubility and diffusivity of acid gases (carbon dioxide, nitrous oxide) in aqueous alkanolamine solutions. J Chem Eng Data 33:29–34. https://doi.org/10.1021/je00051a011
Weiland RH, Dingman JC, Cronin DB, Browning GJ (1998) Density and viscosity of some partially carbonated aqueous alkanolamine solutions and their blends. J Chem Eng Data 43:378–382. https://doi.org/10.1021/je9702044
Xie H, Wang P, He N, Yang X (2015) Toward rational design of amines for CO2 capture: substituent effect on kinetic process for the reaction of monoethanolamine with CO2. J Environ Sci 37:75–82. https://doi.org/10.1016/j.jes.2015.03.033
Xu S, Wang YW, Otto FD, Mather AE (1996) Kinetics of the reaction of carbon dioxide with 2-amino-2-methyl-1-propanol solutions. Chem Eng Sci 51:841–850. https://doi.org/10.1016/0009-2509(95)00327-4
Zhang J, Fennell PS, Trusler JM (2015) Density and viscosity of partially carbonated aqueous tertiary alkanolamine solutions at temperatures between (298.15 and 353.15) K. J Chem Eng Data 60:2392–2399. https://doi.org/10.1021/acs.jced.5b00282
Funding
The authors received funding support from the Science & Engineering Research Board (SERB; File No. EEQ/2016/000420) (a statutory body of the Department of Science & Technology, Government of India), New Delhi, India.
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible Editor: Tito Roberto Cadaval Jr
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Highlights
• Detailed analysis on physicochemical characteristics of different carbon-loaded 30 wt% aqueous MEA/AMP/PZ solutions.
• Non-dimensional model to predict the carbon loading of the 30 wt% aqueous MEA/AMP/PZ solution was developed.
• In addition, a predictive model for viscosity as a function of solvent molecular weight, temperature and carbon loading of the 30 wt% aqueous MEA/AMP/PZ solution was formulated with greater accuracy.
Rights and permissions
About this article
Cite this article
Perumal, M., Karunakaran, N.R., Balraj, A. et al. Experimental investigation on CO2 absorption and physicochemical characteristics of different carbon-loaded aqueous solvents. Environ Sci Pollut Res 28, 63532–63543 (2021). https://doi.org/10.1007/s11356-020-10562-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-020-10562-0