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High Photocatalytic Activity of the Heterojunction Photocatalyst CoFe2O4/AgCl for Efficient Photodegradation of Solophenyl Red 3BL Dye in Water

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Abstract

To increase the photocatalytic activity of AgCl for environmental applications, a simple precipitation–deposition technique was established for the synthesis of the CoFe2O4/AgCl complex. For that, the phase of the nanoparticles was identified by X-ray diffraction (XRD), and combined scanning electron microscopy/energy-dispersive X-ray analysis. The point of zero charges (pHpzc) of CoFe2O4/AgCl was equal to 6.92. The gap energies of CoFe2O4(CFO) and AgCl, evaluated from the UV–VIS diffusion reflectance, were found to be 1.46 eV and 3.20 eV, respectively. The photo-electrochemistry was undertaken to determine the conduction type of the spinel; a flat band of 0.06 VSCE with p-type behavior has been determined and an energy diagram of the hetero-system CFO/AgCl/Na2SO4 electrolyte has been illustrated. As an application, the Solophenyl Red 3BL (SR 3BL), a recalcitrant dye, has been successfully oxidized. The effects of operational factors like the mass ratio (CFO/AgCl), pH, catalyst dose, and initial dye SR 3BL concentration (Co) were optimized. The results revealed a high photoactivity (100%) at pH ~ 3, a catalyst dose of 1 g/L, and an initial concentration (Co) of 10 mg/L within 150 min under visible light. The photo-oxidation data were fitted with the first-order kinetic, and half photocatalytic life of 19 min was extracted. In addition, photodegradation has also been experimented under solar light and a quasi-complete degradation was obtained with a faster kinetic. A photodegradation mechanism was proposed and the radical O2•− was found to be the main active species in the photocatalytic process. Moreover, this hetero-system demonstrated effective oxidation under solar light by facilitating photo-electron transport with the deference potential.

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This work was financially supported by both the Faculties of Mechanical Engineering and Process Engineering.

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  1. Laboratory of Transfer Phenomena, Faculty of Mechanical Engineering and Process Engineering, USTHB, BP 32, Algiers, Algeria

    Billal Brahimi & Elhadj Mekatel

  2. Laboratory of Reaction Engineering, Faculty of Mechanical Engineering and Process Engineering, USTHB, BP 32, Algiers, BP, Algeria

    Oussama Baaloudj

  3. Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry, USTHB, BP 32, Algiers, Algeria

    Mohamed Trari

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  1. Billal Brahimi
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Billal BRAHIMI: writing—original draft preparation; Elhadj MEKATEL: writing—review and editing; Oussama BAALOUDJ: visualization; Mohamed TRARI: supervision.

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Brahimi, B., Mekatel, E., Baaloudj, O. et al. High Photocatalytic Activity of the Heterojunction Photocatalyst CoFe2O4/AgCl for Efficient Photodegradation of Solophenyl Red 3BL Dye in Water. Water Air Soil Pollut 233, 347 (2022). https://doi.org/10.1007/s11270-022-05812-5

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