Abstract
Layered double hydroxide (LDH) is of great interest for stabilizing toxic anions in the environment because its unique structure exposes numerous functional groups and high surface area and shows efficient ion-exchange capacity. However, little is known about the fundamental of the fluoride@LDH stabilization process to amend the contaminated soil, especially the underlying connection between stabilization efficiency and materials structure, which has never been addressed. Herein, Mg–Al LDH and its modified products, calcined LDH (C–LDH), sodium dodecylbenzenesulfonate intercalated LDH (SDBS–LDH), and diethylenetriaminepentaacetic acid intercalated LDH (DTPA–LDH), were synthesized by different methods and applied to the fluoride stabilization for polluted soil. The maximum stabilization capacity of C–LDH, SDBS–LDH, and DTPA–LDH was 713.33, 753.33, and 855.00 mg·g−1, respectively. Various characterization and analysis methods were utilized to elucidate the stabilization mechanism. Based on the kinetic and isotherm analyses, chemisorption dominated the stabilization process and mainly occurred in a monolayer on the well-distributed active sites of materials. For the two intercalation products, anion-exchangeable interlayer sites and surface functional groups contributed the most capacity for fluoride adsorption leading to an excellent performance. But for the C–LDH, the memory effect was predominant, resulting in fluoride intercalation in the reconstruction process of the brucite-like structure. Overall, the obtained results have a positive significance in revealing the role of LDH in the treatment of soil fluoride pollution.
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The data used in this study can be provided by the corresponding author on reasonable request.
References
Bhatnagar, A., Kumar, E., & Sillanpaa, M. (2011). Fluoride removal from water by adsorption-A review. Chemical Engineering Journal, 171(3), 811–840. https://doi.org/10.1016/j.cej.2011.05.028
Borgnino, L., Garcia, M. G., Bia, G., Stupar, Y. V., Le Coustumer, P., & Depetris, P. J. (2013). Mechanisms of fluoride release in sediments of Argentina’s central region. Science of the Total Environment, 443, 245–255. https://doi.org/10.1016/j.scitotenv.2012.10.093
Cai, J., Zhang, Y., Pan, B., Zhang, W., Lv, L., & Zhang, Q. (2016). Efficient defluoridation of water using reusable nanocrystalline layered double hydroxides impregnated polystyrene anion exchanger. Water Research, 102, 109–116. https://doi.org/10.1016/j.watres.2016.06.030
Cai, P., Zheng, H., Wang, C., Ma, H., Hu, J., Pu, Y., & Liang, P. (2012). Competitive adsorption characteristics of fluoride and phosphate on calcined Mg-Al-CO3 layered double hydroxides. Journal of Hazardous Materials, 213–214, 100–108. https://doi.org/10.1016/j.jhazmat.2012.01.069
Cavani, F., Trifiro, F., & Vaccari, A. (1991). Hydrotalcite-type anionic clays: Preparation, properties and applications. Catalysis Today, 11(2), 173–301. https://doi.org/10.1016/0920-5861(91)80068-K
Clearfield, A., Kieke, M., Kwan, J., Colon, J. L., & Wang, R. C. (1991). Intercalation of dodecyl-sulfate into layered double hydroxides. Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 11(4), 361–378. https://doi.org/10.1007/Bf01041414
Cronin, S. J., Neall, V. E., Lecointre, J. A., Hedley, M. J., & Loganathan, P. (2003). Environmental hazards of fluoride in volcanic ash: A case study from Ruapehu volcano, New Zealand. Journal of Volcanology and Geothermal Research, 121(3–4), 271–291. https://doi.org/10.1016/S0377-0273(02)00465-1
Cui, S. F., Fu, Y. Z., Zhou, B. Q., Li, J. X., He, W. Y., Yu, Y. Q., & Yang, J. Y. (2021). Transfer characteristic of fluorine from atmospheric dry deposition, fertilizers, pesticides, and phosphogypsum into soil. Chemosphere, 278, 130432. https://doi.org/10.1016/j.chemosphere.2021.130432
Cui, S. F., & Yang, J. Y. (2021). Effects of fluorine on the growth of broad bean (Vicia faba L.) and maize (Zea mays L.) and the response of microbial community in soils. Water Air and Soil Pollution, 232(1), 27. https://doi.org/10.1007/s11270-021-04983-x
Das, J., Sairam Patra, B., Baliarsingh, N., & Parida, K. M. (2007). Calcined Mg-Fe-CO(3) LDH as an adsorbent for the removal of selenite. Journal of Colloid and Interface Science, 316(2), 216–223. https://doi.org/10.1016/j.jcis.2007.07.082
Das, O., Bhattacharyya, D., & Sarmah, A. K. (2016). Sustainable eco–composites obtained from waste derived biochar: a consideration in performance properties, production costs, and environmental impact. Journal of Cleaner Production, 129, 159-168. https://doi.org/10.1016/j.jclepro.2016.04.088
Dhillon, A., Prasad, S., & Kumar, D. (2017). Recent advances and spectroscopic perspectives in fluoride removal. Applied Spectroscopy Reviews, 52(3), 175–230. https://doi.org/10.1080/05704928.2016.1213737
Dong, Y. B., Lin, H., Zhao, Y. M., & Menzembere, E. R. G. Y. (2021). Remediation of vanadium-contaminated soils by the combination of natural clay mineral and humic acid. Journal of Cleaner Production, 279, 123874. https://doi.org/10.1016/j.jclepro.2020.123874
Du, Y. J., Wei, M. L., Reddy, K. R., Jin, F., Wu, H. L., & Liu, Z. B. (2014). New phosphate-based binder for stabilization of soils contaminated with heavy metals: Leaching, strength and microstructure characterization. Journal of Environmental Management, 146, 179–188. https://doi.org/10.1016/j.jenvman.2014.07.035
Elhalil, A., Qourzal, S., Mahjoubi, F. Z., Elmoubarki, R., Farnane, M., Tounsadi, H., & Barka, N. (2016). Defluoridation of groundwater by calcined Mg/Al layered double hydroxide. Emerging Contaminants, 2(1), 42–48. https://doi.org/10.1016/j.emcon.2016.03.002
Eshaq, G., Rabie, A. M., Bakr, A. A., Mady, A. H., & ElMetwally, A. E. (2016). Cr(VI) adsorption from aqueous solutions onto Mg-Zn-Al LDH and its corresponding oxide. Desalination and Water Treatment, 57(43), 20377–20387. https://doi.org/10.1080/19443994.2015.1110840
Extremera, R., Pavlovic, I., Perez, M. R., & Barriga, C. (2012). Removal of acid orange 10 by calcined Mg/Al layered double hydroxides from water and recovery of the adsorbed dye. Chemical Engineering Journal, 213, 392–400. https://doi.org/10.1016/j.cej.2012.10.042
Fewtrell, L., Smith, S., Kay, D., & Bartram, J. (2006). An attempt to estimate the global burden of disease due to fluoride in drinking water. Journal of Water and Health, 4(4), 533–542. https://www.ncbi.nlm.nih.gov/pubmed/17176823. Accessed 01 Dec 2006
Fu, Y. H., Wang, F., Sheng, H. J., Xu, M., Liang, Y., Bian, Y. R., & Tiedje, J. M. (2020). Enhanced antibacterial activity of magnetic biochar conjugated quaternary phosphonium salt. Carbon, 163, 360–369. https://doi.org/10.1016/j.carbon.2020.03.010
Fu, Y., Wang, F., Sheng, H., Hu, F., Wang, Z., Xu, M., . . . Tiedje, J. M. (2021). Removal of extracellular antibiotic resistance genes using magnetic biochar/quaternary phosphonium salt in aquatic environments: A mechanistic study. Journal of Hazardous Materials, 411, 125048. https://doi.org/10.1016/j.jhazmat.2021.125048
Goswamee, R. L., Sengupta, P., Bhattacharyya, K. G., & Dutta, D. K. (1998). Adsorption of Cr(VI) in layered double hydroxides. Applied Clay Science, 13(1), 21–34. https://doi.org/10.1016/S0169-1317(98)00010-6
Halajnia, A., Oustan, S., Najafi, N., Khataee, A. R., & Lakzian, A. (2012). The adsorption characteristics of nitrate on Mg-Fe and Mg-Al layered double hydroxides in a simulated soil solution. Applied Clay Science, 70, 28–36. https://doi.org/10.1016/j.clay.2012.09.007
Han, D., Wu, X. Y., Li, R., Tang, X. Q., Xiao, S. B., & Scholz, M. (2021). Critical review of electro-kinetic remediation of contaminated soils and sediments: Mechanisms, performances and technologies. Water Air and Soil Pollution, 232(8), 335. https://doi.org/10.1007/s11270-021-05182-4
Hatami, H., Fotovat, A., & Halajnia, A. (2018). Comparison of adsorption and desorption of phosphate on synthesized Zn-Al LDH by two methods in a simulated soil solution. Applied Clay Science, 152, 333–341. https://doi.org/10.1016/j.clay.2017.11.032
Huang, H. H., Xia, C. F., Liang, D. R., Xie, Y., Kong, F. P., Fu, J. X., & Meng, Z. L. (2022). Removal and magnetic recovery of heavy metals and pesticides from soil by layered double hydroxides modified biotite. Chemical Engineering Journal, 431, 134113. https://doi.org/10.1016/j.cej.2021.134113
Huang, M., Zhang, Y., Xiang, W., Zhou, T., Wu, X., & Mao, J. (2019). Efficient adsorption of Mn(II) by layered double hydroxides intercalated with diethylenetriaminepentaacetic acid and the mechanistic study. Journal of Environmental Sciences (china), 85, 56–65. https://doi.org/10.1016/j.jes.2019.04.011
Huang, P. P., Cao, C. Y., Wei, F., Sun, Y. B., & Song, W. G. (2015). MgAl layered double hydroxides with chloride and carbonate ions as interlayer anions for removal of arsenic and fluoride ions in water. Rsc Advances, 5(14), 10412–10417. https://doi.org/10.1039/c4ra15160g
Iriel, A., Bruneel, S. P., Schenone, N., & Cirelli, A. F. (2018). The removal of fluoride from aqueous solution by a lateritic soil adsorption: Kinetic and equilibrium studies. Ecotoxicology and Environmental Safety, 149, 166–172. https://doi.org/10.1016/j.ecoenv.2017.11.016
Jacks, G., Bhattacharya, P., Chaudhary, V., & Singh, K. P. (2005). Controls on the genesis of some high-fluoride groundwaters in India. Applied Geochemistry, 20(2), 221–228. https://doi.org/10.1016/j.apgeochem.2004.07.002
Jayanthi, G., & Akshaya, V. (2022). Preliminary assessment of defluoridation of groundwater in Tamil Nadu, India, by Strychnos potatorum seeds. Water Air and Soil Pollution, 233(4), 130. https://doi.org/10.1007/s11270-022-05535-7
Jia, Y. H., & Liu, Z. H. (2019). Preparation of borate anions intercalated MgAl-LDHs microsphere and its calcinated product with superior adsorption performance for Congo red. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 575, 373–381. https://doi.org/10.1016/j.colsurfa.2019.05.032
Jiang, X., Ni, C., Zhu, B., Zhao, X., Chen, S., Lv, W., & Zhu, Y. (2016). Determination of fluoride in soil water extract by ion chromatography with column-switching technique. Chinese Journal of Chromatography, 34(4), 442–446. https://doi.org/10.3724/sp.J.1123.2015.12025
Jiang, X. Q., Yan, B. G., Chen, J. Y., Li, W. Y., Hu, J. W., & Guan, Y. T. (2019). Transport and retention of phosphorus in soil with addition of Mg-Al layered double hydroxides: Effects of material dosage, flow velocity and pH. Chemical Engineering Journal, 378, 122154. https://doi.org/10.1016/j.cej.2019.122154
Jiang, X. Q., Zhou, D., Yan, B. G., Li, W. Y., & Guan, Y. T. (2021). Experimental and numerical investigations of phosphorus release under carbonate and variable flow in soil with Mg-Al layered double hydroxides. Chemical Engineering Journal, 406, 126735. https://doi.org/10.1016/j.cej.2020.126735
Kameda, T., Oba, J., & Yoshioka, T. (2015). Recyclable Mg-Al layered double hydroxides for fluoride removal: Kinetic and equilibrium studies. Journal of Hazardous Materials, 300, 475–482. https://doi.org/10.1016/j.jhazmat.2015.07.023
Kameda, T., Takeuchi, H., & Yoshioka, T. (2008). Uptake of heavy metal ions from aqueous solution using Mg-Al layered double hydroxides intercalated with citrate, malate, and tartrate. Separation and Purification Technology, 62(2), 330–336. https://doi.org/10.1016/j.seppur.2008.02.001
Kimambo, V., Bhattacharya, P., Mtalo, F., Mtamba, J., & Ahmad, A. (2019). Fluoride occurrence in groundwater systems at global scale and status of defluoridation – State of the art. Groundwater for Sustainable Development, 9, 100223. https://doi.org/10.1016/j.gsd.2019.100223
Lazaridis, N. K., & Asouhidou, D. D. (2003). Kinetics of sorptive removal of chromium(VI) from aqueous solutions by calcined Mg-Al-CO3 hydrotalcite. Water Research, 37(12), 2875–2882. https://doi.org/10.1016/S0043-1354(03)00119-2
Li, B., Zhang, Y. X., Zhou, X. B., Liu, Z. L., Liu, Q. Z., & Li, X. H. (2016). Different dye removal mechanisms between monodispersed and uniform hexagonal thin plate-like MgAl-CO32–LDH and its calcined product in efficient removal of Congo red from water. Journal of Alloys and Compounds, 673, 265–271. https://doi.org/10.1016/j.jallcom.2016.02.248
Li, C., Zeng, G. D., Zhou, M., Fang, Y., Chen, Z. W., Xu, Y. S., . . . Wu, S. P. (2021a). Controllable synthesis of SiC wrapped LDHs to reinforce microwave absorption and exothermic properties of styrene-butadiene-styrene (SBS) polymer modified asphalt. Materials Research Express, 8(3), 035501. https://doi.org/10.1088/2053-1591/abe975
Li, F., Zhang, Y. T., Xu, B., Liu, Y. Q., Qiu, H. Y., Lan, G. H., & Xu, Q. X. (2021). Synthesizing a novel Zr/Fe/Al-incorporated cross-linked chitosan as absorbent for effective removal of fluoride from aqueous solution. Water Air and Soil Pollution, 232(10), 401. https://doi.org/10.1007/s11270-021-05355-1
Li, S., Qin, H. J., Zuo, R. F., & Bai, Z. M. (2015). Friction properties of La-doped Mg/Al layered double hydroxide and intercalated product as lubricant additives. Tribology International, 91, 60–66. https://doi.org/10.1016/j.triboint.2015.06.012
Li, S. F., Shen, Y. M., Liu, D. B., Fan, L. H., & Wu, K. K. (2014). Encapsulation of 2,4-dihydroxybenzophenone into dodecylbenzenesulfonate modified layered double hydroxide for UV absorption properties. Bulletin of the Korean Chemical Society, 35(2), 392–396. https://doi.org/10.5012/bkcs.2014.35.2.392
Liang, X. F., Hou, W. G., Xu, Y. M., Sun, G. H., Wang, L., Sun, Y., & Qin, X. (2010). Sorption of lead ion by layered double hydroxide intercalated with diethylenetriaminepentaacetic acid. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 366(1–3), 50–57. https://doi.org/10.1016/j.colsurfa.2010.05.012
Lin, Y. Y., Xie, X. L., Wang, X., Zhang, B., Li, C. J., Wang, H., & Wang, L. J. (2017). Understanding the enhancement of electrochemical properties of NiCo layered double hydroxides via functional pillared effect: An insight into dual charge storage mechanisms. Electrochimica Acta, 246, 406–414. https://doi.org/10.1016/j.electacta.2017.06.067
Liu, J., Li, J., Wang, L. X., Bing, X. M., Cui, X. L., Ji, F., & Kionga, D. D. (2019). Synthesis of a novel magnetic SnNb2O6/CoFe-LDH 2D/2D heterostructure for the degradation of organic pollutants under visible light irradiation. Journal of Materials Science, 54(1), 172–187. https://doi.org/10.1007/s10853-018-2810-6
Liu, Y. T., Wang, M. K., Chen, T. Y., Chiang, P. N., Huang, P. M., & Lee, J. F. (2006). Arsenate sorption on lithium/ aluminum layered double hydroxide intercalated by chloride and on gibbsite: Sorption isotherms, envelopes, and spectroscopic studies. Environmental Science & Technology, 40(24), 7784–7789. https://doi.org/10.1021/es061530j
Luo, S., Guo, Y. Q., Yang, Y., Zhou, X. H., Peng, L., Wu, X. H., & Zeng, Q. R. (2019). Synthesis of calcined La-doped layered double hydroxides and application on simultaneously removal of arsenate and fluoride. Journal of Solid State Chemistry, 275, 197–205. https://doi.org/10.1016/j.jssc.2019.04.017
Lupo, M., Fina, B. L., Aguirre, M. C., Armendariz, M., & Rigalli, A. (2012). Determination of water fluoride concentration and the influence of the geographic coordinate system and time. Water Air and Soil Pollution, 223(8), 5221–5225. https://doi.org/10.1007/s11270-012-1273-7
Lv, L., He, J., Wei, M., Evans, D. G., & Duan, X. (2006). Factors influencing the removal of fluoride from aqueous solution by calcined Mg-Al-CO3 layered double hydroxides. Journal of Hazardous Materials, 133(1–3), 119–128. https://doi.org/10.1016/j.jhazmat.2005.10.012
Lyu, P., Wang, G., Wang, B., Yin, Q., Li, Y., & Deng, N. (2021). Adsorption and interaction mechanism of uranium (VI) from aqueous solutions on phosphate-impregnation biochar cross-linked Mg Al layered double-hydroxide composite. Applied Clay Science, 209, 106146. https://doi.org/10.1016/j.clay.2021.106146
Malherbe, F., Forano, C., & Besse, J. P. (1997). Use of organic media to modify the surface and porosity properties of hydrotalcite-like compounds. Microporous Materials, 10(1–3), 67–84. https://doi.org/10.1016/S0927-6513(96)00123-X
Millange, F., Walton, R. I., & O’Hare, D. (2000). Time-resolved in situ X-ray diffraction study of the liquid-phase reconstruction of Mg-Al-carbonate hydrotalcite-like compounds. Journal of Materials Chemistry, 10(7), 1713–1720. https://doi.org/10.1039/b002827o
Moujahid, E. M., Inacio, J., Besse, J. P., & Leroux, F. (2003). Adsorption of styrene sulfonate vs. polystyrene sulfonate on layered double hydroxides. Microporous and Mesoporous Materials, 57(1), 37–46. https://doi.org/10.1016/S1387-1811(02)00505-X
Murath, S., Somosi, Z., Toth, I. Y., Tombacz, E., Sipos, P., & Palinko, I. (2017). Delaminating and restacking MgAl-layered double hydroxide monitored and characterized by a range of instrumental methods. Journal of Molecular Structure, 1140, 77–82. https://doi.org/10.1016/j.molstruc.2016.10.056
Nagendra, B., Rosely, C. V. S., Leuteritz, A., Reuter, U., & Gowd, E. B. (2017). Polypropylene/layered double hydroxide nanocomposites: Influence of LDH intralayer metal constituents on the properties of polypropylene. ACS Omega, 2(1), 20–31. https://doi.org/10.1021/acsomega.6b00485
Oestreicher, V., Jobbágy, M., & Regazzoni, A. E. (2014). Halide exchange on Mg(II)–Al(III) layered double hydroxides: Exploring affinities and electrostatic predictive models. Langmuir, 30(28), 8408–8415. https://doi.org/10.1021/la5015187
Ou, B., Wang, J. X., Wu, Y., Zhao, S., & Wang, Z. (2020). Efficient removal of Cr (VI) by magnetic and recyclable calcined CoFe-LDH/g-C3N4 via the synergy of adsorption and photocatalysis under visible light. Chemical Engineering Journal, 380, 122600. https://doi.org/10.1016/j.cej.2019.122600
Qiu, X. H., Sasaki, K., Hirajima, T., Ideta, K., & Miyawaki, J. (2013). Temperature effect on the sorption of borate by a layered double hydroxide prepared using dolomite as a magnesium source. Chemical Engineering Journal, 225, 664–672. https://doi.org/10.1016/j.cej.2013.03.099
Rahmanian, O., Dinari, M., & Neamati, S. (2018). Synthesis and characterization of citrate intercalated layered double hydroxide as a green adsorbent for Ni2+ and Pb2+ removal. Environmental Science and Pollution Research, 25(36), 36267–36277. https://doi.org/10.1007/s11356-018-3584-8
Ropelewska, E., Dziejowski, J., & Zapotoczny, P. (2016). Changes in the microbial activity and thermal properties of soil treated with sodium fluoride. Applied Soil Ecology, 98, 159–165. https://doi.org/10.1016/j.apsoil.2015.10.013
Sarma, G. K., & Rashid, M. H. (2018). Synthesis of Mg/Al layered double hydroxides for adsorptive removal of fluoride from water: A mechanistic and kinetic study. Journal of Chemical and Engineering Data, 63(8), 2957–2965. https://doi.org/10.1021/acs.jced.8b00242
Sayed, M. R., Abukhadra, M. R., Ahmed, S. A., Shaban, M., Javed, U., Betiha, M. A., & Rabie, A. M. (2020). Synthesis of advanced MgAl-LDH based geopolymer as a potential catalyst in the conversion of waste sunflower oil into biodiesel: Response surface studies. Fuel, 282, 118865. https://doi.org/10.1016/j.fuel.2020.118865
Shan, R. R., Yan, L. G., Yang, K., Yu, S. J., Hao, Y. F., Yu, H. Q., & Du, B. (2014). Magnetic Fe3O4/MgAl-LDH composite for effective removal of three red dyes from aqueous solution. Chemical Engineering Journal, 252, 38–46. https://doi.org/10.1016/j.cej.2014.04.105
Sipos, P., Kis, V. K., Balazs, R., Toth, A., & Nemeth, T. (2021). Effect of pedogenic iron-oxyhydroxide removal on the metal sorption by soil clay minerals. Journal of Soils and Sediments, 21(4), 1785-1799. https://doi.org/10.1007/s11368-021-02899-x
Sohrabi, H., Arbabzadeh, O., Falaki, M., Majidi, M. R., Han, N., Yoon, Y., & Khataee, A. (2022). Electrochemical layered double hydroxide (LDH)-based biosensors for pesticides detection in food and environment samples: A review of status and prospects. Food and Chemical Toxicology, 164, 113010. https://doi.org/10.1016/j.fct.2022.113010
Stanimirova, T. S., Kirov, G., & Dinolova, E. (2001). Mechanism of hydrotalcite regeneration. Journal of Materials Science Letters, 20(5), 453–455. https://doi.org/10.1023/A:1010914900966
Sudare, T., Dubois, M., Louvain, N., Kiyama, M., Hayashi, F., & Teshima, K. (2020). Favorable intercalation of nitrate ions with fluorine-substituted layered double hydroxides. Inorganic Chemistry, 59(3), 1602–1610. https://doi.org/10.1021/acs.inorgchem.9b01552
Takahashi, Y., Uchida, H., Kameda, T., Kumagai, S., Saito, Y., Mizushina, K., . . . Yoshioka, T. (2021). Synthesis of MnO2/Mg-Al layered double hydroxide and evaluation of its NO-removal performance. Journal of Alloys and Compounds, 867, 159038. https://doi.org/10.1016/j.jallcom.2021.159038
Tezuka, S., Chitrakar, R., Sakane, K., Sonoda, A., Ooi, K., & Tomida, T. (2004). The synthesis and phosphate adsorptive properties of Mg(II)-Mn(III) layered double hydroxides and their heat-treated materials. Bulletin of the Chemical Society of Japan, 77(11), 2101–2107. https://doi.org/10.1246/bcsj.77.2101
Theiss, F. L., Couperthwaite, S. J., Ayoko, G. A., & Frost, R. L. (2014). A review of the removal of anions and oxyanions of the halogen elements from aqueous solution by layered double hydroxides. Journal of Colloid and Interface Science, 417, 356–368. https://doi.org/10.1016/j.jcis.2013.11.040
Tran, H. N., Lin, C. C., & Chao, H. P. (2018). Amino acids-intercalated Mg/Al layered double hydroxides as dual-electronic adsorbent for effective removal of cationic and oxyanionic metal ions. Separation and Purification Technology, 192, 36–45. https://doi.org/10.1016/j.seppur.2017.09.060
Wan, D. J., Liu, Y. D., Xiao, S. H., Chen, J., & Zhang, J. (2015). Uptake fluoride from water by caclined Mg-Al-CO3 hydrotalcite: Mg/Al ratio effect on its structure, electrical affinity and adsorptive property. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 469, 307–314. https://doi.org/10.1016/j.colsurfa.2015.01.045
Wang, B., Zhang, H., Evans, D. G., & Duan, X. (2005). Surface modification of layered double hydroxides and incorporation of hydrophobic organic compounds. Materials Chemistry and Physics, 92(1), 190–196. https://doi.org/10.1016/j.matchemphys.2005.01.013
Wang, H. T., Chen, J., Cai, Y. F., Ji, J. F., Lin, L. W., & Teng, H. H. (2007). Defluoridation of drinking water by Mg/Al hydrotalcite-like compounds and their calcined products. Applied Clay Science, 35(1–2), 59–66. https://doi.org/10.1016/j.clay.2006.08.005
Wang, J., Zhang, X.-D., Liu, Z.-R., & Jia, W.-G. (2002). Synthesis and structural determination of binuclear nine-coordinate (NH4)4[Yb2(dtpa)2]·9H2O. Journal of Molecular Structure, 613(1–3), 189–193. https://doi.org/10.1016/s0022-2860(02)00181-3
Wang, L., Zhang, Y., Lian, J., Chao, J., Gao, Y., Yang, F., & Zhang, L. (2013). Impact of fly ash and phosphatic rock on metal stabilization and bioavailability during sewage sludge vermicomposting. Bioresource Technology, 136, 281–287. https://doi.org/10.1016/j.biortech.2013.03.039
Wang, M., Li, X., He, W. Y., Li, J. X., Zhu, Y. Y., Liao, Y. L., & Yang, X. E. (2019). Distribution, health risk assessment, and anthropogenic sources of fluoride in farmland soils in phosphate industrial area, southwest China. Environmental Pollution, 249, 423–433. https://doi.org/10.1016/j.envpol.2019.03.044
Wang, M., Yu, X. L., Yang, C. L., Yang, X. Q., Lin, M. Y., Guan, L. T., & Ge, M. F. (2017). Removal of fluoride from aqueous solution by Mg-Al-Zr triple-metal composite. Chemical Engineering Journal, 322, 246–253. https://doi.org/10.1016/j.cej.2017.03.155
Xu, L. N., Meng, Z. L., Lv, F. Z., & Zhang, Y. H. (2014). Adsorption ability of SDS intercalated ZnAL-LDH and MgFe-LDH on simulated organic amine. Advanced Research on Material Engineering, Chemistry, Bioinformatics Iii, 830, 193–196. https://doi.org/10.4028/www.scientific.net/AMR.830.193
Xu, S., Dang, L., Yu, J. Y., Xue, L. H., Hu, C. B., & Que, Y. (2018). Evaluation of ultraviolet aging resistance of bitumen containing different organic layered double hydroxides. Construction and Building Materials, 192, 696–703. https://doi.org/10.1016/j.conbuildmat.2018.10.172
Xu, S., Yu, J. Y., Sun, Y. B., & Wu, S. P. (2015). Synthesis and characterization of organic intercalated layered double hydroxides and their application in bitumen modification. Materials Chemistry and Physics, 152, 54–61. https://doi.org/10.1016/j.matchemphys.2014.12.011
Xu, S., Zhang, L., Zhao, J., Cheng, J., Yu, Q., Zhang, S., & Qiu, X. (2020). Remediation of chromium-contaminated soil using delaminated layered double hydroxides with different divalent metals. Chemosphere, 254, 126879. https://doi.org/10.1016/j.chemosphere.2020.126879
Yadav, K. K., Gupta, N., Kumar, V., Khan, S. A., & Kumar, A. (2018). A review of emerging adsorbents and current demand for defluoridation of water: Bright future in water sustainability. Environment International, 111, 80–108. https://doi.org/10.1016/j.envint.2017.11.014
Yang, J. Y., Wang, M., Lu, J., Yang, K., Wang, K. P., Liu, M., & Wang, B. (2020). Fluorine in the environment in an endemic fluorosis area in Southwest. China Environ Res, 184, 109300. https://doi.org/10.1016/j.envres.2020.109300
Yasaei, M., Khakbiz, M., Ghasemi, E., & Zamanian, A. (2019). Synthesis and characterization of ZnAl-NO3(-CO3) layered double hydroxide: A novel structure for intercalation and release of simvastatin. Applied Surface Science, 467, 782–791. https://doi.org/10.1016/j.apsusc.2018.10.202
Yin, G., Song, X., Tao, L., Sarkar, B., Sarmah, A. K., Zhang, W., & Wang, H. (2020). Novel Fe-Mn binary oxide-biochar as an adsorbent for removing Cd(II) from aqueous solutions. Chemical Engineering Journal, 389, 124465. https://doi.org/10.1016/j.cej.2020.124465
Yu, Y., Chen, D., Xu, W., Fang, J., Sun, J., Liu, Z., & Fang, Z. (2021). Synergistic adsorption-photocatalytic degradation of different antibiotics in seawater by a porous g-C3N4/calcined-LDH and its application in synthetic mariculture wastewater. Journal of Hazardous Materials, 416, 126183. https://doi.org/10.1016/j.jhazmat.2021.126183
Yusupov, D. V., Dorokhova, L. A., Ilenok, S. S., Radomskaya, V. I., Pavlova, L. M., Kraydenko, R. I., & Baranovskaya, N. V. (2021). Fluorite formation in poplar leaves (Populus balsamifera L.) in an HF-polluted area. Water Air and Soil Pollution, 232(9), 369. https://doi.org/10.1007/s11270-021-05279-w
Zaghouane-Boudiaf, H., Boutahala, M., Tiar, C., Arab, L., & Garin, F. (2011). Treatment of 2,4,5-trichlorophenol by MgAl–SDBS organo-layered double hydroxides: Kinetic and equilibrium studies. Chemical Engineering Journal, 173(1), 36–41. https://doi.org/10.1016/j.cej.2011.07.032
Zhang, L., He, F., & Guan, Y. (2022). Immobilization of hexavalent chromium in contaminated soil by nano-sized layered double hydroxide intercalated with diethyldithiocarbamate: Fraction distribution, plant growth, and microbial evolution. Journal of Hazardous Materials, 430, 128382. https://doi.org/10.1016/j.jhazmat.2022.128382
Zhao, J. L., Zhang, L. P., Zhang, S. W., Yuan, W. Y., Fang, X., Yu, Q. Q., & Qiu, X. H. (2021). Remediation of chromium-contaminated soil using calcined layered double hydroxides containing different divalent metals: Temperatures and mechanism. Chemical Engineering Journal, 425, 131405. https://doi.org/10.1016/j.cej.2021.131405
Zhong, J., Lin, S., & Yu, J. G. (2021). Li+ adsorption performance and mechanism using lithium/aluminum layered double hydroxides in low grade brines. Desalination, 505, 114983. https://doi.org/10.1016/j.desal.2021.114983
Zhou, H., Ai, J., Gao, H. Y., Zhang, W. J., & Wang, D. S. (2020). Removal of arsenic in groundwater using Slag based calcined layered double hydroxides (CLDHs) with dual functions of adsorption and photo-catalysis. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 604, 125300. https://doi.org/10.1016/j.colsurfa.2020.125300
Zhou, J., Xu, Z. P., Qiao, S., Liu, Q., Xu, Y., & Qian, G. (2011). Enhanced removal of triphosphate by MgCaFe-Cl-LDH: Synergism of precipitation with intercalation and surface uptake. Journal of Hazardous Materials, 189(1–2), 586–594. https://doi.org/10.1016/j.jhazmat.2011.02.078
Zhou, J. Z., Shu, W. K., Gao, Y., Cao, Z. B., Zhang, J., Hou, H., & Qian, G. R. (2017). Enhanced arsenite immobilization via ternary layered double hydroxides and application to paddy soil remediation. Rsc Advances, 7(33), 20320–20326. https://doi.org/10.1039/c6ra28116h
Zhu, X. P., Wang, Y., Zuo, H. B., Zhao, P., & Wang, Z. P. (2020). Modified layered bimetallic compound used as a novel adsorbent for the solid-phase extraction of monoaromatic hydrocarbons from water samples prior to gas chromatography-mass spectrometry. Arabian Journal of Chemistry, 13(2), 4246–4253. https://doi.org/10.1016/j.arabjc.2019.07.004
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This study was supported by the State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization (2021P4FZG06A) and the Strategic Cooperation Project Between Sichuan University and Yibin Municipal Government (2019CDDYB-19).
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All authors contributed to the conception and design of this study. Material preparation, data collection, and analysis were performed by Dongling-Wang and Yuhan-Fu. Jinyan-Yang guided the writing of the article. The first draft of the manuscript was written by Dongling-Wang, and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Wang, Dl., Fu, Yh. & Yang, Jy. Enhanced Fluoride Stabilization by Modified Layered Double Hydroxides for the Remediation of Soil Pollution: Performance and Mechanism. Water Air Soil Pollut 233, 471 (2022). https://doi.org/10.1007/s11270-022-05938-6
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DOI: https://doi.org/10.1007/s11270-022-05938-6