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Hydroformylation of 1-Hexene on Silicalite-1 Zeolite Membrane Coated Pd–Co/A.C. Catalyst

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Abstract

A core–shell-like encapsulated catalyst was designed where Pd–Co/activated carbon (A.C.) catalyst was enwrapped by silicalite-1 zeolite membrane, which greatly improved normal to iso ratio of aldehyde products during hydroformylation of 1-hexene with syngas (CO + H2), due to its spatial confined structure and shape selective property derived from zeolite membrane.

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Acknowledgements

Authors thank the financial aids from the “863 Program” of the Ministry of Science & Technology of China (No. 2008AA06Z323), the National Natural Science Foundation of China (No. 20806056), the Doctoral Fund of Ministry of Education of China (No. 200800561002), and the Natural Science Foundation of Tianjin (No. 09ZCGHHZ00400). The support from Venture Business Laboratory fund of University of Toyama is also greatly appreciated.

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Authors and Affiliations

  1. Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing, 100029, People’s Republic of China

    Yi Zhang

  2. Tianjin Key Laboratory of Applied Catalysis Science and Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, People’s Republic of China

    Xingang Li & Ming Meng

  3. Department of Applied Chemistry, School of Engineering, University of Toyama, Gofuku 3190, Toyama City, Toyama, 930-8555, Japan

    Fanzhi Meng, Xiaoguang San, Guohui Yang, Minoru Takahashi & Noritatsu Tsubaki

  4. JST, CREST, Sanbancho 5, Chiyoda-ku, Tokyo, 102-0075, Japan

    Noritatsu Tsubaki

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  1. Xingang Li
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  2. Yi Zhang
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  3. Fanzhi Meng
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  4. Xiaoguang San
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  5. Guohui Yang
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  6. Ming Meng
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  7. Minoru Takahashi
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  8. Noritatsu Tsubaki
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Corresponding authors

Correspondence to Xingang Li, Yi Zhang or Noritatsu Tsubaki.

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Li, X., Zhang, Y., Meng, F. et al. Hydroformylation of 1-Hexene on Silicalite-1 Zeolite Membrane Coated Pd–Co/A.C. Catalyst. Top Catal 53, 608–614 (2010). https://doi.org/10.1007/s11244-010-9494-8

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  • DOI: https://doi.org/10.1007/s11244-010-9494-8

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