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Tribological Behavior of Bronze Composite Coatings Obtained by Plasma Thermal Spraying

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Abstract

Bronze aluminum composite coatings containing different amounts of alumina were fabricated by plasma spray process and their tribological properties were investigated using ball-on-disk (BOD) and rubber wheel (RW) tests at room temperature. Main wear mechanisms in pure bronze coatings during the ball-on-disk friction test were abrasion and intersplat delamination. The addition of alumina in bronze coatings clearly enhances their wear resistance. To explain this behavior, this article proposes an additional wear mechanism in the composite coatings that involves the rupture of the alumina lamellae located just below the wear track leading to a uniform distribution of fine alumina particles enveloped by the bronze matrix, which increase the surface hardness and hinder the wear. The deposition of debris on the wear track of composite coatings provokes an enhancement of the wear resistance as well. Bronze coatings show a low and stable friction coefficient of around μ = 0.3. Nevertheless, coatings with reinforcing particles of alumina show an abrupt transition in the friction coefficient from values around μ = 0.4–0.8, related to the modification of the surface contacts on the wear track due to the formation of a compacted debris layer deposited during the tribological test.

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References

  1. Zhong-li, Z., De-yuan, L., Shui-yong, W.: High temperature performance of arc-sprayed aluminum bronze coatings for steel. Trans. Nonferrous Met. Soc. China 16, 868–872 (2006)

    Article  Google Scholar 

  2. Kudashov, D.V., Zauter, R., Müller, H.R.: Spray-formed high-aluminium bronzes. Mater. Sci. Eng. A 477, 43–49 (2008)

    Article  Google Scholar 

  3. Alam, S., Saraki, S., Shimura, H.: Friction and wear characteristics of aluminum bronze coatings on steel substrates sprayed by a low pressure plasma technique. Wear 248, 75–81 (2001)

    Article  CAS  Google Scholar 

  4. van der Heide, E., Stam, E.D., Giraud, H., Lovato, G., Akdut, N., Clarysse, F., Caenen, P., Heikillä, I.: Wear of aluminium bronze in sliding contact with lubricated stainless steel sheet material. Wear 261, 68–73 (2006)

    Article  Google Scholar 

  5. Tura, J.M., Traveria, A., de Castellar, M.D., Pujadas, J., Blouet, J., Gras, R., Magham, H.G., Belair, P., Hanau, T., Romero, A.: Frictional properties and wear of a molybdenum coating and a bronze (Cu–10%Sn) with friction modifier fillers. Wear 189, 70–76 (1995)

    Article  CAS  Google Scholar 

  6. Sharma, S.C., Satish, B.M., Girish, B.M., Somashekar, D.R.: Wear characteristics of phosphor–bronze/silicon carbide particulate composites. J. Mater. Process. Technol. 118, 65–68 (2001)

    Article  CAS  Google Scholar 

  7. Guo, X., Zhang, G., Li, W., Gao, Y., Liao, H., Coddet, C.: Investigation of the microstructure and tribological behavior of cold-sprayed tin-bronze-based composite coatings. Appl. Surf. Sci. 255, 3822–3828 (2009)

    Article  CAS  Google Scholar 

  8. Venkateswarlu, K., Rajinikanth, V., Naveen, T., Prasad, D., Atiquzzaman, S., Kumar Ray, A.: Abrasive wear behavior of thermally sprayed diamond reinforced composite coating deposited with both oxy-acetylene and HVOF techniques. Wear 266, 995–1002 (2009)

    Article  CAS  Google Scholar 

  9. Venkateswarlu, K., Ray, A.K., Gunjan, M.K., Mondal, D.P., Pathak, L.C.: Tribological wear behavior of diamond reinforced composite coating. Mater. Sci. Eng. A 418, 357–363 (2006)

    Article  Google Scholar 

  10. Tillmann, W., Vogli, E., Nebel, J.: Development of detonation flame sprayed Cu-base coatings containing large ceramic particles. J. Therm. Spray Tech. 16(5–6), 751–758 (2007)

    Article  CAS  Google Scholar 

  11. Sornakumar, T., Senthil Kumar, A.: Machinability of bronze–alumina composite with tungsten carbide cutting tool insert. J. Mater. Process. Technol. 202, 402–405 (2008)

    Article  CAS  Google Scholar 

  12. Yilmaz, O., Buytoz, S.: Abrasive wear of Al2O3-reinforced aluminium-based MMCs. Compos. Sci. Technol. 61, 2381–2392 (2001)

    Article  CAS  Google Scholar 

  13. Travitzky, N.A.: Microstructure and mechanical properties of alumina/copper composites fabricated by different infiltration techniques. Mater. Lett. 36, 114–117 (1998)

    Article  CAS  Google Scholar 

  14. Hung, J.H.H., Chiu, Y.L., Liang, J.: Reciprocating wear properties of thermal sprayed titanium aluminide–alumina composite coatings. Surf. Coat. Technol. 202, 5599–5602 (2008)

    Article  CAS  Google Scholar 

  15. Miguel, J.M., Guilemany, J.M., Vizcaino, S.: Tribological study of NiCrBSi coating obtained by different processes. Tribol. Int. 36, 181–187 (2003)

    Article  CAS  Google Scholar 

  16. Steinhäuser, S., Wielage, B., Hofmann, U., Schnick, Th., Ilyuschenko, A., Azarova, T.: Plasma-sprayed wear-resistant coatings with respect to ecological aspects. Surf. Coat. Technol. 131, 365–371 (2000)

    Article  Google Scholar 

  17. Pawlowski, L.: The Science and Engineering of Thermal Spray Coatings, pp. 33–35. Wiley, New York (1992). ISBN 0 471 95253 2

  18. Jose, M.: Miguel, Propiedades mecánicas y tribológicas de recubrimientos de proyección térmica. PhD thesis, Barcelona (Feb 2002)

  19. Tan, K.S., Wharton, J.A., Wood, R.J.K.: Solid particle erosion–corrosion behaviour of a novel HVOF nickel aluminium bronze coating for marine applications—correlation between mass loss and electrochemical measurements. Wear 258, 629–640 (2005)

    Article  CAS  Google Scholar 

  20. ASM International: Metals Handbook, Properties and Selection: Nonferrous Alloys and Special-Purpose Materials, vol. 2, 10th edn. ASM International, Materials Park, OH (2006). ISBN 0-87170-378-3

  21. ASM International: Metals Handbook, Friction, Lubrication and Wear Technology, vol 18, 10th edn. ASM International, Materials Park, OH (2006). ISBN 0-87170-378-3

  22. Tabor, D.: The physical meaning of indentation and scratch hardness. Br. J. Appl. Phys. 7, 159–166 (1956)

    Article  Google Scholar 

  23. Erickson, L.C., Westergard, R., Wiklund, U., Axén, N., Hawthorne, H.M., Hogmark, S.: Cohesion in plasma-sprayed coatings—a comparison between evaluation methods. Wear 214, 30–37 (1998)

    Article  CAS  Google Scholar 

  24. Prchlik, L., Sampath, S.: Effect of the microstructure of thermally sprayed coatings on friction and wear response under lubricated and dry sliding conditions. Wear 262, 11–23 (2007)

    Article  CAS  Google Scholar 

  25. Kalin, M.: Influence of flash temperatures on the tribological behaviour in low-speed sliding: a review. Mater. Sci. Eng. A 374, 390–397 (2004)

    Article  Google Scholar 

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Acknowledgments

The authors would like to thank the Generalitat de Catalunya -project 2009SGR00390.

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Correspondence to J. M. Miguel.

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Miguel, J.M., Vizcaino, S., Lorenzana, C. et al. Tribological Behavior of Bronze Composite Coatings Obtained by Plasma Thermal Spraying. Tribol Lett 42, 263–273 (2011). https://doi.org/10.1007/s11249-011-9769-7

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  • DOI: https://doi.org/10.1007/s11249-011-9769-7

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