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Microwave Assisted Synthesis of Cyclic Carbonate Using Homogeneous and Heterogeneous Ionic Liquid Catalysts

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Abstract

A comparative study was effectuated between the catalytic performance of homogeneous and silica supported ionic liquids (SSILs) for the cycloaddition of epoxides and CO2 under microwave irradiation by varying the reaction parameters. Compared to the classical heating mode, both catalysts showed higher activity at moderate reaction condition through microwave irradiation.

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Acknowledgements

The authors are grateful to Korea Science and Engineering Foundation (R01-2007-000-10183-0), Pusan National University (Post-Doc. 2009) and BK 21 for the financial support and KBSI, Busan for the catalyst and product characterization.

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Authors and Affiliations

  1. Department of Chemical Engineering, Pusan National University, Busan, 609 735, Korea

    Manju Mamparambath Dharman, Hye-Ji Choi, Sang-Wook Park & Dae-Won Park

Authors
  1. Manju Mamparambath Dharman
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  2. Hye-Ji Choi
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  3. Sang-Wook Park
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  4. Dae-Won Park
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Correspondence to Dae-Won Park.

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Mamparambath Dharman, M., Choi, HJ., Park, SW. et al. Microwave Assisted Synthesis of Cyclic Carbonate Using Homogeneous and Heterogeneous Ionic Liquid Catalysts. Top Catal 53, 462–469 (2010). https://doi.org/10.1007/s11244-010-9473-0

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  • DOI: https://doi.org/10.1007/s11244-010-9473-0

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