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Highly effective surface modification using plasma technologies toward green coloration of polyester fabrics

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Abstract

This study is anchored on the use of an eco-friendly effective plasma technique and cationization treatment to improve the hydrophobic nature of polyester (PET) fabric by incorporating hydrophilic functional groups onto the PET surface. The PET surface was initially treated with three different plasma gases prior to cationization treatment with quaternary ammonium salt (Quat 188). Madder roots were used, to produce natural dyes for the green coloration of PET fabrics in both dyeing and printing processes. The color strength (K/S) was measured to study the influence of both plasma gases and the cationization treatment on the coloration of PET fabric. Exposure to nitrogen plasma gases prior to the cationization treatment showed promising results for efficient PET coloration, resulting in the selection of nitrogen as a working gas at a flow rate of 3 l/min. The results also demonstrated that by combining the nitrogen plasma technique and cationization treatment, PET fabric with a highly effective surface was obtained, resulting in improved coloration, wettability, tensile strength, and roughness properties.

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References

  • Abdelghaffar F, Abdelghaffar RA, Arafa AA, Kamel MM (2018) Functional antibacterial finishing of woolen fabrics using ultrasound technology. Fibers Polym 19:2103–2111

    CAS  Google Scholar 

  • Abdelghaffar F, Abdelghaffar RA, Mahmoud SA, Youssef BM (2019) Modified sugarcane bagasse for the removal of anionic dyes from aqueous solution. Pigm Resin Technol 48:464–471

    CAS  Google Scholar 

  • Adeel S, Gulzar T, Azeem M, Saeed M, Hanif I, Iqbal N (2017) Appraisal of marigold flower based lutein as natural colourant for textile dyeing under the influence of gamma radiations. Radiat Phys Chem 130:35–39

    CAS  Google Scholar 

  • Agnhage T, Perwuelz A, Behary N (2016) Eco-innovative coloration and surface modification of woven polyester fabric using bio-based materials and plasma technology. J Ind Crops Prod 86:334–341

    CAS  Google Scholar 

  • Agnhage T, Zhou Y, Guan J, Chen G, Perwuelz A, Behary N, Nierstrasz V (2017) Bioactive and multifunctional textile using plant-based madder dye: characterization of UV protection ability and antibacterial activity. Fibers Polym 18:2170–2175

    CAS  Google Scholar 

  • Ahmed H, Khattab TA, Mashaly H, El-Halwagy A, Rehan M (2020) Plasma activation toward multi-stimuli responsive cotton fabric via in situ development of polyaniline derivatives and silver nanoparticles. Cellulose: 27:2913–2926. https://doi.org/10.1007/s10570-020-02980-7

  • Barani H, Maleki H (2011) Plasma and ultrasonic process in dyeing of wool fibers with madder in presence of lecithin. J Dispers Sci Technol 32:1191–1199

    CAS  Google Scholar 

  • Blackburn RS (2017) Natural dyes in madder (Rubia spp.) and their extraction and analysis in historical textiles. Color Technol 133:449–462

    CAS  Google Scholar 

  • Costa T, Feitor M, Alves C Jr, Freire P, De Bezerra C (2006) Effects of gas composition during plasma modification of polyester fabrics. J Mater Process Technol 173:40–43

    CAS  Google Scholar 

  • Elabid AE, Zhang J, Shi J, Guo Y, Ding K, Zhang J (2016) Improving the low temperature dyeability of polyethylene terephthalate fabric with dispersive dyes by atmospheric pressure plasma discharge. Appl Surf Sci 375:26–34

    CAS  Google Scholar 

  • El-Zawahry MM, Abdelghaffar F (2013) Preparation and characterisation of novel phospholipid cationic liposomes to improve the alkaline hydrolysis and dyeability of polyester fabric. Color Technol 129:193–202

    CAS  Google Scholar 

  • Francke K-P, Rudolph R, Miessner H (2003) Design and operating characteristics of a simple and reliable DBD reactor for use with atmospheric air. Plasma Chem Plasma Process 23:47–57

    CAS  Google Scholar 

  • Gaminian H, Montazer M (2015) Enhanced self-cleaning properties on polyester fabric under visible light through single-step synthesis of cuprous oxide doped nano-TiO2. Photochem Photobiol 91:1078–1087

    CAS  Google Scholar 

  • Garg S, Hurren C, Kaynak A (2007) Improvement of adhesion of conductive polypyrrole coating on wool and polyester fabrics using atmospheric plasma treatment. Synth Met 157:41–47

    CAS  Google Scholar 

  • Gherardi N, Gouda G, Gat E, Ricard A, Massines F (2000) Transition from glow silent discharge to micro-discharges in nitrogen gas. Plasma Sources Sci Technol 9:340–346

    CAS  Google Scholar 

  • Gorjanc M, Mozetič M, Primc G, Vesel A, Spasić K, Puač N, Petrović ZL, Kert M (2017) Plasma treated polyethylene terephthalate for increased embedment of UV-responsive microcapsules. Appl Surf Sci 419:224–234

    CAS  Google Scholar 

  • Gotoh K, Yasukawa A (2011) Atmospheric pressure plasma modification of polyester fabric for improvement of textile-specific properties. Text Res J 81:368–378

    CAS  Google Scholar 

  • Grčić I, Erjavec B, Vrsaljko D, Guyon C, Tatoulian M (2017) Influence of plasma surface pretreatment and triarylmethane dye on the photocatalytic performance of TiO2-chitosan coating on textile. Prog Org Coat 105:277–285

    Google Scholar 

  • Gupta B, Edwards J (2009) 3-Textile materials and structures for wound care products. In: Advanced textiles for wound care. Elsevier, pp 48–96. https://doi.org/10.1533/9781845696306.1.48

  • Hakeim OA, Abdelghaffar F, Haroun AA (2019) UV-protection of cellulosic fabric prints using hyperbranched polyester-stabilized titania coating. Prog Org Coat 136:105295

    CAS  Google Scholar 

  • Hardick O, Dods S, Stevens B, Bracewell DG (2013) Nanofiber adsorbents for high productivity downstream processing. Biotechnol Bioeng 110:1119–1128

    CAS  Google Scholar 

  • Harifi T, Montazer M (2017) Application of sonochemical technique for sustainable surface modification of polyester fibers resulting in durable nano-sonofinishing. Ultrason Sonochem 37:158–168

    CAS  Google Scholar 

  • He X, Zhou Q, Xie K (2014) Effect of PEGylated chitosan on plasma etched PET fabrics surface properties. J Appl Polym Sci:131:1–8

  • Hossain MM (2009) Plasma technology for deposition and surface modification. (Logos Verlag Berlin GmbH)

  • Kamel M, Abdelghaffar F, El-Zawahry M (2011) Eco-friendly dyeing of wool with a mixture of natural dyes. J Nat Fibers 8:289–307

    CAS  Google Scholar 

  • Khattab TA, Haggag KM, Elnagdi MH, Abdelrahman AA, Abdelmoez AS (2016) Microwave-assisted synthesis of arylazoaminopyrazoles as disperse dyes for textile printing. Z Anorg Allg Chem 642:766–772

    CAS  Google Scholar 

  • Khattab TA, Elnagdi MH, Haggaga KM, Abdelrahmana AA, Abdelmoez AS (2017) Green synthesis, printing performance, and antibacterial activity of disperse dyes incorporating arylazopyrazolopyrimidines. AATCC J Res 4:1–8

    CAS  Google Scholar 

  • Khattab TA, Aly SA, Klapötke TM (2018a) Naked-eye facile colorimetric detection of alkylphenols using Fe (III)-impregnated silica-based strips. Chem Pap 72:1553–1559

    CAS  Google Scholar 

  • Khattab TA, Fouda MM, Allam AA, Othman SI, Bin-Jumah M, Al-Harbi HM, Rehan M (2018b) Selective colorimetric detection of Fe (III) using metallochromic tannin-impregnated silica strips. ChemistrySelect 3:12065–12071

    CAS  Google Scholar 

  • Khattab TA, Dacrory S, Abou-Yousef H, Kamel S (2019a) Development of microporous cellulose-based smart xerogel reversible sensor via freeze drying for naked-eye detection of ammonia gas. Carbohydr Polym 210:196–203

    CAS  Google Scholar 

  • Khattab TA, Dacrory S, Abou-Yousef H, Kamel S (2019b) Smart microfibrillated cellulose as swab sponge-like aerogel for real-time colorimetric naked-eye sweat monitoring. Talanta 205:120166

    CAS  Google Scholar 

  • Khattab TA, Fouda MM, Abdelrahman MS, Othman SI, Bin-Jumah M, Alqaraawi MA, Al Fassam H, Allam AA (2019c) Co-encapsulation of enzyme and tricyanofuran hydrazone into alginate microcapsules incorporated onto cotton fabric as a biosensor for colorimetric recognition of urea. React Funct Polym 142:199–206

    CAS  Google Scholar 

  • Leroux F, Campagne C, Perwuelz A, Gengembre L (2008) Fluorocarbon nano-coating of polyester fabrics by atmospheric air plasma with aerosol. Appl Surf Sci 254:3902–3908

    CAS  Google Scholar 

  • Lv J, Zhou Q, Zhi T, Gao D, Wang C (2016) Environmentally friendly surface modification of polyethylene terephthalate (PET) fabric by low-temperature oxygen plasma and carboxymethyl chitosan. J Clean Prod 118:187–196

    CAS  Google Scholar 

  • Mech J, Grela MA, Szaciłowski K (2014) Ground and excited state properties of alizarin and its isomers. Dyes Pigments 103:202–213

    CAS  Google Scholar 

  • Nersisyan G, Graham W, Technology (2004) Characterization of a dielectric barrier discharge operating in an open reactor with flowing helium. Plasma Sources Sci Technol 13:582–587

    CAS  Google Scholar 

  • Parvinzadeh M, Ebrahimi I (2011) Influence of atmospheric-air plasma on the coating of a nonionic lubricating agent on polyester fiber. Radiat Eff Defects Solids 166:408–416

    CAS  Google Scholar 

  • Roy S, Yue CY (2011) Surface modification of COC microfluidic devices: a comparative study of nitrogen plasma treatment and its advantages over argon and oxygen plasma treatments. Plasma Process Polym 8:432–443

    CAS  Google Scholar 

  • Sadeghi-Kiakhani M (2015) Eco-friendly dyeing of wool and nylon using madder as a natural dye: kinetic and adsorption isotherm studies. Int J Environ Sci Technol 12:2363–2370

    CAS  Google Scholar 

  • Shahid M, Mohammad F (2013) Recent advancements in natural dye applications: a review. J Clean Prod 53:310–331

    CAS  Google Scholar 

  • Vogel AI (1975) Elementary practical organic chemistry, part 3, quantitative organic analysis. Longman Group Ltd, London

    Google Scholar 

  • Wilson D, Rhodes N, Williams R (2003) Surface modification of a segmented polyetherurethane using a low-powered gas plasma and its influence on the activation of the coagulation system. Biomaterials 24:5069–5081

    CAS  Google Scholar 

  • Zaman M, Liu H, Xiao H, Chibante F, Ni Y (2013) Hydrophilic modification of polyester fabric by applying nanocrystalline cellulose containing surface finish. Carbohydr Polym 91:560–567

    CAS  Google Scholar 

  • Zhang C, Zhao M, Wang L, Qu L, Men Y (2017) Surface modification of polyester fabrics by atmospheric-pressure air/He plasma for color strength and adhesion enhancement. Appl Surf Sci 400:304–311

    CAS  Google Scholar 

  • Zille A, Oliveira FR, Souto AP (2015) Plasma treatment in textile industry. Plasma Process Polym 12:98–131

    CAS  Google Scholar 

Download references

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Correspondence to Fatma Abdelghaffar.

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Abdelghaffar, F., Abdelghaffar, R.A., Rashed, U.M. et al. Highly effective surface modification using plasma technologies toward green coloration of polyester fabrics. Environ Sci Pollut Res 27, 28949–28961 (2020). https://doi.org/10.1007/s11356-020-09081-9

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  • DOI: https://doi.org/10.1007/s11356-020-09081-9

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