Skip to main content

Advertisement

Log in

Friction and Wear Behavior of Irradiated Polyethylene Sliding Against a Rough Steel Surface

  • Original Paper
  • Published:
Tribology Letters Aims and scope Submit manuscript

Abstract

The aim of this study was to evaluate the tribological behavior of polyethylene crosslinked by gamma radiation sliding against a steel surface. Two high-density polyethylenes were irradiated to a total dose in the range of 2−20 Mrad under vacuum and at room temperature. After irradiation, the materials were annealed at 423 K and then cooled slowly to room temperature. The same thermal treatment was applied to the non-irradiated polymer. The wear behavior of the polymers was determined under controlled ambient temperature of 298 and 333 K using a homemade tribometer. Sheet-shaped specimens were loaded against the surface of a steel disc with different normal loads to generate nominal contact pressures in the range of 0.25–1.5 MPa. The tests were performed under dry conditions using a disc rotation to produce an average sliding speed of 0.6 m/s and during a period of time to provide an average sliding distance of 1,080 m. The wear rate was obtained as the mass loss by the sample divided by the sliding distance, and the friction coefficient was determined by measuring the friction force. The results indicate that the wear rate increases with load in the case of non-irradiated polyethylene and low-dose irradiated polymers, while the wear rate reaches a maximum value with the load in the case of the irradiated samples with high doses. The samples irradiated with a dose of 10 Mrad showed the lowest wear. The coefficient of friction (COF) increases slightly with the load in all the cases. Most irradiated polymers show higher COF than the non-irradiated material when compared at a given load. The results show that the irradiation dose applied to the polyethylenes produced no noticeable effect on the COF values when a comparison was made at a given applied load.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Brostow, W., Corneliussen, R.: Friction and Wear of Failure of Plastics. Hanser, New York (1986)

    Google Scholar 

  2. Lyons, B., Weir, F.: The Radiation Chemistry of Macromolecules. Academic Press, New York (1973)

    Google Scholar 

  3. Chodák, I.: Properties of crosslinked polyolefin-based materials. Prog. Polym. Sci. 20(6), 1165–1199 (1995)

    Article  Google Scholar 

  4. Failla, M., Vallés, E., Lyons, B.: Effect of initial crystallinity on the response of high-density polyethylene to high-energy radiation. J. Appl. Polym. Sci. 71, 1375–1384 (1999)

    Article  Google Scholar 

  5. Shen, C., Dumbleton, J.H.: The friction and wear behavior of irradiated very high molecular weight polyethylene. Wear 30, 349–364 (1974)

    Article  Google Scholar 

  6. Muratoglu, O., Bragdon, C., O’Connor, D., Jasty, M., Harris, W., Gul, R., McGarry, F.: Unified wear model for highly crosslinked ultra-high molecular weight polyethylenes (UHMWPE). Biomaterials 20(16), 1463–1470 (1999)

    Article  Google Scholar 

  7. McKellop, H., Shen, F.W., Lu, B., Campbell, P., Salovey, R.: Development of an extremely wear-resistant ultra high molecular weight polyethylene for total hip replacements. J. Orthop. Res. 17(2), 157–167 (1999)

    Article  Google Scholar 

  8. Wang, A., Sun, D., Yau, S., Edwards, B., Sokol, M., Essner, A., Polineni, V., Stark, C., Dumbleton, J.: Orientation softening in the deformation and wear of ultra-high molecular weight polyethylene. Wear 203, 230–241 (1997)

    Article  Google Scholar 

  9. Pruitt, L.: Deformation, yielding, fracture and fatigue behavior of conventional and highly cross-linked ultra high molecular weight polyethylene. Biomaterials 26, 905–915 (2005)

    Article  Google Scholar 

  10. Tervoort, T., Visjager, J., Smith, P.: On abrasive wear of polyethylene. Macromolecules 35, 8467–8471 (2002)

    Article  Google Scholar 

  11. Lucas, A., Ambrósio, J., Otaguro, H., Costa, L., Agnelli, J.: Abrasive wear of HDPE/UHMWPE blends. Wear 270, 576–583 (2011)

    Article  Google Scholar 

  12. Jacobs, O., Mentz, N., Poeppel, A., Schulte, K.: Sliding wear performance of HD–PE reinforced by continuous UHMWPE fibers. Wear 244, 20–28 (2000)

    Article  Google Scholar 

  13. Awatani, J., Minegaki, M.: Measurements of effects of γ-ray irradiation on polyethylene by a vibration reed method. Trans. Jpn. Soc. Mech. Eng. 7(26), 302–309 (1964)

    Google Scholar 

  14. Matsubara, K., Watanabe, M.: The wear properties of high density polyethylene irradiated by gamma rays. Wear 10, 214–222 (1967)

    Article  Google Scholar 

  15. Kampouris, E., Andreopoulus, A.: The effect of the gel content of crosslinked polyethylene on its physical properties. Eur. Polym. J. 25(3), 321–324 (1989)

    Article  Google Scholar 

  16. Sakoda, H., Voice, A.M., McEwen, H., Isaac, G., Hardaker, C., Wroblewski, B., Fisher, J.: A comparison of the wear and physical properties of silane cross-linked polyethylene and ultra-high molecular weight polyethylene. J Arthroplast. 16(8), 1018–1023 (2001)

    Article  Google Scholar 

  17. Atkinson, J., Cicek, R.: Silane crosslinked polyethylene for prosthetic applications: II. Creep and wear behaviour and a preliminary moulding test. Biomaterials 5(6), 326–335 (1984)

    Article  Google Scholar 

  18. Tuckart, W., Rosevear, M., Molinari, E., Gregorio, M., Failla, M.: Sliding wear behaviour of high density polyethylene cross-linked by gamma radiation. Rev. Lat. Am. Metal. Mat. 32(2), 261–268 (2012)

    Google Scholar 

  19. Jones Jr, W., Hady, W., Crugnola, A.: Effect of γ irradiation on the friction and wear of ultrahigh molecular weight polyethylene. Wear 70(1), 77–92 (1981)

    Article  Google Scholar 

  20. Budinski, K.: Resistance to particle abrasion of selected plastics. Wear 203–204, 302–309 (1997)

    Article  Google Scholar 

  21. Quinn Jr, F., Mandelkern, L.: Additions and corrections: thermodynamics of crystallization in high polymers: polyethylene. Am. Chem. Soc. 81, 6533 (1959)

    Article  Google Scholar 

  22. Perez, C., Vallés, E., Failla, M.: The effect of post-irradiation annealing on the crosslinking of high density polyethylene induced by gamma-radiation. Radiat. Phys. Chem. 79(6), 710–717 (2010)

    Article  Google Scholar 

  23. Lawton, E., Powell, R., Balwit, J.: Effect of physical state during the electron irradiation of hydrocarbon polymers. Part I. The influence of physical state on reactions occurring in polyethylene during and following the irradiation. J. Polym. Sci. 32(125), 257–275 (1958)

    Article  Google Scholar 

  24. Kang, H., Saito, O., Dole, M.: The radiation chemistry of polyethylene. Temperature coefficient of cross-linking and other effects. J. Am. Chem. Soc. 89(9), 1980–1986 (1967)

    Article  Google Scholar 

  25. Dole, M.: Cross-linking and crystallinity in irradiated polyethylene. Polym. Plast. Technol. Eng. 13(1), 41–64 (1979)

    Article  Google Scholar 

  26. Henderson, P., Wallace, A.: Hardness and creep of crosslinked polyethylene. Polymer 30, 2209–2214 (1989)

    Article  Google Scholar 

  27. Baltá-Calleja, F.J.: Dependence of micro-indentation hardness on the superstructure of polyethylene. Colloid Polym. Sci. 254, 258–266 (1976)

    Article  Google Scholar 

  28. Briscoe, B., Sinha, S.: Wear of polymers. J. Eng. Tribol. 216, 401–413 (2002)

    Google Scholar 

  29. Myshkin, N.K., Kovalev, A.: Tribology of polymers adhesion and friction of polymers. Tribol. Int. 38, 910–921 (2005)

    Article  Google Scholar 

  30. Bahadur, S., Stiglich, J.: The wear of high density polyethylene sliding against steel surface. Wear 68, 85–95 (1981)

    Article  Google Scholar 

  31. Sinha, K., Briscoe, B.: Polymer Tribology. Imperial College Press, London (2009)

    Book  Google Scholar 

  32. Bahadur, S.: The development of transfer layers and their role in polymer tribology. Wear 245, 92–99 (2000)

    Article  Google Scholar 

  33. Briscoe, B., Pogosian, A., Tabor, D.: The friction and wear of high density polyethylene: the action of lead oxide and copper oxide fillers. Wear 27, 19–34 (1974)

    Article  Google Scholar 

  34. da Silva, C., Tanaka, D., Sinatora, A.: The effect of load and relative humidity on friction coefficient between high density polyethylene on galvanized steel—preliminary results. Wear 225–229, 339–342 (1999)

    Article  Google Scholar 

  35. Braithwaite, E.R.: Lubrication and Lubricants. Elsevier, Amsterdam (1967)

    Google Scholar 

  36. Lancaster, J.K.: Abrasive wear of polymers. Wear 14, 223–239 (1969)

    Article  Google Scholar 

  37. Hutchings, I.M.: Tribology, Friction and Wear of Engineering Materials. CRC Press, Boca Raton (1992)

    Google Scholar 

  38. Lancaster, J.K.: Relationships between the wear of polymers and their mechanical properties. Proc. Inst. Mech. Eng. 183, 98–106 (1968)

    Google Scholar 

  39. Vallés, E., Failla, M.: The effect of temperature on the tensile mechanical behavior of irradiated linear polyethylene. J. Appl. Polym. Sci. 88(8), 1925–1936 (2003)

    Article  Google Scholar 

  40. Muratoglu, O., Bragdon, C., O’Connor, D., Jasty, M., Harris, W., Gul, R., McGarry, F.: Unified wear model for highly crosslinked ultra-high molecular weight polyethylenes (UHMWPE). Biomaterials 20, 1463–1470 (1999)

    Article  Google Scholar 

  41. Ting-Yung, H., Eiss Jr., N.S.: The effects of molecular weight and cooling rate on fine structure, stress–strain behavior and wear of polytetrafluoroethylene. Wear 84, 203–215 (1983)

    Article  Google Scholar 

  42. Kanaga Karuppiah, K., Bruck, A., Sundararajan, S., Wang, J., Lin, Z., Xu, Z., Li, X.: Friction and wear behavior of ultra-high molecular weight polyethylene as a function of polymer crystallinity. Acta Biomater. 4, 1401–1410 (2008)

    Article  Google Scholar 

  43. Komoto, T., Tanaka, K., Hironaka, S., Matsumoto, T., Takano, N.: Morphological study of the wear of crystalline polymers I: high density polyethylene. Wear 75, 173–182 (1982)

    Article  Google Scholar 

  44. Spalding, M., Hyun, K.: Polymer coefficients of dynamic friction as a function of temperature, pressure, and velocity for several polyethylene resins. Eng. Sci. 35(7), 557–563 (1995)

    Google Scholar 

  45. Mathew, M., Novo, J., Rocha, L., Covas, J., Gomes, J.: Tribological, rheological and mechanical characterization of polymer blends for ropes and nets. Tribol. Int. 43, 1400–1409 (2010)

    Article  Google Scholar 

  46. Santner, E., Czichos, H.: Tribology of polymers. Tribol. Int. 22, 103–109 (1989)

    Article  Google Scholar 

Download references

Acknowledgments

The authors wish to express their appreciation for the support given to the Engineering Department of Universidad Nacional del Sur and CONICET for the financial support of this article.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to W. Tuckart.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tuckart, W., Molinari, E., Rossit, D. et al. Friction and Wear Behavior of Irradiated Polyethylene Sliding Against a Rough Steel Surface. Tribol Lett 55, 165–176 (2014). https://doi.org/10.1007/s11249-014-0344-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11249-014-0344-x

Keywords

Navigation