Abstract
In recent years, bismuth has gained attention of many researchers because of its sorptive properties. Sorptive properties of bismuth compounds are used for removal of ionic contaminants from aqueous solution. In this paper, an attempt is made to review the recent developments in the area of contaminant removal from aqueous solutions using bismuth-based media. List of various bismuth-based adsorbents are collected from published literature and their adsorption capacities are also compared. The methods of characterization of some of the synthesized bismuth-based materials have also been discussed. Hydrous bismuth oxides (HBOs) have sorptive potential for nitrate and fluoride removal from aqueous solution with maximum capacity of 0.508–0.512 mg/g and 0.60–1.93 mg/g respectively. Thus, it can be beneficially used for treatment of drinking water treatment, particularly in small scale household applications.
Similar content being viewed by others
References
Anand PS, Baxi DR (1978a) Preparation and ion exchange properties of basic bismuth nitrate. Indian J Chem Techn 16:198–200
Anand PS, Baxi DR (1978b) Preparation and ion exchange properties of basic bismuth sillicate. Indian J Chem Techn 16:211–212
Anku WW, Oppong SOB, Govender PP (2018) Bismuth - advanced applications and defects characterization: bismuth-based nanoparticles as photocatalytic materials. Chapter 2, InTech Open pp 25-44. https://doi.org/10.5772/intechopen.75104:25-44
Arti and Seema (2012) Synthesis & characterization of bismuth(III) tungstomolybdate as a new cation exchanger, and its analytical applications. Elixir Appl Chem 53:11858–11864
Atwal A, Cousin GCS (2016) Bismuth toxicity in patients treated with bismuth iodoform paraffin packs. BRIT J Oral Max Surg 54:111–112
Bhakti KS (1977) Radiochemistry of bismuth nuclear science series. Academy of science-National research council, Washington, DC
Biswas K, Bandhoyapadhyay D, Ghosh UC (2007) Adsorption kinetics of fluoride on iron(III)-zirconium(IV)hybrid oxide. Adsorption 13:83–94
Biswas K, Gupta K, Ghosh UC (2009) Adsorption of fluoride by hydrous iron(III)–tin(IV) bimetal mixed oxide from the aqueous solutions. Chem Eng J 149:196–206
Briand GG, Burford N (1999) Bismuth compounds and preparations with biological or medicinal relevance. Chem Rev 99:2601–2657
Buamah R, Oduro CA, Sadik MH (2016) Fluoride removal from drinking water using regenerated aluminum oxide coated media. J Environ Chem Eng 4(1):250–258
Cai J, Zhao X, Zhang Y, Zhang Q, Pan B (2018) Enhanced fluoride removal by La-doped Li/Al layered double hydroxides. J Colloid Interface Sci 509:353–359
Cengiz N, Uslu Y, Gok F, Anarat A (2005) Acute renal failure after overdose of colloidal bismuth subcitrate. Pediatr Nephrol 20:1355–1358
CGWB (2014) Concept note on geogenic contamination of ground water in India (2014) Central Ground Water Board, Ministry of Water Resources, Govt of India. http://cgwbgovin/WQ/Geogenic%20Finalpdf. Accessed 20 Oct 2018
Cheng Y, Zhang H (2018) Novel bismuth-based nanomaterials used for cancer diagnosis and therapy. Chem Eur J 24:17405–17418. https://doi.org/10.1002/chem.201801588
Chubar N (2011) New inorganic anion exchangers based on Mg–Al hydrous oxides: (Alkoxide-free) sol–gel synthesis and characterization. J Colloid Interface Sci 357:198–209
Deng M, Wu X, Zhu A, Zhang Q, Liu Q (2019) Well-dispersed TiO2 nanoparticles anchored on Fe3O4 magnetic nanosheets for efficient arsenic removal. J Environ Manag 237:63–74
Devi RR, Umlong IM, Raul PK, Das B, Banerjee S, Singh L (2014) Defluoridation of water using nano-magnesium oxide. J Exp Nanosci 9(5):512–524
Dou X, Mohan D, Pittman CUJ, Yang S (2012) Remediating fluoride from water using hydrous zirconium oxide. Chem Eng J 198–199:236–245
Fristche U (1993) Removal of nitrates and other anions from water by yellow bismuth hydroxide. J Env Sci Health A28 9:1903–1913
García-Sánchez JJ, Solache-Ríos M, Martínez-Miranda V, Morelos CS (2013) Removal of fluoride ions from drinking water and fluoride solutions by aluminum modified iron oxides in a column system. J Colloid Interface Sci 407:410–415
He Y, Lin H, Dong Y, Li B, Wang L, Chu S, Luo M, Liu J (2018) Zeolite supported Fe/Ni bimetallic nanoparticles for simultaneous removal of nitrate and phosphate: synergistic effect and mechanism. Chem Eng Sci 347:669–681
Hollemann AF, Wiberg E (1960) Lehrbuch der Anorganischen Chmie. Berlin ed (47–56 ed) Germany
Howe HE (1968) In Hampel (Ed), The Encyclopedia of the Chemical Elements Reinhold Book Corporation, New York
Inchaurrondo N, di Luca C, Mori F, Pintar A, Zerjav G, Valiente M, Palet C (2019) Synthesis and adsorption behavior of mesoporous alumina and Fe-doped alumina for the removal of dominant arsenic species in contaminated waters. J Environ Chem Eng 7:102901. https://doi.org/10.1016/j.jece.2019.102901
Islam M, Patel RK (2009) Nitrate sorption by thermally activated Mg/Al chloride hydrotalcite-like compound. J Hazard Mater 169:524–531
Islam M, Patel RK (2010) Synthesis and physicochemical characterization of Zn/Al chloride layered double hydroxide and evaluation of its nitrate removal efficiency. Desalination 256:120–128
Islam M, Patel RK (2011) Physicochemical characterization and adsorption behavior of Ca/Al chloride hydrotalcite-like compound towards removal of nitrate. J Hazard Mater 190:659–668
Ito T, Yashida T (1970) Adsorption and elution of chloride ion on bismuth (III) hydroxide. Nippon Kagaku Zasshi 91(11):1054–1058
Jain S, Bansiwal A, Biniwale RB, Milmille S, Das S, Tiwari S, Antony PS (2015) Enhancing adsorption of nitrate using metal impregnated alumina. J Env Chem Eng 3:2342–2349
Jang JH, Dempsey BA (2008) Coadsorption of arsenic(III) and arsenic(V) onto hydrous ferric oxide: effects on abiotic oxidation of arsenic(III), extraction efficiency, and model accuracy. Environ Sci Technol 42:2893–2898
Javaheri F, Hassanajili S (2016) Synthesis of Fe3O4@SiO2@MPS@P4VP nanoparticles for nitrate removal from aqueous solutions. J Appl Polym Sci 44330:1–9
JCPDS (2003) - International Centre for Diffraction Data 12 Campus Boulevard, Newtown Square, PA 19073-3273 USA
Kameda T, Oba J, Yoshioka T (2017) Kinetics and equilibrium studies on Mg-Al oxide for removal of fluoride in aqueous solution and its use in recycling. J Env Mgt 156:252–256
Kang D, Yu X, Tong S, Ge M, Zuo J, Cao C, Song W (2013) Performance and mechanism of Mg/Fe layered double hydroxides for fluoride and arsenate removal from aqueous solution. Chem Eng J 228:731–740
Karthikeyan M, Elango KP (2009) Removal of fluoride from water using aluminium containing compounds. J Environ Sci 21:1513–1518
Kodama H (1993) The removal and solidification of radioactive iodide ions using a new organic anion exchanger. Special Publication. RSC Adv 122:55–62
Krause KA, Nelson F (1956) Oak Ridge report. ORNL 2159:41
Lenoble V, Chabroullet C, Shukry RA, Serpaud B, Deluchat V, Bollinger JC (2004) Dynamic arsenic removal on a MnO2-loaded resin. J Colloid Interface Sci 280(1):62–67
Li H, Sun H (2012) Recent advances in bioinorganic chemistry of bismuth. Curr Opin Chem Biol 16:74–83
Li Z, Deng S, Yu G, Huang J, Lim VC (2010) As(V) and As(III) removal from water by a Ce–Ti oxide adsorbent: behavior and mechanism. Chem Eng J 161:106–113
Liu S, Kang S, Wang H, Wang G, Zhao H, Cai W (2016) Nanosheets-built flowerlike micro/nanostructured Bi2O23.3 and its highly efficient iodine removal performances. Chem Eng J 289:219–230
Liu Y, Zhuang J, Zhang X, Le C, Zhu N, Yang L, Wang Y, Chen T, Wang Y, Zhang LW (2017) Autophagy associated cytotoxicity and cellular uptake mechanisms of bismuth nanoparticles in human kidney cells. Toxicol Lett 275:39–48
Mahdavi S, Molodi P, Zarabi M (2018) Utilization of bare MgO, CeO2, and ZnO nanoparticles for nitrate removal from aqueous solution. Environ Prog Sustain Energy 37(6):1908–1917
Manna B, Ghosh UC (2007) Adsorption of arsenic from aqueous solution on synthetic hydrous stannic oxide. J Hazard Mater 144:522–531
Martinson CA, Reddy KJ (2009) Adsorption of arsenic(III) and arsenic(V) by cupric oxide nanoparticles. J Colloid Interface Sci 336:406–411
Mehrabi N, Soleimani M, Yeganeh MM, Sharififard H (2015) Parameter optimization for nitrate removal from water using activated carbon and composite of activated carbon and Fe2O3 nanoparticles. RSC Adv 5:51470–51482
Mishra SP, Singh VK (1998) Ion oxide exchangers in radioactive waste management part X removal of barium ions from aqueous solutions by hydrous bismuth using radiotracer technique and nuclear and radiochemistry laboratory. Appl Radiat lsot 49(1-2):43–48
Noronha DM, Pius IC, Chaudhury S (2017) Co-precipitation of plutonium(IV) and americium(III) from nitric acid–oxalic acid solutions with bismuth oxalate. J Radioanal Nucl Chem 313:523–529
Parashar K, Ballav N, Debnath S, Pillay K, Maity A (2016) Rapid and efficient removal of fluoride ions from aqueous solution using a polypyrrole coated hydrous tin oxide nanocomposite. J Colloid Interface Sci 476:103–118
Pauling L (1960) The nature of the chemical bond and the structure of molecules and crystals, 3rd edn. Cornell University Press, New York
Pourbaix M (1996) Atlas of electrochemical equilibrium in aqueous solutions. Pergamon press, Oxford
Ranjan M (2011) Effects of cationic ligands on nitrate and fluoride removal from water by bismuth based media. M.Tech. Dissertation, IIT(BHU), India
Ranjan M, Srivastav AL, Shaktibala (2015) Effects of addition of cationic ligands in hydrous bismuth oxide on removal of fluoride from aqueous solutions. Curr Sci 108:9–10
Ren Z, Zhang G, Chen JP (2011) Adsorptive removal of arsenic from water by an iron-zirconium binary oxide adsorbent. J Colloid Interface Sci 358:230–237
Rouhani Z, Karimi-Sabet J, Mehdipourghazi M, Hadi A, Dastbaz A (2019) Response surface optimization of hydrothermal synthesis of bismuth ferrite nanoparticles under supercritical water conditions: application for photocatalytic degradation of Tetracycline. Environ Nanotechnol Monit Manage 11:100198
Sadler PJ (1991) Inorganic chemistry and drug design In sykes AG(Ed). Advance in organic chemistry Academy press. Inc London 36:1–44
Sadler PJ, Li H, Sun H (1999) Coordination chemistry of metals in medicine: target sites for bismuth. Coord Chem Rev 185–186:689–709
Schlesinger M, Weber M, Schulze S, Hietschold M, Mehring M (2013) Metastable β-Bi2O3 nanoparticles with potential for photocatalytic water purification using visible light irradiation. Chemistryopen 2:146–155
Sidwick NV (1950) The chemical elements and their compounds. Vol(I), Oxford at the Clarenden Press UK
Siji S, Janardanan C (2014) Synthesis and characterization of bismuth based novel inorganic ion exchange materials and their analytical applications. IOSR. J App Chemistry (IOSR-JAC) 7(1):77–84
Singh PK (1999) Nitrate removal from water by bismuth based media. Ph.D. Thesis, IIT Kanpur, India
Singh PK, Ghosh DK (2000) Nitrate removal from water by bismuth based media. In: Jana BB, Banerjee RD, Guterstam B, Heeb J (eds) Waste recycling and resource management in the developing world. University of Kalyani, India and International Ecological Engineering Society, Switzerland, pp 456–459
Singh PK, Ghosh DK (2002) Nitrate removal from water by bismuth based media. In Waste Recycling and Resource Management in the Developing World 456-459
Singh TS, Pant KK (2004) Equilibrium, kinetics and thermodynamic studies for adsorption of As(III) on activated alumina. Sep Purif Technol 36:139–147
Singh PK, Srivastav AL, Ghosh DK, Sharma YC (2012) Preparation and properties of hydrous bismuth oxides for nitrate removal from aqueous solutions. Desalin Water Treat 40(1-3):144–152
Singh PK, Banerjee S, Srivastav AL, Sharma YC (2015) Kinetic and equilibrium modeling for removal of nitrate from aqueous solutions and drinking water by a potential adsorbent, hydrous bismuth oxide. RSC Adv 5:35365–35376
Srivastav AL (2013) Development of inorganic adsorptive media for nitrate and fluoride removal from water. Ph.D. Thesis, IIT (BHU), India
Srivastav AL, Singh PK, Weng CH, Sharma YC (2014) Novel adsorbent hydrous bismuth oxide for the removal of nitrate from aqueous solutions. J hazard toxic radioact ASCE 04014028(8)
Srivastav AL, Singh PK, Sharma YC (2015) Synthesis of a novel adsorbent, hydrous bismuth oxide (HBO2) for the removal of fluoride from aqueous solutions. Desalin Water Treat 55:604–614
Srivastav AL, Singh PK, Srivastava V, Sharma YC (2013) Application of a new adsorbent for fluoride removal from aqueous solutions. J Hazard Mater 263:342–352
Srivastava A, Singh PK (2017) Adsorption of nitrate from ground water using Indian bentonite: fixed bed column study. IJERT 6(5):390–394
Stewart CAC (2014) An investigation into the tailoring of bismuth oxide nanoceramic with a biomedical application as a high Z radiation enhancer for cancer therapy, Master of Science (Research) thesis, School of Chemistry, University of Wollongong. http://ro.uow.edu.au/theses/4325
Streat M, Hellgardt K, Newton NLR (2008) Hydrous ferric oxide as an adsorbent in water treatment Part 2. Adsorption studies. Process Saf Environ Prot 86:11–20
Sujana MG, Anand S (2010) Iron and aluminum based mixed hydroxides: a novel sorbent for fluoride removal from aqueous solutions. Appl Surf Sci 256:6956–6962
Sun H, Li H, Sadler PJ (1997) The biological and medicinal chemistry of bismuth. Chem Ber/Recueil 130:669–681
Suzuki TM, Bomani JO, Matsunaga H, Yokoyama T (2000) Preparation of porous resin loaded with crystalline hydrous zirconium oxide and its application to the removal of arsenic. React Funct Polym 43:165–172
Tomar V, Prasad S, Kumar D (2013) Adsorptive removal of fluoride from water samples using Zr–Mn composite material. Microchem J 111:116–124
Udalova TA, Logutenko OA, Timakova EV, Afonina LI, Naydenko ES, Yukhin YM (2008) Bismuth compounds in medicine. New materials and technologies IFOST:137–140
Vesely V, Pekarek V (1972) Synthetic inorganic ion exchangers: hydrous oxides acidic salts of multivalent metals. Talanta 19:219–262
Wang M, Yu X, Yang C, Yang X, Lin M, Guan L, Ge M (2017) Removal of fluoride from aqueous solution by Mg-Al-Zr triple-metal composite. Chem Eng J 322:246–253
Wang J, Wu L, Li J, Tang D, Zhang G (2018) Simultaneous and efficient removal of fluoride and phosphate by Fe-La composite: adsorption kinetics and mechanism. J Alloys Compd 753:422–432
Wen T, Wu X, Tan X, Wang X, Xu A (2013) One-pot synthesis of water-swellable Mg-Al layered double hydroxides and graphene oxide nanocomposites for efficient removal of As(V) from aqueous solutions. ACS Appl Mater Interfaces 5(8):3304–3311
WHO (2002) World Health Organization. Guidelines for Drinking Water Quality. Recommendations. 2nd Ed Geneva
Wilkinson SG (1987) Comprehensive coordination chemistry: the synthesis reactions, properties and applications of coordination compounds, vol 3. Pergamon Press, Oxford, pp 279–298
Yan L, Huang Y, Cui J, Jing C (2015) Simultaneous As(III) and Cd removal from copper smelting wastewater using granular TiO2 columns. Water Res 68:572–579
Zhang Y, Yang M, Dou XM, He H, Wang DS (2005) Arsenate adsorption on an Fe-Ce bimetal oxide adsorbent: role of surface properties. Env Sci Tech 39(18):7246–7253
Zhang M, Gao B, Yao Y, Xue Y, Inyang M (2012) Synthesis of porous MgO biochar nanocomposites for removal of phosphate and nitrate from aqueous solutions. Chem Eng J 210:26–32
Zhang G, Ren Z, Zhang X, Chen J (2013) Nanostructured iron(III)-copper(II) binary oxide: a novel adsorbent for enhanced arsenic removal from aqueous solutions. Water Res 47:4022–4031
Zhang T, Yue X, Gao L, Qiu F, Xu J, Rong J, Pan J (2017) Hierarchically porous bismuth oxide/layered double hydroxide composites: preparation, characterization and iodine adsorption. J Clean Prod 144:220–227
Zhang W, Liu C, Wang L, Zheng T, Ren G, Li J, Ma J, Zhang G, Song H, Zhang Z, Li Z (2018) A novel nanostructured Fe-Ti-Mn composite oxide for highly efficient arsenic removal: preparation and performance evaluation. Colloids Surf A Physicochem Eng Asp 561:364–372. https://doi.org/10.1016/j.colsurfa.2018.10.077
Zhu N, Yan T, Qiao J, Cao H (2016) Adsorption of arsenic, phosphorus and chromium by bismuth impregnated biochar: adsorption mechanism and depleted adsorbent utilization. Chemosphere 164:32–40
Zhu N, Qiao J, Ye Y, Yan T (2018) Synthesis of mesoporous bismuth-impregnated aluminum oxide for arsenic removal: adsorption mechanism study and application to a lab-scale column. J Env Mgt 211:73–82
Acknowledgments
All the necessary facilities for this work have been provided by the Indian Institute of Technology (Banaras Hindu University), India. Thanks are also due to anonymous reviewers for their comments and suggestion.
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible editor: Tito Roberto Cadaval Jr
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Ranjan, M., Singh, P.K. & Srivastav, A.L. A review of bismuth-based sorptive materials for the removal of major contaminants from drinking water. Environ Sci Pollut Res 27, 17492–17504 (2020). https://doi.org/10.1007/s11356-019-05359-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-019-05359-9