Skip to main content
SpringerLink
Log in

Effect of Surface Treatment on the Selective Photocatalytic Oxidation of Benzyl Alcohol into Benzaldehyde by O2 on TiO2 Under Visible Light

  • Original Paper
  • Published:
Topics in Catalysis Aims and scope Submit manuscript

Abstract

The photocatalytic oxidation of benzyl alcohol into benzaldehyde proceeded with high conversion and selectivity on a TiO2 photocatalyst by O2 under visible light irradiation. Surface complex formed by the interaction of benzyl alcohol with the Ti sites and/or surface OH groups of TiO2 play an important role in the absorption of visible light and unique selective photocatalytic reaction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Kitano M, Iyatani K, Tsujimaru K, Matsuoka M, Takeuchi M, Ueshima M, Thomas JM, Anpo M (2008) Top Catal 49:24

    Article  CAS  Google Scholar 

  2. Grätzel M (2003) J Photochem Photobiol C Photochem Rev 4:145

    Article  Google Scholar 

  3. Fujishima A, Rao TN, Tryk DA (2000) J Photochem Photobiol C Photochem Rev 1:1

    Article  CAS  Google Scholar 

  4. Fox MA, Dulay MT (1993) Chem Rev 93:341

    Article  CAS  Google Scholar 

  5. Chen J, Ollis DF, Rulkens WH, Bruning H (1998) Water Res 33:669

    Article  Google Scholar 

  6. Muggli DS, Mccue JT, Falconer JL (1998) J Catal 173:470

    Article  CAS  Google Scholar 

  7. Falconer JL, Magrini-Bair KA (1998) J Catal 179:171

    Article  CAS  Google Scholar 

  8. Hussein FH, Pattenden G, Rudham R, Russell JJ (1984) Tetrahedron Lett 25:3363

    Article  CAS  Google Scholar 

  9. Pillai UR, Sahle-Demessie E (2002) J Catal 211:434

    CAS  Google Scholar 

  10. Mohamed OS, Gaber AEM, Abdel-Wahab AA (2002) J Photochem Photobiol A 148:205

    Article  CAS  Google Scholar 

  11. Farhadi S, Afshari M, Maleki M, Badazadeh Z (2005) Tetrahedron Lett 46:8483

    Article  CAS  Google Scholar 

  12. Yurdakal S, Palmisano G, Loddo V, Augugliaro V, Palmisano L (2008) J Am Chem Soc 130:1568

    Article  CAS  Google Scholar 

  13. Augugliaro V, Caronna T, Loddo V, Marci G, Palmisano G, Palmisano L, Yurdakal S (2008) Chem Eur J 14:4640

    Article  CAS  Google Scholar 

  14. Palmisano G, Yurdakal S, Augugliaro V, Loddo V, Palmisano L (2007) Adv Synth Catal 349:964

    Article  CAS  Google Scholar 

  15. Palmisano G, Addamo M, Augugliaro V, Caronna T, Garcia-Lopez E, Loddo V, Palmisano L (2006) Chem Commun 1012

  16. Addamo M, Augugliaro V, Bellardita M, Paola AD, Loddo V, Palmisano G, Palmisano L, Yurdakal S (2008) Catal Lett 126:58

    Article  CAS  Google Scholar 

  17. Ohuchi T, Miyatake T, Hitomi Y, Tanaka T (2007) Catal Today 120:233

    Article  CAS  Google Scholar 

  18. Shishido T, Miyatake T, Teramura K, Hitomi Y, Yamashita H, Tanaka T (2009) J Phys Chem C 113:18713

    Article  CAS  Google Scholar 

  19. Higashimoto S, Kitao N, Yoshida N, Sakura T, Azuma M, Ohue H, Sakata Y (2009) J Catal 266:279

    Article  CAS  Google Scholar 

  20. Wang Y, Hang K, Anderson NA, Lian T (2003) J Phys Chem B 107:9434

    Article  CAS  Google Scholar 

  21. Tachikawa T, Tojo S, Fujitsuka M, Majima T (2004) Langmuir 20:2753

    Article  CAS  Google Scholar 

  22. Takeuchi M, Bertinetti L, Martra G, Coluccia S, Anpo M (2006) Appl Catal A Gen 307:13

    Article  CAS  Google Scholar 

  23. Nosaka AY, Nishino J, Fujiwara T, Ikegami T, Yagi H, Akutsu H, Nosaka Y (2006) J Phys Chem B 110:8380

    Article  CAS  Google Scholar 

  24. Parfitt GD (1976) Prog Surf Membr Sci 11:181

    CAS  Google Scholar 

  25. Yang HG, Sun CH, Qiao SZ, Zou J, Liu G, Smith SC, Cheng HM, Lu GQ (2008) Nature 453:638

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, College of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka, 535-8585, Japan

    Shinya Higashimoto, Kohei Okada, Tomoki Morisugi, Masashi Azuma & Hiroyoshi Ohue

  2. Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka, 599-8531, Japan

    Tae-Ho Kim, Masaya Matsuoka & Masakazu Anpo

Authors
  1. Shinya Higashimoto
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kohei Okada
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Tomoki Morisugi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Masashi Azuma
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Hiroyoshi Ohue
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Tae-Ho Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Masaya Matsuoka
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Masakazu Anpo
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shinya Higashimoto.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Higashimoto, S., Okada, K., Morisugi, T. et al. Effect of Surface Treatment on the Selective Photocatalytic Oxidation of Benzyl Alcohol into Benzaldehyde by O2 on TiO2 Under Visible Light. Top Catal 53, 578–583 (2010). https://doi.org/10.1007/s11244-010-9490-z

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11244-010-9490-z

Keywords

Search

Navigation