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A potassium-encapsulated Preyssler-based structure modified by binuclear cyclic copper(II) clusters: photocatalytic and electrochemical properties

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Abstract

Through the use of a flexible ligand 1,1′-bis(3,5-dimethyl-1H-pyrazolate)methane (H2bdpm), a K-encapsulated Preyssler-based complex, [Cu4(H2bdpm)4(H2O)10(H6KP5W30O110)]·2(H2bdpm)·14H2O, has been synthesized under hydrothermal conditions. Single crystal X-ray diffraction analysis shows that the complex contains rare K-encapsulated Preyssler anions, which are linked by binuclear cyclic clusters [Cu2(H2bdpm)2]4+ to form a 1D chain. Adjacent chains are further connected by abundant intermolecular forces to construct a 2D supramolecular framework. The photocatalytic and electrochemical properties of the complex have been investigated.

Graphical abstract

(1) The Preyssler-based POM-TMCs are rarely reported. (2) The K-encapsulated Preyssler anion is uncommonly observed in Preyssler-based compound. (3) Preyssler anions are linked by binuclear CuII clusters to form a 1D chain. (4) Compound 1 exhibits photocatalytic and electrochemical properties.

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Acknowledgements

This research received financial support from the National Natural Science Foundation of China (Nos. 21571023, and 21101015) and Talent-supporting Program Foundation of Education Office of Liaoning Province (LJQ2012097).

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Authors and Affiliations

  1. Department of Chemistry, Bohai University, Jinzhou, 121013, People’s Republic of China

    Ai-Xiang Tian, Yan Yang, Huai-Ping Ni, Yu-Bo Fu, Meng-Le Yang, Guo-Cheng Liu & Jun Ying

  2. Liaoning Ocean and Fisheries Science Research Institute, Dalian, People’s Republic of China

    Gui-Ying Liu

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  1. Ai-Xiang Tian
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  2. Yan Yang
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Correspondence to Ai-Xiang Tian or Jun Ying.

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Tian, AX., Yang, Y., Ni, HP. et al. A potassium-encapsulated Preyssler-based structure modified by binuclear cyclic copper(II) clusters: photocatalytic and electrochemical properties. Transit Met Chem 44, 303–309 (2019). https://doi.org/10.1007/s11243-018-00294-z

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  • DOI: https://doi.org/10.1007/s11243-018-00294-z

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