Abstract
Biodiesel, an alternative to petroleum-derived diesel fuel, is defined as the mono-alkyl esters of vegetable oils and animal fats. Several current issues affecting biodiesel that are briefly discussed include the role of new feedstocks in meeting increased demand for biodiesel and circumventing the food versus fuel issue, biodiesel production, as well as fuel properties and their improvement.
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References
Mittelbach M, Remschmidt C (2004) Biodiesel––the comprehensive handbook. M Mittelbach, Graz, Austria
Knothe G, Van Gerpen J, Krahl J (eds) (2005) The biodiesel handbook. AOCS Press, Champaign, IL
American Society for Testing and Materials (ASTM) Standard D6751. Standard specification for biodiesel fuel blend stock (B100) for middle distillate fuels. ASTM, West Conshohocken, PA
Sims REH (1985) Tallow esters as an alternative diesel fuel. Trans ASAE 28:716–721
Zheng D, Hanna MA (1996) Preparation and properties of methyl esters of beef tallow. Bioresour Technol 57:137–142
Nye MJ, Williamson TW, Deshpande S, Schrader JH, Snively WH, Yurkewich TP, French CL (1983) Conversion of used frying oil to diesel fuel by transesterification: preliminary tests. J Am Oil Chem Soc 60:1598–1601
Kulkarni MG, Dalai AK (2006) Waste cooking oil––an economical source for biodiesel: a review. Ind Eng Chem Res 45:2901–2913
Chisti Y (2007) Biodiesel from microalgae. Biotechnol Adv 25:294–306
Schenk PM, Thomas-Hall SR, Stephens E, Marx UC, Mussgnug JH, Posten C, Kruse O, Hankamer B (2008) Second generation biofuels: high-efficiency microalgae for biodiesel production. Bioenergy Res 1:20–43
Hu Q, Sommerfeld M, Jarvis E, Ghirardi M, Posewitz M, Seibert M, Darzins A (2008) Microalgal triacylglycerols as feedstocks for biofuel production: perspectives and advances. Plant J 54:621–639
Lardon L, Hélias A, Sialve B, Steyer JP, Bernard A (2009) Life-cycle assessment of biodiesel production from microalgae. Environ Sci Technol 43:6475–6481
Foidl N, Foidl G, Sanchez M, Mittelbach M, Hackel S (1996) Jatropha Curcas L. as a source for the production of biofuel in Nicaragua. Bioresour Technol 58:77–82
Wood P (2005) Out of Africa. Could Jatropha be Europe’s biodiesel feedstock? Refocus 6:40–44
Berchmans HJ, Hirata S (2008) Biodiesel production from crude Jatropha curcas L. seed oil with a high content of free fatty acids. Bioresour Technol 99:1716–1721
European Committee for Standardization. Standard EN 14214. Automotive fuels––fatty acid methyl esters (FAME) for diesel engines––requirements and test methods
Diesel R (1913) Die Entstehung des Dieselmotors. Verlag von Julius Springer, Berlin
Diesel R (1912) The diesel oil-engine. Engineering 93:395–406
Knothe G (2001) Historical perspectives on vegetable oil-based diesel fuel. INFORM 12:1103–1107
Chavanne CG (1937) Procédé de transformation d’huiles végétales en vue de leur utilisation comme carburants (Procedure for the transformation of vegetable oils in view of their use as fuels). Belgian Patent BE 422,877, 31 Aug 1937
van den Abeele M (1942) Palm oil as raw material for the production of a heavy motor fuel (L’huile de palme. Matière première pour la préparation d’un carburant lourd utilisable dans les moteurs à combustion interne) Bull Agr Congo Belge 33:3–90
Chavanne G (1942) Sur un mode d’utilisation possible de l’huile de palme à la fabrication d’un carburant lourd. (A method of possible utilization of palm oil for the manufacture of a heavy fuel) Bull Soc Chim 19:52–58
Bruwer JJ, van d Boshoff B, Hugo FJC, Fuls J, Hawkins C, van der Walt AN, Engelbrecht A, du Plessis LM (1980) The utilization of sunflower seed oil as a renewable fuel for diesel engines. Nat Energy Symp, ASAE, Kansas City, MO
Bruwer JJ, van d Boshoff B, Hugo FJC, du Plessis LM, Fuls J, Hawkins C, van der Walt AN, Engelbrecht A (1980) Sunflower seed oil as an extender for diesel fuel in agricultural tractors. Symp S Afr Inst Agricult Eng
Freedman B, Pryde EH, Mounts TL (1984) Variables affecting the yields of fatty esters from transesterified vegetable oils. J Am Oil Chem Soc 61:1638–1643
Wicke B, Dornburg V, Junginger M, Faaij A (2008) Different palm oil production systems for energy purposes and their greenhouse gas implications. Biomass Bioenergy 32:1322–1337
Yee KF, Tan KT, Abdullah AZ, Lee KT (2009) Life cycle assessment of palm biodiesel: revealing facts and benefits and sustainability. Appl Energy 86:S189–S196
Crutzen PJ, Mosier AR, Smith KA, Winiwarter W (2008) N2O Release from agro-biofuel production negates global warming reduction by replacing fossil fuels. Atmos Chem Phys Discuss 7:11191–11205; Atmos Chem Phys Discuss 8:389–395
Hill J, Nelson E, Tilman D, Polasky S, Tiffany D (2006) Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels. Proc Nat Acad Sci 103:11206–11210
Huo H, Wang M, Bloyd C, Putsche V (2009) Life cycle assessment of energy use and greenhouse gas emissions of soybean-derived biodiesel and renewable fuels. Environ Sci Technol 43:750–756
Williams PRD, Inman D, Aden A, Heath GA (2009) Environmental and sustainability factors associated with next-generation biofuels in the U.S.: what do we really know? Environ Sci Technol 43:4763–4775
Frondel M, Peters J (2007) Biodiesel: a new oildorado? Energy Policy 35:1675–1684
National Biodiesel Board. http://www.biodiesel.org/pdf_files/fuelfactsheets/Production_Capacity.pdf, http://www.biodiesel.org/pdf_files/fuelfactsheets/Production_Graph_Slide.pdf. Accessed 2 Nov 2009
European Biodiesel Board. http://www.ebb-eu.org/stats.php, http://www.ebb-eu.org/prev_stats_production.php. Accessed 2 Nov 2009
Canakci M, Van Gerpen J (1999) Biodiesel production via acid catalysis. Trans ASAE 42:1203–1210
Gutsche B (1997) Technology of methyl ester production and its application to biofuels. (Technologie der Methylesterherstellung - Anwendung für die Biodieselproduktion). Fett/Lipid 99:418–427
Schuchardt U, Serchelt R, Vargas RM (1998) Transesterification of vegetable oils: a review. J Braz Chem Soc 9:199–210
Ma F, Hanna MA (1999) Biodiesel production: a review. Bioresour Technol 70:1–15
Fukuda H, Kondo A, Noda H (2001) Biodiesel fuel production by transesterification of oils. J Biosci Bioeng 92:405–416
Haas MJ, Piazza GJ, Foglia TA (2002) Enzymatic approaches to the production of biodiesel fuels. In: Kuo TM, Gardner HW (eds) Lipid biotechnology. Marcel Dekker, New York, Basel, pp 587–598
Shah S, Sharma S, Gupta MN (2003) Enzymatic transesterification for biodiesel production. Ind J Biochem Biophys 40:392–399
Nakazono Y (2003) Production technology for biodiesel fuels (Article in Japanese). Eco Indus 8:43–53
Bondioli P (2004) The preparation of fatty acid esters by means of catalytic reactions. Top Catal 27:77–82
Hoydonckx HE, De Vos DE, Chavan SA, Jacobs PA (2004) Esterification and transesterification of renewable chemicals. Top Catal 27:83–96
Lotero E, Liu Y, Lopez DE, Suwannakarn K, Bruce DA, Goodwin JG Jr (2005) Synthesis of biodiesel via acid catalysis. Ind Eng Chem Res 44:5353–5363
Meher LC, Sagar DV, Nail SN (2006) Technical aspects of biodiesel production by transesterification––a review. Renew Sustain Energy Rev 10:248–268
Mbaraka IK, Shanks BH (2006) Conversion of oils and fats using advanced mesoporous heterogeneous catalysts. J Am Oil Chem Soc 83:79–91
Lotero E, Goodwin JG Jr, Bruce DA, Suwannakarn K, Liu Y, Lopez DE (2006) The catalysis of biodiesel synthesis. Catalysis 19:41–83
Marchetti JM, Miguel VU, Errazu AF (2007) Possible methods for biodiesel production. Renew Sustain Energy Rev 11:1300–1311
Behzadi S, Farid MM (2007) Review: examining the use of different feedstock for the production of biodiesel. Asia-Pacific J Chem Eng 2:480–486
Al-Zuhair S (2007) Production of biodiesel: possibilities and challenges. Biofuels Bioprod Bioref 1:57–66
Akoh CC, Chang S-W, Lee G-C, Shaw J-F (2007) Enzymatic approach to biodiesel production. J Agric Food Chem 55:8995–9005
Ranganathan SV, Lakshmi Narasimhan S, Muthukumar K (2008) An overview of enzymatic production of biodiesel. Bioresour Technol 99:3975–3981
Nikiema J, Heitz M (2008) Biodiesel. II. Production––a synthesis (Le biodiesel. II. Production––une synthèse). Can J Civil Eng 35:107–117
Nielsen PM, Brask J, Fjerbaek L (2008) Enzymatic biodiesel production: technical and economical considerations. Eur J Lipid Sci Technol 110:692–700
Di Serio M, Tesser RL, Pengmei L, Santacesaria E (2008) Heterogeneous catalysts for biodiesel production. Energy Fuels 22:207–217
Fjerbaek L, Christensen KV, Norddahl B (2009) A review of the current state of biodiesel production using enzymatic transesterification. Biotechnol Bioeng 102:1298–1315
Harrington KJ (1986) Chemical and physical properties of vegetable oil esters and their effect on diesel fuel performance. Biomass 9:1–17
Knothe G, Matheaus AC, Ryan TW III (2003) Cetane numbers of branched and straight-chain fatty esters determined in an ignition quality tester. Fuel 82:971–997
Ladommatos N, Parsi M, Knowles A (1996) The effect of fuel cetane improver on diesel pollutant emissions. Fuel 75:8–14
McCormick RL, Graboski MS, Alleman TL, Herring AM (2001) Impact of biodiesel source material and chemical structure on emissions of criteria pollutants from a heavy-duty engine. Environ Sci Technol 35:1742–1747
Knothe G, Sharp CA, Ryan TW III (2006) Exhaust emissions of biodiesel. Petrodiesel, neat methyl esters, and alkanes in a new technology engine. Energy Fuels 20:403–408
Knothe G, Steidley KR (2005) Kinematic viscosity of biodiesel fuel components. influence of compound structure and comparison to petrodiesel fuel components. Fuel 84:1059–1065
Frankel EN (2005) Lipid oxidation, 2nd edn. The Oily Press, PJ Barnes & Associates, Bridgwater, England
Knothe G (2002) Structure indices in FA Chemistry. How relevant is the iodine value? J Am Oil Chem Soc 79:847–854
Dunn RO, Bagby MO (1995) Low-temperature properties of triglyceride-based diesel fuels: transesterified methyl esters and petroleum middle distillate/ester blends. J Am Oil Chem Soc 72:895–904
Lacey PI, Westbrook SR (1995) Diesel fuel lubricity. SAE Technical Paper Series 950248
Knothe G, Steidley KR (2005) Lubricity of components of biodiesel and petrodiesel. The origin of biodiesel lubricity. Energy Fuels 19:1192–1200
Yu L, Lee I, Hammond EG, Johnson LA, Van Gerpen JH (1998) The influence of trace components on the melting point of methyl soyate. J Am Oil Chem Soc 75:1821–1824
Bondioli P, Cortesi N, Mariani C (2008) Identification and Quantification of steryl glucosides in biodiesel. Eur J Lipid Sci Technol 110:120–126
Moreau RA, Scott KM, Haas MJ (2008) The identification of steryl glucosides in precipitates from commercial biodiesel. J Am Oil Chem Soc 85:761–770
Van Hoed V, Zyaykina N, De Greyt W, Maes J, Verhé R, Demeestere K (2008) Identification and occurrence of steryl glucosides in palm and soy biodiesel. J Am Oil Chem Soc 85:701–709
Bringe NA (2005) Soybean oil composition for biodiesel. In: Knothe G, Van Gerpen J, Krahl J (eds) The biodiesel handbook. AOCS Press, Champaign, IL, pp 161–164
Knothe G (2008) “Designer” biodiesel: optimizing fatty ester composition to improve fuel properties. Energy Fuels 22:1358–1364
Knothe G, Cermak SC, Evangelista RL (2009) Cuphea oil as source of biodiesel with improved fuel properties caused by high content of methyl decanoate. Energy Fuels 23:1743–1747
Dehesh K (2001) How can we genetically engineer oilseed crops to produce high levels of medium-chain fatty acids? Eur J Lipid Sci Technol 103:688–697
Moser BR, Knothe G, Vaughn SF, Isbell TA (2009) Production and evaluation of biodiesel from field pennycress (Thlaspi arvense L.). Oil Energy Fuels 23:4149–4155
Knothe G (2009) Improving biodiesel fuel properties by modifying fatty ester composition. Energy Environ. Sci. 2:759–766
Pinzi S, Garcia IL, Lopez-Gimenez FJ, Luque de Castro MD, Dorado G, Dorado MP (2009) The ideal vegetable oil-based biodiesel composition: a review of social. Economical and technical implications. Energy Fuels 23:2325–2341
Roessler PG, Brown LM, Dunahay TG, Heacox DA, Jarvis EE, Schneider JC, Talbot SG, Zeiler KG (1994) Genetic engineering approaches for enhanced production of biodiesel fuel from microalgae. ACS Symp Ser 566:255–270 (Enzymatic conversion of biomass for fuels production)
Dunahay TG, Jarvis EE, Dais SS, Roessler PG (1996) Manipulation of microalgal lipid production using genetic engineering. Appl Biochem Biotechnol 57–58:223–231
Kalscheuer R, Stölting T, Steinbüchel A (2006) Microdiesel: Escherichia coli engineered for fuel production. Microbiology 152:2529–2536
Keasling JD, Hu Z, Somerville C, Church G, Berry D, Friedman L, Schirmer A, Brubaker S, del Cardayré SB (2007) Production of fatty acids and derivatives thereof, WO/2007/136762, November 29, 2007. http://www.wipo.int/pctdb/en/wo.jsp?WO=2007136762
Wackett LP (2008) Biomass to fuels via microbial transformations. Curr Opin Chem Biol 12:187–193
Stöveken T, Steinbüchel A (2008) Bacterial acyltransferases as an alternative for lipase-catalyzed acylation for the production of oleochemicals and fuels. Angew Chem Int Ed 47:3688–3694
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Knothe, G. Biodiesel: Current Trends and Properties. Top Catal 53, 714–720 (2010). https://doi.org/10.1007/s11244-010-9457-0
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DOI: https://doi.org/10.1007/s11244-010-9457-0