Abstract
The samples of natural and iron-modified clinoptilolite (GC, Na-GC, Fe1-GC, and Fe2-GC) were assessed as adsorbent for arsenate removal by batch and column studies. The influences of retention time, pH, adsorbent dosage, and initial arsenate concentration on the arsenate adsorption efficiency were investigated. The experiments demonstrated that Fe1-GC has the highest arsenate removal efficiency with the adsorption capacity of 8.4 μg g−1 at equilibrium time of 60 min. Both the Fe1-GC and Fe2-GC removed arsenate effectively over the initial pH range 4–10. Adsorption capacity of Fe1-GC was adequately described by Freundlich isotherm. According to the results of the desorption performance experiments, the Fe1-GC was used six times until arsenic removal efficiency was reduced to 19 %. The adsorption percentage of arsenic increased with the diminish of initial concentration of arsenic and increase of adsorbent dose for all types of clinoptilolite. The column study demonstrated that Fe1-GC was achieved to reduce final arsenate of about 10 μg L−1 or below for up to 300 bed volumes in a continuous flow mode. The results of this study show that Fe1-GC can be used as an alternative adsorbent for arsenate removal.
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Akin, I., Arslan, G., Tor, A., Cengeloglu, Y., & Ersoz, M. (2011). Removal of arsenate [As(V)] and arsenite [As(III)] from water by SWHR and BW-30 reverse osmosis. Desalination, 281, 88–92.
Altundogan, H. S., Altundogan, S., Tumen, F., & Bildik, M. (2000). Arsenic removal from aqueous solutions by adsorption on red mud. Waste Management, 20, 761–767.
Bilici Baskan, M., & Pala, A. (2009). Determination of arsenic removal efficiency by ferric ions using response surface methodology. Journal of Hazardous Materials, 166, 796–801.
Bilici Baskan, M., & Pala, A. (2010). A statistical experiment design approach for arsenic removal by coagulation process using aluminum sulfate. Desalination, 254, 42–48.
Bilici Baskan, M., & Pala, A. (2011). Removal of arsenic from drinking water using modified natural zeolite. Desalination, 281, 396–403.
Chen, Y., Chai, L., & Shu, Y. (2008). Study of arsenic(V) adsorption on bone char from aqueous solution. Journal of Hazardous Materials, 160, 168–172.
Chiavola, A., D'Amato, E., & Baciocchi, R. (2012). Ion exchange treatment of groundwater contaminated by arsenic in the presence of sulphate. Breakthrough experiments and modeling. Water, Air, & Soil Pollution, 223(5), 2373–2386.
Chutia, P., Kato, S., Kojima, T., & Satokawa, S. (2009). Arsenic adsorption from aqueous solution on synthetic zeolites. Journal of Hazardous Materials, 162, 440–447.
Doğan, M., & Doğan, A. U. (2007). Arsenic mineralization, source, distribution, and abundance in the Kutahya region of the Western Anatolia, Turkey. Environmental Geochemistry and Health, 29, 119–129.
García-Lara, A. M., & Montero-Ocampo, C. (2010). Improvement of arsenic electro-removal from underground water by lowering the interference of other ions. Water, Air, & Soil Pollution, 205, 237–244.
Gemici, Ü., Tarcan, G., Helvacı, C., & Somay, A. M. (2008). High arsenic and boron concentrations in groundwaters related to mining activity in the Bigadiç borate deposits (Western Turkey). Applied Geochemistry, 23, 2462–2476.
Glocheux, Y., Pasarin, M. M., Albadarin, A. B., Allen, S. J., & Walker, G. M. (2013). Removal of arsenic from groundwater by adsorption onto an acidified laterite by-product. Chemical Engineering Journal, 228, 565–574.
Habuda Stanic, M., Kalajdzic, B., Kules, M., & Velic, N. (2008). Arsenite and arsenate sorption by hydrous ferric oxide/polymeric material. Desalination, 229, 1–9.
Han, R., Wang, Y., Sun, Q., Wang, L., Song, J., He, X., & Dou, C. (2010). Malachite green adsorption onto natural zeolite and reuse by microwave irradiation. Journal of Hazardous Materials, 175, 1056–1061.
Jain, C. K., & Ali, I. (2000). Arsenic: occurrence, toxicity and speciation techniques. Water Research, 34(17), 4304–4312.
Jeon, C. S., Baek, K., Park, J. K., Oh, Y. K., & Lee, S. D. (2009). Adsorption characteristics of As(V) on iron-coated zeolite. Journal of Hazardous Materials, 163, 804–808.
Lamm, S. H., Engel, A., Kruse, M. B., Feinleib, M., Byrd, D. M., Lai, S., & Wilson, R. (2001). Arsenic in drinking water and bladder cancer mortality in the United States: an analysis based on 133 US countries and 30 years of observation. Journal of Occupational and Environmental Medicine, 46(3), 298–306.
Lenoble, V., Laclautre, C., Deluchat, V., Serpaud, B., & Bollinger, J. C. (2005). Arsenic removal by adsorption on iron(III) phosphate. Journal of Hazardous Materials, B123, 262–268.
Li, Q., Xu, X., Cui, H., Pang, J., Wei, Z., Sun, Z., & Zhai, J. (2012). Comparison of two adsorbents for the removal of pentavalent arsenic from aqueous solutions. Journal of Environmental Management, 98, 98–106.
Liu, X., Ao, H., Xiong, X., Xiao, J., & Liu, J. (2012). Arsenic removal from water by iron-modified bamboo charcoal. Water, Air, & Soil Pollution, 223, 1033–1044.
Macedo Miranda, M. G., & Olguin, M. T. (2007). Arsenic sorption by modified clinoptilolite-heulandite rich tuffs. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 59, 131–142.
Menhaje-Bena, R., Kazemian, H., Shahtaheri, S., Ghazi-Khansari, M., & Hosseini, M. (2004). Evaluation of iron modified zeolites for removal of arsenic from drinking water. Studies in Surface Science and Catalysis, 154, 1892–1899.
Mondal, D., & Polya, D. A. (2008). Rice as a major exposure route for arsenic in Chakdaha block, Nadia district, West Bengal, India: a probabilistic risk assessment. Applied Geochemistry, 23(11), 2987–2998.
Nabi, D., Aslam, I., & Qazı, I. A. (2009). Evaluation of the adsorption potential of titanium dioxide nanoparticles for arsenic removal. Journal of Environmental Sciences, 21, 402–408.
Sadiq, M., & Alam, I. (2004). Arsenic chemistry in a groundwater aquifer from the Eastern Province of Saudi Arabia. Water, Air, and Soil Pollution, 89, 67–76.
Smedley, P. L., & Kinniburgh, D. G. (2002). A review of the source, behaviour and distribution of arsenic in natural waters. Applied Geochemistry, 17, 517–568.
Su, C., & Puls, R. W. (2008). Arsenate and arsenite sorption on magnetite: relations to groundwater arsenic treatment using zerovalent iron and natural attenuation. Water, Air, & Soil Pollution, 193, 65–78.
Tavares, D. S., Lopes, C. B., Coelho, J. P., Sánchez, M. E., Garcia, A. I., Duarte, A. C., Otero, M., & Pereira, E. (2012). Removal of arsenic from aqueous solutions by sorption onto sewage sludge-based sorbent. Water, Air, & Soil Pollution, 223(5), 2311–2321.
Wang, S., & Mulligan, C. N. (2006). Occurrence of arsenic contamination in Canada: sources, behaviour and distribution. Science of the Total Environment, 366, 701–721.
Wang, S., Terdkiatburana, T., & Tade, M. O. (2008). Adsorption of Cu(II), Pb(II) and humic acid on natural zeolite tuff in single and binary systems. Separation and Purification Technology, 62, 64–70.
Xu, Y., Nakajima, T., & Ohki, A. (2002). Adsorption and removal of arsenic(V) from drinking water by aluminum-loaded Shirasu-zeolite. Journal of Hazardous Materials, B92, 275–287.
Yu, Y., Zhao, C., Wang, Y., Fan, W., & Luan, Z. (2013). Effects of ion concentration and natural organic matter on arsenic(V) removal by nanofiltration under different transmembrane pressures. Journal of Environmental Sciences, 25(2), 302–307.
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This study was supported by the Izmir Environmental Protection Foundation and the Scientific Research Projects of the Dokuz Eylul University, Izmir, Turkey, under grant number 2005.KB.FEN.003.
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Baskan, M.B., Pala, A. Batch and Fixed-Bed Column Studies of Arsenic Adsorption on the Natural and Modified Clinoptilolite. Water Air Soil Pollut 225, 1798 (2014). https://doi.org/10.1007/s11270-013-1798-4
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DOI: https://doi.org/10.1007/s11270-013-1798-4