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Effect of gold addition on Pt and Pd catalysts in liquid phase oxidations

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Single phase Au–Pd and Au–Pt on carbon catalysts have been compared in the liquid phase oxidation of glycerol (representative for polyols) and n-octanol (representative for long chain aliphatic alcohol). The observed overall enhancement of catalytic activity appeared to be function of support, substrate and reaction conditions. Effect of substrate structure has been disentangled: synergistic effect between Au and Pt was maximized when polyol-like substrates were oxidized whereas Au–Pd based catalyst showed a more general match.

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References

  1. M. Haruta (2004) Gold Bull 37 127

    Google Scholar 

  2. M. Haruta (2005) Nature 437 1098 Occurrence Handle16237427 Occurrence Handle10.1038/4371098a Occurrence Handle1:CAS:528:DC%2BD2MXhtFaht7fN Occurrence Handle2005Natur.437.1098H

    Article  PubMed  CAS  ADS  Google Scholar 

  3. M. Corti R. Holliday A. Laguna B. Nieuwenhuys D. Thompson (2003) Gold Bull 36 144

    Google Scholar 

  4. D.T. Thompson (2006) Topics Catal. 38 231 Occurrence Handle10.1007/s11244-006-0021-x Occurrence Handle1:CAS:528:DC%2BD28XnvFKrurg%3D

    Article  CAS  Google Scholar 

  5. G.J. Hutchings S. Carrettin P. Landon J.K. Edwards D. Enache D.W. Knight Y.-J. Xu A.F. Carley (2006) Topics Catal. 38 223 Occurrence Handle10.1007/s11244-006-0020-y Occurrence Handle1:CAS:528:DC%2BD28XnvFKrurs%3D

    Article  CAS  Google Scholar 

  6. D.T. Thompson (2003) Appl. Cat. A 243 201 Occurrence Handle10.1016/S0926-860X(02)00551-3 Occurrence Handle1:CAS:528:DC%2BD3sXislehur8%3D

    Article  CAS  Google Scholar 

  7. G.C. Bond D.T. Thompson (1999) Catal. Rev.Sci. Eng 41 319 Occurrence Handle10.1081/CR-100101171 Occurrence Handle1:CAS:528:DyaK1MXmvFehsLk%3D

    Article  CAS  Google Scholar 

  8. M. Haruta M. Daté (2001) Appl. Cat. A 222 427 Occurrence Handle10.1016/S0926-860X(01)00847-X Occurrence Handle1:CAS:528:DC%2BD38XjvFai

    Article  CAS  Google Scholar 

  9. M.S. Chen D.W. Goodman (2006) Catal. Today 111 22 Occurrence Handle10.1016/j.cattod.2005.10.007 Occurrence Handle1:CAS:528:DC%2BD2MXhtlCnsb3P

    Article  CAS  Google Scholar 

  10. G.J. Hutchings (2005) Catal.Today 100 55 Occurrence Handle10.1016/j.cattod.2004.12.016 Occurrence Handle1:CAS:528:DC%2BD2MXjs1Sms70%3D

    Article  CAS  Google Scholar 

  11. L. Prati M. Rossi (1998) J.Catal 176 552 Occurrence Handle10.1006/jcat.1998.2078 Occurrence Handle1:CAS:528:DyaK1cXjvFemsr0%3D

    Article  CAS  Google Scholar 

  12. L. Prati G. Martra (1999) Gold Bull 32 96 Occurrence Handle1:CAS:528:DC%2BD3cXnt1ejsw%3D%3D

    CAS  Google Scholar 

  13. F. Porta L. Prati M. Rossi S. Coluccia G. Martra (2000) Catal. Today 61 165 Occurrence Handle10.1016/S0920-5861(00)00370-9 Occurrence Handle1:CAS:528:DC%2BD3cXmtF2nu74%3D

    Article  CAS  Google Scholar 

  14. D.T. Thompson (2004) Platinum Metals Rev 48 169 Occurrence Handle10.1595/147106704X5717 Occurrence Handle1:CAS:528:DC%2BD2MXitVCrtbg%3D

    Article  CAS  Google Scholar 

  15. W.D. Provine P.L. Mills J.J. Lerou (1996) Stud. Surf. Sci. Catal 101 191 Occurrence Handle1:CAS:528:DyaK28XmtFWgtb0%3D Occurrence Handle10.1016/S0167-2991(96)80229-1

    Article  CAS  Google Scholar 

  16. N. Macleod J.M. Keel R. Lambert (2004) Appl. Catal. A 261 37 Occurrence Handle10.1016/j.apcata.2003.10.032 Occurrence Handle1:CAS:528:DC%2BD2cXivVWgu74%3D

    Article  CAS  Google Scholar 

  17. S. Hermans S. Vanderheyden M. Devilliers (2005) Catal. Lett 99 55 Occurrence Handle10.1007/s10562-004-0776-2 Occurrence Handle1:CAS:528:DC%2BD2MXotFGm

    Article  CAS  Google Scholar 

  18. L. Bianchi P. Canton N. Dimitratos F. Porta L. Prati (2005) Catal. Today 102 203 Occurrence Handle10.1016/j.cattod.2005.02.003 Occurrence Handle1:CAS:528:DC%2BD2MXks1Wru7g%3D

    Article  CAS  Google Scholar 

  19. D. Wang , A. Villa, F. Porta, D. Su and L. Prati, Chem. Commun. (2006) 1956

  20. M. Comotti C. Della Pina M. Rossi (2006) J. Mol. Cat. A 251 89 Occurrence Handle10.1016/j.molcata.2006.02.014 Occurrence Handle1:CAS:528:DC%2BD28XjvFyksbk%3D

    Article  CAS  Google Scholar 

  21. A.M. Venezia V. Parola ParticleLa G. Deganello B. Pawelec J.L.G. Fierro (2003) J. Catal 215 317 Occurrence Handle10.1016/S0021-9517(03)00005-8 Occurrence Handle1:CAS:528:DC%2BD3sXjvVCnt70%3D

    Article  CAS  Google Scholar 

  22. M.O. Nutt J.B. Hughes M.S. Wong (2005) Environ. Sci. Technol 39 1346 Occurrence Handle15787376 Occurrence Handle10.1021/es048560b Occurrence Handle1:CAS:528:DC%2BD2MXjs1Kgtw%3D%3D

    Article  PubMed  CAS  Google Scholar 

  23. P. Landon, P.J. Collier, A.J. Papworth, C.J. Kiely, G.J. Hutchings, Chem. Commun. (2002) 2058

  24. J.K. Edwards B.E. Solsona P. Landon A.F. Carley A. Herzing C.J. Kiely G.J. Huthchings (2005) J. Catal 236 69 Occurrence Handle10.1016/j.jcat.2005.09.015 Occurrence Handle1:CAS:528:DC%2BD2MXhtFKmur%2FM

    Article  CAS  Google Scholar 

  25. B.E. Solsona J.K. Edwards P. Landon A.F. Carley A. Herzing C.J. Kiely G.J. Huthchings (2006) Chem. Mater 18 2689 Occurrence Handle10.1021/cm052633o Occurrence Handle1:CAS:528:DC%2BD28XktFShurY%3D

    Article  CAS  Google Scholar 

  26. L. Gang D.I. Enache J.K. Edwards A.F. Carley D.W. Knight G.J. Huthchings (2006) Catal. Lett 110 7 Occurrence Handle10.1007/s10562-006-0083-1 Occurrence Handle1:CAS:528:DC%2BD28XnvFKkuro%3D

    Article  CAS  Google Scholar 

  27. D.I. Enache J.K. Edwards P. Landon B.E. Solsona A.F. Carley A. Herzing M. Watanabe C.J. Kiely D.W. Knight G.J. Huthchings (2006) Science 311 362 Occurrence Handle16424335 Occurrence Handle10.1126/science.1120560 Occurrence Handle1:CAS:528:DC%2BD28XlvFSgsA%3D%3D Occurrence Handle2006Sci...311..362E

    Article  PubMed  CAS  ADS  Google Scholar 

  28. M.D. Hughes Y.J. Xu P. Jenkins P. McMorn P. Landon D.I. Enache A.F. Carley G.A. Attard G.J. Hutchings F. King E. Hugh Stitt P. Johnston K. Griffin C.J. Kiely (2005) Nature 437 1132 Occurrence Handle16237439 Occurrence Handle10.1038/nature04190 Occurrence Handle1:CAS:528:DC%2BD2MXhtFahtLzN Occurrence Handle2005Natur.437.1132H

    Article  PubMed  CAS  ADS  Google Scholar 

  29. P.N. Njoki J. Luo L. Wang M.M. Maye H. Quaizir C.-J. Zhong (2005) Langmuir 21 1623 Occurrence Handle15697317 Occurrence Handle10.1021/la047555i Occurrence Handle1:CAS:528:DC%2BD2MXhs1Wisw%3D%3D

    Article  PubMed  CAS  Google Scholar 

  30. N. Dimitratos A. Villa D. Wang F. Porta D. Su L. Prati (2006) J. Catal 244 113 Occurrence Handle10.1016/j.jcat.2006.08.019 Occurrence Handle1:CAS:528:DC%2BD28XhtVykt7jP

    Article  CAS  Google Scholar 

  31. Schwank J., Gold Bull. 18 (1985) 2 and reference cited therein

  32. Guczi L., Catal. Today 101 (2005) 53 and reference cited therein

  33. M. Chen D. Kumar C.W. Yi D.W. Goodman (2005) Science 310 291 Occurrence Handle16224016 Occurrence Handle10.1126/science.1115800 Occurrence Handle1:CAS:528:DC%2BD2MXhtV2hurrL Occurrence Handle2005Sci...310..291C

    Article  PubMed  CAS  ADS  Google Scholar 

  34. A. Groβ (2006) Topics Catal. 37 29 Occurrence Handle10.1007/s11244-006-0005-x Occurrence Handle1:CAS:528:DC%2BD28XjslKitrs%3D

    Article  CAS  Google Scholar 

  35. C. Burato P. Centomo G. Pace M. Favaro L. Prati B. Corain (2005) J. Mol. Cat. A 238 26 Occurrence Handle10.1016/j.molcata.2005.04.062 Occurrence Handle1:CAS:528:DC%2BD2MXmtlOjs7Y%3D

    Article  CAS  Google Scholar 

  36. N. Dimitratos F. Porta L. Prati A. Villa (2005) Catal. Lett 99 181 Occurrence Handle10.1007/s10562-005-2114-8 Occurrence Handle1:CAS:528:DC%2BD2MXovFOmtA%3D%3D

    Article  CAS  Google Scholar 

  37. L. Guczi (1984) J. Mol. Catal 25 13 Occurrence Handle10.1016/0304-5102(84)80028-0 Occurrence Handle1:CAS:528:DyaL2cXlslSnsb8%3D

    Article  CAS  Google Scholar 

  38. J.W.A. Sachtler G.A. Somorjai (1984) J. Catal 89 35 Occurrence Handle10.1016/0021-9517(84)90277-X Occurrence Handle1:CAS:528:DyaL2cXkvFeitbs%3D

    Article  CAS  Google Scholar 

  39. T. Mallat A. Baiker (1994) Catal.Today 19 247 Occurrence Handle10.1016/0920-5861(94)80187-8 Occurrence Handle1:CAS:528:DyaK2cXivFOlsr0%3D

    Article  CAS  Google Scholar 

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Correspondence to Laura Prati.

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Prati, L., Villa, A., Campione, C. et al. Effect of gold addition on Pt and Pd catalysts in liquid phase oxidations. Top Catal 44, 319–324 (2007). https://doi.org/10.1007/s11244-007-0305-9

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