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Supported Ionic Liquid Catalysts (SILCA) for Preparation of Organic Chemicals

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Abstract

Supported Ionic Liquid Catalysts (SILCA) designed by immobilization of catalytic species residing in an ionic liquid layer, which in turn was immobilized on a solid support, were applied on the selective hydrogenation of citral in a batch reactor and in a continuous reactor. Different ionic liquids with and without addition of acid modificators were studied in terms of the catalyst activity and product selectivity. Consequently, mechanistic kinetic models describing the differences in the activity and selectivity of the catalysts consisting different ionic liquids, were developed.

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Acknowledgments

Financial support from the Academy of Finland is gratefully acknowledged (Decisions nr. 124640, 209391 and 211463). This work is a part of the activities at the Åbo Akademi Process Chemistry Centre (PCC) within the Finnish Centre of Excellence Programs (2000–2005 and 2006–2011) by the Academy of Finland.

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Authors and Affiliations

  1. Laboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, Åbo Akademi, 20500, Turku/Åbo, Finland

    Pasi Virtanen, Tapio O. Salmi & Jyri-Pekka Mikkola

  2. Department of Chemistry, Technical Chemistry, Chemical-Biological Center, Umeå University, 90187, Umeå, Sweden

    Jyri-Pekka Mikkola

Authors
  1. Pasi Virtanen
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  2. Tapio O. Salmi
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  3. Jyri-Pekka Mikkola
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Correspondence to Pasi Virtanen.

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Virtanen, P., Salmi, T.O. & Mikkola, JP. Supported Ionic Liquid Catalysts (SILCA) for Preparation of Organic Chemicals. Top Catal 53, 1096–1103 (2010). https://doi.org/10.1007/s11244-010-9540-6

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