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Electrochemical promotion in a monolith electrochemical plate reactor applied to simulated and real automotive pollution control

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The novel monolithic-type electrochemical promoted reactor (MEPR), filled with thick Rh and Pt coated films on thin yttria-stabilized zirconia (YSZ) plates, has been tested in simulated and real automotive exhaust gas. Ethylene oxidation and NO reduction by C2H4 in presence of oxygen were investigated in laboratory scale while the automotive bench testing was performed in the exhaust of a diesel engine. In all cases electropromotion was achieved, an advance which in addition to their compact and simple design, makes electropromoted units quite promising for automotive exhaust pollution control.

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References

  1. C.G. Vayenas, S. Bebelis, C. Pliangos, S. Brosda and D. Tsiplakides, in: Electrochemical Activation of Catalysis: Promotion, Electrochemical Promotion and Metal-Support Interactions. (Kluwer Academic/Plenum Publishers, New York, 2001)

  2. P. Avila M. Montes E.E. Miro (2005) Chem. Eng. J. 109 11 Occurrence Handle10.1016/j.cej.2005.02.025 Occurrence Handle1:CAS:528:DC%2BD2MXks1KqsLk%3D

    Article  CAS  Google Scholar 

  3. R.M. Heck and R.J. Farrauto, in: Catalytic Air Pollution Control-Commercial Technology, (Van Nostrand Reinhold, New York U.S.A., 1995)

  4. J.W. Geus J.C. Giezen Particlevan (1999) Catal. Today 47 169 Occurrence Handle10.1016/S0920-5861(98)00297-1 Occurrence Handle1:CAS:528:DyaK1cXnvVSlt7o%3D

    Article  CAS  Google Scholar 

  5. A.G. Konstandopoulos, M. Kostoglou, E. Skaperdas, E. Papaioannou, D. Zarvalis and E. Kladopoulou (2000) SAE Tech. Paper 2000-01-1016

  6. R.M. Heck S. Gulati R.J. Farrauto (2001) Chem. Eng. J. 82 149 Occurrence Handle10.1016/S1385-8947(00)00365-X Occurrence Handle1:CAS:528:DC%2BD3MXhvFKhurw%3D

    Article  CAS  Google Scholar 

  7. S. Balomenou D. Tsiplakides A. Katsaounis S. Thiemann-Handler B. Cramer G. Foti C. Conminellis C.G. Vayenas (2004) Appl. Catal. B 52 181 Occurrence Handle10.1016/j.apcatb.2004.04.007 Occurrence Handle1:CAS:528:DC%2BD2cXmt1Wrsbk%3D

    Article  CAS  Google Scholar 

  8. D. Tsiplakides S. Balomenou A. Katsaounis D. Archonta C. Koutsodontis C.G. Vayenas (2005) Catal. Today 100 133–144 Occurrence Handle10.1016/j.cattod.2004.12.015 Occurrence Handle1:CAS:528:DC%2BD2MXjs1Smsr8%3D

    Article  CAS  Google Scholar 

  9. A.G. Konstandopoulos, E. Papaioannou, D. Zarvalis, S. Skopa, P. Baltzopoulou, E. Kladopoulou, M. Kostoglou and S. Lorentzou, SAE Technical Paper 2005-01-0670 (SP-1942), (2005)

  10. A.G. Konstandopoulos, N. Vlachos, I. Stavropoulos, S. Skopa, U. Schumacher, D. Woiki and M. Frey, SAE Technical Paper 2005-01-0968 (SP-1940), (2005)

  11. A.G. Konstandopoulos, et al., SAE Tech. Paper No. 2004-01-0694 (SP-1861), (2004)

  12. C. Pliangos I.V. Yentekakis X.E. Verykios C.G. Vayenas (1995) J. Catal. 154 124 Occurrence Handle10.1006/jcat.1995.1154 Occurrence Handle1:CAS:528:DyaK2MXmtVKhtrs%3D

    Article  CAS  Google Scholar 

  13. C.G. Vayenas S. Brosda C. Pliangos (2001) J. Catal. 203 329 Occurrence Handle10.1006/jcat.2001.3348 Occurrence Handle1:CAS:528:DC%2BD3MXotF2itL4%3D

    Article  CAS  Google Scholar 

  14. C.G. Vayenas S. Bebelis S. Ladas (1990) Nature 343 625 Occurrence Handle10.1038/343625a0 Occurrence Handle1:CAS:528:DyaK3cXitVKmsr8%3D

    Article  CAS  Google Scholar 

  15. C. Pliangos C. Raptis T. Badas C.G. Vayenas (2000) Solid State Ionics 136/137 767 Occurrence Handle10.1016/S0167-2738(00)00549-X

    Article  Google Scholar 

  16. M.D. Amiridis T. Zhang R.J. Farrauto (1996) Appl. Catal. B 10 203 Occurrence Handle10.1016/0926-3373(96)00031-8 Occurrence Handle1:CAS:528:DyaK28XltlOqt7Y%3D

    Article  CAS  Google Scholar 

  17. N. Kotsionopoulos S. Bebelis (2005) J. Appl. Electrochem. 35 1253 Occurrence Handle10.1007/s10800-005-9037-3 Occurrence Handle1:CAS:528:DC%2BD2MXhtlCrtbbI

    Article  CAS  Google Scholar 

  18. J. Nicole D. Tsiplakides S. Wodiunig C. Comninellis (1997) J. Electrochem. Soc. 144 IssueID12 L312 Occurrence Handle10.1149/1.1838143 Occurrence Handle1:CAS:528:DyaK1cXhtFWktQ%3D%3D

    Article  CAS  Google Scholar 

  19. J. Nicole D. Tsiplakides C. Pliangos X.E. Verykios C. Comninellis C.G. Vayenas (2001) J. Catal. 204 23 Occurrence Handle10.1006/jcat.2001.3360 Occurrence Handle1:CAS:528:DC%2BD3MXotF2itbk%3D

    Article  CAS  Google Scholar 

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Correspondence to Constantinos G. Vayenas.

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Balomenou, S.P., Tsiplakides, D., Vayenas, C.G. et al. Electrochemical promotion in a monolith electrochemical plate reactor applied to simulated and real automotive pollution control. Top Catal 44, 481–486 (2007). https://doi.org/10.1007/s11244-006-0140-4

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