Abstract
The use of fuels with strong percentage of ethanol that is done in countries such as Brazil and Australia causes a more and more relevant presence of traces of ethanol in natural waters. The ethanol present in these fuels seems to contribute to increase, through various mechanisms, the concentration of hydrocarbons in the same waters and soil. The ethanol content in natural waters must therefore be monitored frequently. It was therefore proposed a very simple innovative method, based on a catalytic fuel cell with the alcohol dehydrogenase enzyme immobilized in the anodic compartment of the device. The analytical performances of this new device were then evaluated by checking traces of alcohol in different types of natural waters (rain, river, and groundwater), with a good degree of precision and with an acceptable level of accuracy.
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References
Angeloni R, Tomassetti M, Castrucci M, Campanella L (2015) Ethanol determination in alcoholic beverages using two different amperometric enzyme sensors. Curr Anal Chem 11:56–67
Campanella L, Spuri Capesciotti G, Gatta T, Tomassetti M (2010) An innovative organic phase enzyme electrode (OPEE) for the determination of ethanol in leadless petrols. Sensors Actuat B Chem 147(1):78–86
Campanella L, Spuri Capesciotti G, Russo MV, Tomassetti M (2008) Study of the catalytic mechanism of the enzyme catalase on organic hydroperoxides in non-polar organic solvent. Curr Enzym Inhib 4:86–92
Chen CS, Shu YY, Wu SH, Tien CJ (2015) Assessing soil and groundwater contamination from biofuel spills. Environ Sci Process Impacts 17(3):533–542
Corseuil HX, Alvarez PJJ (1996) Natural bioremediation perspective for BTX-contaminated groundwater in Brazil: effects of ethanol. Water Sci Technol 34(7–8):311–318
Kumagai T, Horiba T, Kamo T, Takeuchi S, Iwamoto K, Kitami K, Tamura K (1989) Google Patents, US 4810597 A
Niven RK (2005) Ethanol in gasoline: environmental impacts and sustainability review article. Renew Sust Energ Rev 9(6):535–555
Outreach College of Science University of Canterbury Private Bag 4800 Christchurch New Zealand (2011): Determination of ethanol by redox titration with potassium dichromate. http://www.canterbury.ac.nz/media/documents/science-outreach/ethanol.pdf
Sparks D, Laroche C, Tran N, Goetzinger D, Najafi N, Kawaguchi K, Yasuda M (2005) A new methanol concentration microsensor for improved DMFC performance. Fuel cell summit 2005, Uncasville (Hartford), Connecticut, USA Oct. 23-25, 2005
Sun W, Sun G, Yang W, Yang S, Xin Q (2006) A methanol concentration sensor using twin membrane electrode assemblies operated in pulsed mode for DMFC. J Power Sources 162:1115–1121
Suzuki K, Katayama M, Takamatsu K, Kaneko S, Ishikawa H, Matsuda Y (2011) Development of high performance liquid chromatography with electrochemical detection for alcohols and its application to the determination of ethanol in detergents and alcohol beverage. Bunseki Kagaku 60(9):761–764
Tomassetti M, Angeloni R, Merola G, Castrucci M, Campanella L (2016a) Catalytic fuel cell used as an analytical tool for methanol and ethanol determination. Application to ethanol determination in alcoholic beverages. Electrochim Acta 191:1001–1009
Tomassetti M, Merola G, Angeloni R, Marchiandi S, Campanella L (2016b) Further development on DMFC device used for analytical purpose: real applications in the pharmaceutical field and possible in biological fluids. Anal Bioanal Chem 408:7311–7319
Tomassetti M, Spuri Capesciotti G, Angeloni R, Martini E, Campanella L (2016c) Bioethanol in biofuels checked by an amperometric organic phase enzyme electrode (OPEE) working in “substrate antagonism” format. Sensors 16(9):1355–1365
Wang ML, Choong YM, Su NW, Lee MH (2003) A rapid method for determination of ethanol in alcoholic beverages using capillary gas chromatography. J Food Drug Anal 11(2):133–140
Zhang Y, Khan IA, Chen X, Spalding RF (2006) Transport and degradation of ethanol in groundwater. J Contam Hydrol 82:183–194
Zhao H, Shen J, Zhang J, Wang H, Wilkinson DP, Gu CE (2006) Liquid methanol concentration sensors for direct methanol fuel cell. J Power Sources 159:626–636
Funding
This work was funded by the University of Rome “La Sapienza”, Center “Protezione dell’Ambiente e dei Beni Culturali (CIABC)” and “Istituto per lo Studio dei Materiali Nanostrutturati (ISMN)” of CNR.
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Responsible editor: Philippe Garrigues
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Tomassetti, M., Angeloni, R., Castrucci, M. et al. Ethanol traces in natural waters checked using a new DMFC enzymatic device. Environ Sci Pollut Res 25, 28741–28747 (2018). https://doi.org/10.1007/s11356-017-0435-y
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DOI: https://doi.org/10.1007/s11356-017-0435-y