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Two nickel(II) carboxyphosphonates with different supramolecular structures: synthesis, crystal structures and magnetic properties

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Abstract

Two Ni(II) carboxyphosphonates, namely [Ni(H4L)2] (1) and [Ni(H3L)(H2O)]·2H2O (2) (H5L=HOOCC6H4CH2N(CH2PO3H2)2), have been hydrothermally synthesized. Structural analyses reveal that 1 shows a two-dimensional (2D) inorganic layer structure, and the layers are further packed into a three-dimensional (3D) supramolecular structure through the interlayer hydrogen-bonding interactions. In 2, two adjacent {NiO5N} polyhedra are connected to form a {Ni2O8N2} dimer, and these dimers are further linked by {CPO3} tetrahedra to form a one-dimensional (1D) chain. Consecutive chains are further connected by the intermolecular hydrogen-bonding interactions, resulting in a 2D supramolecular layer structure. Magnetic analyses exhibited that 1 shows major antiferromagnetic behavior, whereas 2 displays ferromagnetic interactions at low temperatures. Meanwhile, the magnetic properties of 1 and 2 have also been quantified using the Curie–Weiss law and the PHI program package, respectively.

Graphic abstract

Two nickel(II) carboxyphosphonates with different structures showed different magnetic behaviors. Meanwhile, the magnetic properties of 1 and 2 have also been quantified using the Curie–Weiss law and the PHI program package.

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Acknowledgements

We thank Dr. Meng Yin-Shan from Dalian university of technology for providing the help of magnetic measurement. This work was also supported by the Scientific Research Fund of Liaoning Provincial Education Department (Grant No. LQ2020023) and the Doctoral Scientific Research Project of Liaoning Normal University (Grant No. BS2020L001).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People’s Republic of China

    Yan Yu Zhu, Xu Zhang, Ya Nan Zhou, Zhen Gang Sun & Cheng Qi Jiao

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  1. Yan Yu Zhu
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  2. Xu Zhang
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  3. Ya Nan Zhou
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Zhu, Y.Y., Zhang, X., Zhou, Y.N. et al. Two nickel(II) carboxyphosphonates with different supramolecular structures: synthesis, crystal structures and magnetic properties. Transit Met Chem 46, 593–600 (2021). https://doi.org/10.1007/s11243-021-00476-2

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