Skip to main content
Log in

Sono assisted electrocoagulation process for the removal of pollutant from pulp and paper industry effluent

  • Water Reclamation and Reuse
  • Published:
Environmental Science and Pollution Research Aims and scope Submit manuscript

Abstract

In the present work, the efficiency of the sonication, electrocoagulation, and sono-electrocoagulation process for removal of pollutants from the industrial effluent of the pulp and paper industry was compared. The experimental results showed that the sono-electrocoagulation process yielded higher pollutant removal percentage compared to the sonication and electrocoagulation process alone. The effect of the operating parameters in the sono-electrocoagulation process such as electrolyte concentration (1–5 g/L), current density (1–5 A/dm2), effluent pH (3–11), COD concentration (1500–6000 mg/L), inter-electrode distance (1–3 cm), and electrode combination (Fe and Al) on the color removal, COD removal, and power consumption were studied. The maximum color and COD removal percentages of 100 and 95 %, respectively, were obtained at the current density of 4 A/dm2, electrolyte concentration of 4 g/L, effluent pH of 7, COD concentration of 3000 mg/L, electrode combination of Fe/Fe, inter-electrode distance of 1 cm, and reaction time of 4 h, respectively. The color and COD removal percentages were analyzed by using an UV/Vis spectrophotometer and closed reflux method. The results showed that the sono-electrocoagulation process could be used as an efficient and environmental friendly technique for complete pollutant removal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  • Al Aji B, Yavuz Y, SavasKoparal A (2012) Electrocoagulation of heavy metals containing model wastewater using monopolar iron electrodes. Sep Purif Technol 86:248–254

    Article  CAS  Google Scholar 

  • APHA, AWWA, WEF (1995) Standard methods for the examination of water and wastewater, 19th ed. APHA, Washington, USA

  • Ashrafi O, Yerushalmi L, Haghighat F (2015) Wastewater treatment in the pulp-and-paper industry: a review of treatment processes and the associated greenhouse gas emission. J Environ Manag 158:146–157

    Article  CAS  Google Scholar 

  • Babuponnusami A, Muthukumar K (2012) Advanced oxidation of phenol: a comparison between Fenton, electro-Fenton, sono-electro-Fenton and photo-electro-Fenton processes. Chem Eng J 183:1–9

    Article  CAS  Google Scholar 

  • Barrera-Díaz Carlos E, Roa-Morales G, Balderas Hernández P, Fernandez-Marchante CM, Rodrigo MA (2014) Enhanced electrocoagulation: new approaches to improve the electrochemical process. J Electrochem Sci Eng 4(4):285–296

    Google Scholar 

  • Bayar S, Yilmaz AE, Boncukcuoğlu R, Fìl BA, Kocakerìm MM (2013) Effects of operational parameters on cadmium removal and energy consumption by electrochemical coagulation methods. Desalin Water Treat 51(13-15):2635–2643

    Article  CAS  Google Scholar 

  • Bayar S, Boncukcuoğlu R, Yilmaza AE, Fil BA (2014) Pre-treatment of pistachio processing industry wastewaters (PPIW) by electrocoagulation using Al plate electrode. Sep Sci Technol 49(7):1008–1018

    Article  CAS  Google Scholar 

  • Bayramoglu M, Kobya M, Eyvazb M, Senturk E (2006) Technical and economic analysis of electrocoagulation for the treatment of poultry slaughterhouse wastewater. Sep Purif Technol 51:404–408

    Article  CAS  Google Scholar 

  • Bengtsson S, Werker A, Christensson M, Welander T (2008) Production of polyhydroxyalkanoates by activated sludge treating a paper mill wastewater. Bioresour Technol 99:509–516

    Article  CAS  Google Scholar 

  • Bernal-Martíneza LA, Barrera-Díaza C, Solís-Morelosb C, Natividada R (2010) Synergy of electrochemical and ozonation processes in industrial wastewater treatment. Chem Eng J 165:71–77

    Article  Google Scholar 

  • Boroski M, Rodrigues A, Carla Garcia J, Carlos Sampaio L, Nozaki J, Hioka N (2009) Combined electrocoagulation and TiO2 photoassisted treatment applied to wastewater effluents from pharmaceutical and cosmetic industries. J Hazard Mater 162:448–454

    Article  CAS  Google Scholar 

  • Can BZ, Boncukcuoglu R, Yilmaz AE, Fil BA (2012) Effect of some operational parameters on the arsenic removal by electrocoagulation using aluminum electrodes. Energy Educ Sci Technol Part A: Energy Sci Res 30(SI-2):611–622

    Google Scholar 

  • Can BZ, Boncukcuoglu R, Yilmaz AE, Fil BA (2014) Effect of some operational parameters on the arsenic removal by electrocoagulation using iron electrodes. J Environ Health Sci Eng 12(95):1–10

    Google Scholar 

  • Chakma S, Moholkar VS (2014) Investigations in synergism of hybrid advanced oxidation processes with combinations of sonolysis + Fenton process + UV for degradation of bisphenol A. Ind Eng Chem Res 53:6855–6865

    Article  CAS  Google Scholar 

  • Chakmaa S, Moholkar VS (2015) Intensification of wastewater treatment using sono-hybrid processes: an overview of mechanistic synergism. Indian Chem Eng 57(3-4):1–23

    Google Scholar 

  • Choua WL, Wang CT, Huang K-Y (2009) Effect of operating parameters on indium (III) ion removal by iron electrocoagulation and evaluation of specific energy consumption. J Hazard Mater 167:467–474

    Article  Google Scholar 

  • Chu JY, Li YR, Li N, Huang WH (2012) Treatment of car-washing wastewater by electrocoagulation-ultrasound technique for reuse. Adv Mater Res 433:227–232

    Article  Google Scholar 

  • Comas CM, McKinley D (2008) Reduction of phosphorus and other pollutants from industrial dischargers using pollution prevention. J Clean Prod 16:727–733

    Article  Google Scholar 

  • Dalvand A, Gholami M, Joneidi A, Mohammad Mahmoodi N (2011) Dye removal, energy consumption and operating cost of electrocoagulation of textile wastewater as a clean process. Clean Soil Air Water 39(7):665–672

    Article  CAS  Google Scholar 

  • Daneshvar N, Khataee AR, Amani Ghadim AR, Rasoulifard MH (2007) Decolorization of C.I. acid yellow 23 solution by electrocoagulation process: investigation of operational parameters and evaluation of specific electrical energy consumption (SEEC). J Hazard Mater 148:566–572

    Article  CAS  Google Scholar 

  • Earnhart (2013) Water pollution from industrial sources. Reference module in earth systems and environmental sciences 3: 114–120

  • Farhadi S, Aminzadeh B, Torabian A, Khatibikamal V, AlizadehFard M (2012) Comparison of COD removal from pharmaceutical wastewater by electrocoagulation, photoelectrocoagulation, peroxi-electrocoagulation and peroxi-photo electrocoagulation processes. J Hazard Mater 219-220:35–42

    Article  CAS  Google Scholar 

  • Farooq R, Wang Y, Lin F, Shaukat SF, Donaldson J, Chouhdary AJ (2002) Effect of ultrasound on the removal of copper from the model solutions for copper electrolysis process. Water Res 36:3165–3169

    Article  CAS  Google Scholar 

  • Fil BA, Boncukcuoğlu R, Yilmaz AE, Bayar S (2014) Electro-oxidation of Pistachio Processing Industry Wastewaters (PPIW) using graphite anode. Clean Air Soil Water 42(9):1232–1238

    Article  CAS  Google Scholar 

  • García-García P, López-López A, María Moreno-Baquero J, Garrido-Fernández A (2011) Treatment of wastewaters from the green table olive packaging industry using electro-coagulation. Chem Eng J 170:59–66

    Article  Google Scholar 

  • Gengec E, Kobya M, Demirbas E, Akyol A, Oktor K (2012) Optimization of baker’s yeast wastewater using response surface methodology by electrocoagulation. Desalination 286:200–209

    Article  CAS  Google Scholar 

  • Gogate PR (2011) Cavitational reactors for process intensification of chemical processing applications: a critical review. Chem Eng Process Process Intensif 47(4):515–527

    Article  Google Scholar 

  • Houshyar Z, Baradar Khoshfetrat A, Fatehifar E (2012) Influence of ozonation process on characteristics of pre-alkalized tannery effluents. Chem Eng J 191:59–65

    Article  CAS  Google Scholar 

  • Idris SM, Jones PL, Salzman SA, Croatto G, Allinson G (2012) Evaluation of the giant reed (Arundo donax) in horizontal subsurface flow wetlands for the treatment of dairy processing factory wastewater. Environ Sci Pollut Res 19(8):3525–3537

    Article  CAS  Google Scholar 

  • Kathiravan MN, Muthukumar K (2011) Ultrasound mediated reduction of Cr(VI) using sludge obtained during electrocoagulation. Environ Technol 32:1523–1531

    Article  CAS  Google Scholar 

  • Kobya M, Hiz H, Senturk E, Aydiner C, Demirbas E (2006) Treatment of potato chips manufacturing wastewater by electrocoagulation. Desalination 190:201–211

    Article  CAS  Google Scholar 

  • Koparal AS, Ogutveren UB (2002) Removal of nitrate from water by electroreduction and electrocoagulation. J Hazard Mater B 89:83–94

    Article  CAS  Google Scholar 

  • Kovatcheva VK, Parlapanski MD (1999) Sono-electrocoagulation of iron hydroxides. Colloids Surf A 149:603–608

    Article  CAS  Google Scholar 

  • Kul S, Boncukcuoğlu R, Yilmaz AE, Fil BA (2015) Treatment of olive mill wastewater with electro-oxidation method. J Electrochem Soc 162(8):G41–G47

    Article  CAS  Google Scholar 

  • Lucas MS, Peres JA, Yan Lan B, Li Puma G (2009) Ozonation kinetics of winery wastewater in a pilot-scale bubble column reactor. Water Res 43:1523–1532

    Article  CAS  Google Scholar 

  • Maha Lakshmi P, Sivashanmugam P (2013) Treatment of oil tanning effluent by electrocoagulation: influence of ultrasound and hybrid electrode on COD removal. Sep Purif Technol 116:378–384

    Article  CAS  Google Scholar 

  • Maljaei A, Arami M, Mahmoodi NM (2009) Decolorization and aromatic ring degradation of colored textile wastewater using indirect electrochemical oxidation method. Desalination 249:1074–1078

    Article  CAS  Google Scholar 

  • Nadarajan Kathiravan M, Muthukumar K (2011) Ultrasound mediated reduction of Cr(VI) using sludge obtained during electrocoagulation. Environ Technol 32:1523–1531

    Article  Google Scholar 

  • Natarajan TS, Natarajan K, Bajaj HC, Tayade RJ (2013) Study on identification of leather industry wastewater constituents and its photocatalytic treatment. Int J Environ Sci Technol 10(4):855–864

    Article  CAS  Google Scholar 

  • Ngamlerdpokin K, Kumjadpai S, Chatanon P, Tungmanee U, Chuenchuanchom S, Jaruwat P, Lertsathitphongs P, Hunsom M (2011) Remediation of biodiesel wastewater by chemical- and electro-coagulation: a comparative study. J Environ Manag 92:2454–2460

    Article  CAS  Google Scholar 

  • Olajire AA (2012) The brewing industry and environmental challenges. J Clean Prod 03:30–36

    Google Scholar 

  • Pablo Pocostales J, Alvarez P, Beltran FJ (2012) Kinetic modeling of granular activated carbon promoted ozonation of a food-processing secondary effluent. Chem Eng J 183:395–401

    Article  Google Scholar 

  • Pokhrel D, Viraraghavan T (2004) Treatment of pulp and paper mill wastewater—a review. Sci Total Environ 333:37–58

    Article  CAS  Google Scholar 

  • Rajkumar K, Muthukumar M, Sivakumar R (2010) Novel approach for the treatment and recycle of wastewater from soya edible oil refinery industry—an economic perspective. Resour Conserv Recycl 54:752–758

    Article  Google Scholar 

  • Raschitor A, Fernandez CM, Cretescu I, Rodrigo MA, Cañizares P (2014) Sono-electrocoagulation of wastewater polluted with Rhodamine 6G. Sep Purif Technol 135:110–116

    Article  CAS  Google Scholar 

  • Saravanan M, Pabmanavhan N, Sambhamurthy Sivarajan M (2010) Treatment of acid blue 113 dye solution using iron electrocoagulation. Clean Soil Air Water 38(5–6):565–571

    Article  CAS  Google Scholar 

  • Sebastian Secula M, Creţescu I, Petrescu S (2011) An experimental study of indigo carmine removal from aqueous solution by electrocoagulation. Desalination 277:227–235

    Article  Google Scholar 

  • Segura Y, Molina R, Martínez F, Melero JA (2009) Integrated heterogeneous sono-photo Fenton processes for the degradation of phenolic aqueous solutions. Ultrason Sonochem 16:417–424

    Article  CAS  Google Scholar 

  • Singh J, Ali A, Jaswal VS, Prakash V (2015) Desalination of Cd2+ and Pb2+ from paint industrial wastewater by Aspergillus niger decomposed Citrus limetta peel powder. Int J Environ Sci Technol 12(8):2523–2532

    Article  CAS  Google Scholar 

  • Song S, He Z, Qiu J, Xu L, Chen J (2007) Ozone assisted electrocoagulation for decolorization of C.I. reactive black 5 in aqueous solution: an investigation of the effect of operational parameters. Sep Purif Technol 55:238–245

    Article  CAS  Google Scholar 

  • Sridhar R, Sivakumar V, Prince Immanuel V, Prakash Maran J (2011) Treatment of pulp and paper industry bleaching effluent by electrocoagulant process. J Hazard Mater 186:1495–1502

    Article  CAS  Google Scholar 

  • Srivastava SK, Gupta VK, Mohan D (1996) Kinetic parameters for the removal of lead and chromium from wastewater using activated carbon developed from fertilizer waste material. Environ Model Assess 1(4):281–290

    Article  Google Scholar 

  • The World Bank Group Pollution Prevention and Abatement Handbook (1999). 1998: toward cleaner, the international bank for reconstruction and development. Washington D.C., United States

  • Vahid B, Khataee A (2013) Photoassisted electrochemical recirculation system with boron-doped diamond anode and carbon nanotubes containing cathode for degradation of a model azo dye. Electrochim Acta 88:614–620

    Article  CAS  Google Scholar 

  • Wang C-T, Chou W-L, Kuo Y-M (2009) Removal of COD from laundry wastewater by electrocoagulation/electroflotation. J Hazard Mater 164:81–86

    Article  CAS  Google Scholar 

  • Wu Y, Zhou S, Zheng K, Ye X, Qin F (2011) Mathematical model analysis of Fenton oxidation of landfill leachate. Waste Manag 31:468–474

    Article  CAS  Google Scholar 

  • Yilmaz AE, Bayar S, Boncukuoglu R, Fi BA, Kocakerim MM (2012) Removal of cadmium by electrocoagulation and a cost evaluation. Ekoloji 21(85):26–33

    Article  CAS  Google Scholar 

  • Zheng Y-M, Yunus RV, Nadeeshani Nanayakkara KG, Paul Chen J (2012) Electrochemical decoloration of synthetic wastewater containing rhodamine 6G: behaviors and mechanism. Ind Eng Chem Res 51:5953–5960

    Article  CAS  Google Scholar 

  • Zhou L, Li H, Zhang Y, Wang Y, Han S, Xu H (2012) Abundance and diversity of Sphingomonas in Shenfu petroleum-wastewater irrigation zone, China. Environ Sci Pollut Res 19(1):282–294

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are grateful to the University of Malaya High Impact Research Grant (HIR-MOHE-D000037-16001) from the Ministry of Higher Education Malaysia which financially supported this work.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to P. Asaithambi or Abdul Raman Abdul Aziz.

Additional information

Responsible editor: Bingcai Pan

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Asaithambi, P., Aziz, A.R.A., Sajjadi, B. et al. Sono assisted electrocoagulation process for the removal of pollutant from pulp and paper industry effluent. Environ Sci Pollut Res 24, 5168–5178 (2017). https://doi.org/10.1007/s11356-016-6909-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11356-016-6909-5

Keywords

Navigation