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Development of magnetic graphene oxide adsorbent for the removal and preconcentration of As(III) and As(V) species from environmental water samples

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Abstract

New-generation adsorbent, Fe3O4@SiO2/GO, was developed by modification of graphene oxide (GO) with silica-coated (SiO2) magnetic nanoparticles (Fe3O4). The synthesized adsorbent was characterized using Fourier transform infrared spectroscopy, X-ray diffractometry, energy-dispersive X-ray spectroscopy, and field emission scanning electron microscopy. The developed adsorbent was used for the removal and simultaneous preconcentration of As(III) and As(V) from environmental waters prior to ICP-MS analysis. Fe3O4@SiO2/GO provided high adsorption capacities, i.e., 7.51 and 11.46 mg g−1 for As(III) and As(V), respectively, at pH 4.0. Adsorption isotherm, kinetic, and thermodynamic were investigated for As(III) and As(V) adsorption. Preconcentration of As(III) and As(V) were studied using magnetic solid-phase extraction (MSPE) method at pH 9.0 as the adsorbent showed selective adsorption for As(III) only in pH range 7–10. MSPE using Fe3O4@SiO2/GO was developed with good linearities (0.05–2.0 ng mL−1) and high coefficient of determination (R 2 = 0.9992 and 0.9985) for As(III) and As(V), respectively. The limits of detection (LODs) (3× SD/m, n = 3) obtained were 7.9 pg mL−1 for As(III) and 28.0 pg mL−1 for As(V). The LOD obtained is 357–1265× lower than the WHO maximum permissible limit of 10.0 ng mL−1. The developed MSPE method showed good relative recoveries (72.55–109.71 %) and good RSDs (0.1–4.3 %, n = 3) for spring water, lake, river, and tap water samples. The new-generation adsorbent can be used for the removal and simultaneous preconcentration of As(III) and As(V) from water samples successfully. The adsorbent removal for As(III) is better than As(V).

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Acknowledgments

The authors gratefully acknowledge the Ministry of Education (MOE) Malaysia for financial support through the Research Grants No. 10J43 and 04H22. H. R. Nodeh would like to thank UTM for the International Doctoral Fellowship (IDF) received.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM, Johor Bahru, Johor, Malaysia

    Hamid Rashidi Nodeh, Wan Aini Wan Ibrahim & Mohd Marsin Sanagi

  2. Separation Science and Technology Group, Frontier Materials Research Alliance, Universiti Teknologi Malaysia, 81310 UTM, Johor Bahru, Johor, Malaysia

    Wan Aini Wan Ibrahim

  3. Department of Chemistry, Jamia Millia Islamia (Central University), New Delhi, 110025, India

    Imran Ali

  4. Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310 UTM, Johor Bahru, Johor, Malaysia

    Mohd Marsin Sanagi

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Rashidi Nodeh, H., Wan Ibrahim, W.A., Ali, I. et al. Development of magnetic graphene oxide adsorbent for the removal and preconcentration of As(III) and As(V) species from environmental water samples. Environ Sci Pollut Res 23, 9759–9773 (2016). https://doi.org/10.1007/s11356-016-6137-z

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